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Volumn 42, Issue 37, 2003, Pages 4486-4489

A pair of remarkably stable mononuclear chromium(III) and chromium(IV) hydrides

Author keywords

Chromium; Density functional calculations; Hydrides; N ligands; Tripodal ligands

Indexed keywords

ELECTRONIC STRUCTURE; HYDRIDES; REACTION KINETICS; SYNTHESIS (CHEMICAL);

EID: 0141782262     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352177     Document Type: Article
Times cited : (22)

References (33)
  • 16
    • 85007645007 scopus 로고    scopus 로고
    • note
    • Experimental and computational details of 2 and 4 can be found in the Supporting Information.
  • 18
    • 33748242734 scopus 로고
    • a) R. A. Heintz, B. S. Haggerty, H. Wan, A. L. Rheingold, K. H. Theopold, Angew. Chem. 1992, 104, 1100-1102; Angew. Chem. Int. Ed. Engl. 1992, 31, 1077-1079;
    • (1992) Angew. Chem. Int. Ed. Engl. , vol.31 , pp. 1077-1079
  • 20
    • 85007645026 scopus 로고    scopus 로고
    • dissertation, Humboldt-Universität zu Berlin, Cuvillier Verlag, Göttingen
    • 3) were characterized by X-ray crystallography and display similar structural features with 2: S. Schneider, dissertation, Humboldt-Universität zu Berlin, Cuvillier Verlag, Göttingen, 2003.
    • (2003)
    • Schneider, S.1
  • 21
    • 85007645640 scopus 로고    scopus 로고
    • note
    • 3N is also formed in this reaction, which is difficult to separate from 4 by repeated recrystallizations from pentane without considerable loss in yield.
  • 23
    • 85007648447 scopus 로고    scopus 로고
    • note
    • -1.
  • 24
    • 85007625436 scopus 로고    scopus 로고
    • note
    • 3 groups and coordinated THF (2).
  • 25
    • 85007645022 scopus 로고    scopus 로고
    • note
    • -3. CCDC-200256 and CCDC-200257 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
  • 26
    • 85007645017 scopus 로고    scopus 로고
    • references [1] and [2]
    • Chromium(III) complexes usually display an octahedral and rarely a square-pyramidal, trigonal-bipyramidal, or trigonal-planar coordination sphere, and chromium(IV) complexes are in general tetrahedral: a) references [1] and [2];


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.