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85007645007
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note
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Experimental and computational details of 2 and 4 can be found in the Supporting Information.
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17
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0141452585
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a) R. A. Heintz, B. S. Haggerty, H. Wan, A. L. Rheingold, K. H. Theopold, Angew. Chem. 1992, 104, 1100-1102; Angew. Chem. Int. Ed. Engl. 1992, 31, 1077-1079;
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0000385541
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85007645026
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dissertation, Humboldt-Universität zu Berlin, Cuvillier Verlag, Göttingen
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3) were characterized by X-ray crystallography and display similar structural features with 2: S. Schneider, dissertation, Humboldt-Universität zu Berlin, Cuvillier Verlag, Göttingen, 2003.
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(2003)
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Schneider, S.1
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21
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85007645640
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note
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3N is also formed in this reaction, which is difficult to separate from 4 by repeated recrystallizations from pentane without considerable loss in yield.
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22
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0031466855
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2]: R. R. Schrock, S. W. Seidel, N. C. Mösch-Zanetti, K.-Y. Shih, M. B. O'Donoghue, W. M. Davis, W. M. Reiff, J. Am. Chem. Soc. 1997, 119, 11876-11893.
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23
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85007648447
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note
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-1.
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24
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85007625436
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note
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3 groups and coordinated THF (2).
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25
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85007645022
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note
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-3. CCDC-200256 and CCDC-200257 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
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26
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85007645017
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