Synthesis, reactivity and comparative structural studies on copper(I) and gold(I) halo complexes with tripodal polyphosphines in 1:1 metal to ligand ratio. The X-ray crystal structures of three mononuclear neutral compounds

Inorganica Chimica Acta

Volumn 353, Issue , 2003, Pages 206-216

  García Seijo, M Inés ^a   Sevillano, Paloma ^a   Gould, Robert O ^b   Fernández Anca, Damián ^a   García Fernández, M Esther ^a  

^a UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

^b UNIVERSITY OF EDINBURGH   (United Kingdom)

Author keywords

31P NMR spectroscopy; Copper(I) and gold(I); Ring closure and opening reactions; Tripodal polyphosphines; X ray diffraction

Indexed keywords

BROMINE; CHELATION; CHLORINE COMPOUNDS; COPPER COMPOUNDS; CRYSTALS; LIGANDS; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS COMPOUNDS; POSITIVE IONS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

31P-NMR SPECTROSCOPY; CONDUCTIVITY MEASUREMENTS; DISTORTED TETRAHEDRAL GEOMETRIES; METAL TO LIGAND RATIOS; OPENING REACTIONS; POLYPHOSPHINES; RING CLOSURE REACTIONS; X RAY CRYSTAL STRUCTURES;

GOLD COMPOUNDS;

CHELATING AGENT; COPPER COMPLEX; GOLD COMPLEX; HALIDE; LIGAND; METAL; MONOMER; PHOSPHINE DERIVATIVE; PHOSPHORUS;

ADDITION REACTION; ARTICLE; CHELATION; CHEMICAL STRUCTURE; COMPARATIVE STUDY; COMPLEX FORMATION; CONDUCTANCE; CRYSTAL; CRYSTAL STRUCTURE; GEOMETRY; MASS SPECTROMETRY; MEASUREMENT; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; RING CLOSING METATHESIS; RING OPENING; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0141851900     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(03)00253-6     Document Type: Article

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