Direct synthesis of polycarbonate from carbon monoxide and bisphenol A catalyzed by Pd-carbene complex

Macromolecules

Volumn 36, Issue 19, 2003, Pages 6953-6955

  Okuyama, Ken Ichi ^a,b   Sugiyama, Jun Ichi ^a   Nagahata, Ritsuko ^a   Asai, Michihiko ^a   Ueda, Mitsuru ^b   Takeuchi, Kazuhiko ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CARBONYLATION; CATALYSIS; CATALYSTS; MOLECULAR SIEVES; MOLECULAR WEIGHT; POLYMERIZATION; SYNTHESIS (CHEMICAL);

AROMATIC POLYCARBONATES; BISPHENOL A; PALLADIUM CARBENE COMPLEX;

POLYCARBONATES;

EID: 0141844449     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma034442h     Document Type: Article

References (17)

1. Freitag, D.; Grigo, U.; Muller, P. R.; Nouvertne, W. In Encyclopedia of Polymer Science and Engineering; Wiley: New York, 1988; Vol. 11.
2. Chem. Br. 1994, 30, 970.
3. (a) Hallgren, J. E.; Lucas, G. M. J. Organomet. Chem. 1981, 212, 135.
4. (b) Goyal, M.; Nagahata, R.; Sugiyama, J.; Asai, M.; Ueda, M.; Takeuchi, K. Polymer 2000, 41, 2289.
5. (c) Chaudhari, R. V.; Kelkar, A. A.; Gupte, P.; Bhanage, B. M.; Qureshi, M. S.; Moasser, B.; Pressman, E. J.; Sivaram, S.; Avadhani, C. V.; Kanagasabapathy, S. US Pat. 6,222,002, 2001.
6. (d) Kim, M. B.; Lee, J. S. J. Appl. Polym. Sci. 2002, 86, 937.
7. (a) Goyal, M.; Nagahata, R.; Sugiyama, J.; Asani, M.; Ueda, M.; Takeuchi, K. Catal. Lett. 1998, 54, 29.
8. (b) Ishii, H.; Ueda, M.; Takeuchi, K.; Asai, M. J. Mol. Catal. A: Chem. 1999, 144, 369.
9. (c) Ishii, H.; Goyal, M.; Ueda, M.; Takeuchi, K.; Asai, M. Catal. Lett. 2000, 65, 57.
10. (d) Ishii, H.; Goyal, M.; Ueda, M.; Takeuchi, K.; Asai, M. Appl. Catal., A 2000, 201, 101.
11. Ishii, H.; Goyal, M.; Ueda, M.; Takeuchi, K.; Asai, M. Macromol. Rapid Commun. 2001, 22, 376.
12. Bielawski, C. W.; Benitez, D.; Grubbs, R. H. Science 2002, 297, 2041.
13. Herrmann, W. A.; Reisinger, C. P.; Spiegler, M. J. Organomet. Chem. 1998, 557, 93.
14. Zhang, C.; Trudell, M. L. Tetrahedron Lett. 2000, 42, 595.
15. Gardiner, M. G.; Herrmann, W. A.; Reisinger, C. P.; Schwarz, J.; Spiegler, M. J. Organomet. Chem. 1999, 572, 239.
16. Okuyama, K.; Sugiyama, J.; Nagahata, R.; Asai, M.; Ueda, M.; Takeuchi, K. J. Mol. Catal. A: Chem. 2003, 203, 21.
17. 2. The reactor was heated at 100 °C for 24 h, after which the reaction was quenched by cooling the autoclave in a water bath and by degassing. After filtering the reaction mixture, the product was isolated by precipitation from the condensed reaction mixture (5 mL) by adding excess methanol to give light brown PC at 80% yield (0.41 g).