The potential energy curve of the ground state of lithium, X1Σg+ Li2

Journal of Molecular Spectroscopy

Volumn 221, Issue 1, 2003, Pages 67-71

  Zavitsas, Andreas A ^a  

^a LONG ISLAND UNIVERSITY   (United States)

Author keywords

Li2; Lithium; Potential energy curve; RKR; Universal potential energy function

Indexed keywords

BOND STRENGTH (CHEMICAL); DISSOCIATION; FUNCTIONS; GROUND STATE; POTENTIAL ENERGY; SPECTROSCOPIC ANALYSIS;

MORSE FUNCTIONS; SPECTROSCOPIC POTENTIALS; UNIVERSAL POTENTIAL ENERGY FUNCTION;

LITHIUM;

EID: 0141883900     PISSN: 00222852     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-2852(03)00202-9     Document Type: Article

References (12)

1. A.A. Zavitsas, J. Am. Chem. Soc. 113 (1991) 4755-4767.
2. e in the inner limb and to 68.0% in the outer.
3. e.
4. e.
5. e in the inner limb and to 99.6% in the outer.
6. e.
7. e in the inner limb and to 88.3% in the outer.
8. e.
9. W.T. Zemke, W.C. Stwalley, J. Phys. Chem. 97 (1993) 2053-2058.
10. C.A. Coulson, Valence, Oxford University Press, London, 1959, p. 40; We calculate the effective nuclear charge for an electron approaching the atom in question to form the bond, not the highest energy electron of the atom.
11. C. Linton, F. Martin, I. Russier, A.J. Ross, P. Crozet, S. Churassy, R. Bacis, J. Mol. Spectrosc. 175 (1996) 340-353.
12. Values of the reported potential exceeding 97% of dissociation were excluded from the calculation, because the upper parts of potentials are known to have a great deal of uncertainty in distances.