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For examples of the Pd-catalyzed tandem coupling of organic halides, unsaturated compounds and organoboranes, see: (a) Yang, F. Y.; Wu, M. Y.; Cheng, C. H. J. Am. Chem. Soc. 2000, 122, 7122. (b) Huang, T. H.; Chang, H. M.; Wu, M. Y.; Cheng, C. H. J. Org. Chem. 2002, 67, 99. (c) Thadani, A. N.; Rawal, V. H. Org, Lett. 2002, 4, 4317. (d) Shaulis, K. M.; Hoskin, B. L.; Townsend, J. R.; Goodson, F. E.; Incarvito, C. D.; Rheingold, A. L. J. Org. Chem. 2002, 67, 5860.
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For examples of the Pd-catalyzed tandem coupling of organic halides, unsaturated compounds and organoboranes, see: (a) Yang, F. Y.; Wu, M. Y.; Cheng, C. H. J. Am. Chem. Soc. 2000, 122, 7122. (b) Huang, T. H.; Chang, H. M.; Wu, M. Y.; Cheng, C. H. J. Org. Chem. 2002, 67, 99. (c) Thadani, A. N.; Rawal, V. H. Org, Lett. 2002, 4, 4317. (d) Shaulis, K. M.; Hoskin, B. L.; Townsend, J. R.; Goodson, F. E.; Incarvito, C. D.; Rheingold, A. L. J. Org. Chem. 2002, 67, 5860.
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For examples of the Pd-catalyzed tandem coupling of organic halides, unsaturated compounds and organoboranes, see: (a) Yang, F. Y.; Wu, M. Y.; Cheng, C. H. J. Am. Chem. Soc. 2000, 122, 7122. (b) Huang, T. H.; Chang, H. M.; Wu, M. Y.; Cheng, C. H. J. Org. Chem. 2002, 67, 99. (c) Thadani, A. N.; Rawal, V. H. Org, Lett. 2002, 4, 4317. (d) Shaulis, K. M.; Hoskin, B. L.; Townsend, J. R.; Goodson, F. E.; Incarvito, C. D.; Rheingold, A. L. J. Org. Chem. 2002, 67, 5860.
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note
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The cis-alkyne insertion has been proven by the structures of products which were determined by NOESY NMR experiments.
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