Evaluation of novel getters for adsorption of radioiodine from groundwater and waste glass leachates

Radiochimica Acta

Volumn 91, Issue 9, 2003, Pages 539-545

  Mattigod, S V ^a   Fryxell, G E ^a   Serne, R J ^a   Parker, K E ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

Adsorption; Distribution coefficients; Getters; Groundwater; Iodine; Waste glass leachate

Indexed keywords

ANION; GLASS; GROUND WATER; IODINE; MERCURY; RADIOACTIVE IODINE; SILICON DIOXIDE; SILVER;

ADSORPTION; ARTICLE; DEGRADATION; LEACHING; PH; RADIOACTIVE WASTE DISPOSAL; WEATHERING;

EID: 0141761157     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.91.9.539.20001     Document Type: Article

References (39)

1. Mann, F. M., Puigh II, R. J., Rittmann, P. D., Kline, N. W., Voogd, J. A., Chen, Y., Eiholzer, C. R., Kincaid, C. T., McGrail, B. P., Lu, A. H., Williamson, G. F., Brown, N. R., LaMont, P. E.: Hanford Immobilized Low-Activity Tank Waste Performance Assessment. DOE/RL-97-69, Rev. 0, U.S. Department of Energy, Richland Operations Office, Richland, Washington (1998).
2. Haq, Z., Bancroft, G. M., Fyfe, W. S., Bird, G., Lopata, V. J.: Sorption of iodide on copper. Env. Sci. Technol. 14, 1106 (1980).
3. Strickert, R., Friedman, A. M., Fried, S.: The sorption of technetium and iodine radioisotopes by various minerals. Nucl. Technol. 49, 253 (1980).
4. Allard, G., Torstenfelt, B., Andersson, K., Rydberg, J.: Possible Retention of Iodine in the Ground. In: Material Research Society Symposium Proceedings, Material Research Society, Pittsburgh, Pennsylvania (1981) Vol. 176, pp. 673-680.
5. Huie, Z., Jishu, Z., Lanying, Z.: Sorption of radionuclides technetium and iodine on minerals. Radiochim. Acta 44/45, 143 (1988).
6. Rancon, D.: Comparative study of radioiodine behavior in soils under various experimental and natural conditions. Radiochim. Acta 88, 187 (1988).
7. 129I waste management. Radiochim. Acta 65, 195 (1994).
8. Balsley, S. D., Brady, P. V., Krumhansl, J. M., Anderson, H. L.: Iodide retention by metal sulfide surfaces: cinnabar and chalcocite. Env. Sci. Technol. 30, 3025 (1997).
9. 4 Scavengers for Low Level Radioactive Waste Backfills. SAND95-2978. Sandia National Laboratories, Albuquerque, New Mexico (1997).
10. Balsley, S. D., Brady, P. V., Krumhansl, J. M., Anderson, H. L.: Anion scavengers for low-level radioactive waste repository backfills. J. Soil Contamination 7, 125 (1998).
11. 129I-Disposal Special Analysis. WSRC-TR-2000-00283, Rev. 0. Westinghouse Savannah River Company, Savannah River Site, Aiken, South Carolina (2000).
12. Atkins, M., Glasser, F. P.: Encapsulation of Radioiodine in Cementitious Waste forms. In: Material Research Society Symposium Proceedings. Material Research Society, Pittsburgh, Pennsylvania (1990) Vol. 176, pp. 15-22.
13. Couture, R. A., Seitz, M. G.: Sorption of anions of iodine by iron oxides and kaolinite. Nucl. Chem. Waste Management 4, 301 (1983).
14. Taylor, P.: A Review of Methods for Immobilizing Iodine-129 Arising from a Nuclear Fuel Cycle Plant, with Emphasis on Waste-Form Chemistry. AECL-10163, Atomic Energy Canada Ltd., Whiteshell Nuclear Research Establishment, Pinawa, Canada (1990).
15. 129I waste management. J. Nucl. Sci. Technol. 31, 620 (1994).
16. Hakem, N., Fourest, B., Guillaumont, R., Marmier, N.: Sorption of iodine and cesium on some mineral oxide colloids. Radiochim. Acta 74, 225 (1996).
17. Kaplan, D., Serne, R. J., Parker, K. E., Kutnyakov, I. V.: Iodide sorption to subsurface sediments and illitic minerals. Env. Sci. Technol. 34, 399 (2000).
18. - on Mg/A1 layered double hydroxide. Radiochim. Acta 85, 57 (1999).
19. Gradev, G. D.: Sorption of iodide ions on cationic forms of clinoptilolite. J. Radioanal. Nucl. Chem. 116, 341 (1987).
20. Bors, J.: Sorption of radioiodine in organo-clays and soils. Radiochim. Acta 51, 139 (1990).
21. Bors, J.: Sorption and desorption of radioiodine on organo-clays. Radiochim. Acta 58/59, 235 (1992).
22. Bors, J., Gorny, A., Dultz, S.: Studies on the interaction of radionuclides with organophilic clays. Radiochim. Acta 66/67, 309 (1994).
23. Bors, J., Gorny, A., Dultz, S.: Some factors affecting the interactions of organophilic clay minerals with radioiodine. Radiochim. Acta 74, 231 (1996).
24. Bors, J., Dultz, S., Gorny, A.: Sorption of iodide, cesium, and strontium on organophilic bentonite. Radiochim. Acta 82, 269 (1998).
25. 129I Wastes. In: Material Research Society Symposium Proceedings. Material Research Society, Pittsburgh, Pennsylvania (1995) Vol. 353, pp. 1037-1043.
26. Viani, B.: Assessing Materials ("Getters") to Immobilize or Retard the Transport of Techetium Through Engineered Barrier System at the Potential Yucca Mountain Nuclear Waste Repository. UCRL-ID-133596. Lawrence Livermore National Laboratory, Livermore, California (1999).
27. Fryxell, G. E., Liu, J., Hauser, A. A., Nie, Z., Ferris, K. F., Mattigod, S. V., Gong, M., Hallen, R. T.: Design and synthesis of selective mesoporous anion traps. Chem. Mater. 11, 2148 (1999).
28. Fryxell, G. E., Liu, J., Mattigod, S. V.: Self-assembled monolayers on mesoporous supports (SAMMS) - an innovative environmental sorbent. Mater. Technol. Adv. Perf. Mater. 14, 188 (1999).
29. Fryxell, G. E., Liu, J., Mattigod, S. V., Wang, L. Q., Gong, M., Hauser, T. A., Lin, Y., Ferris, K. F., Feng, X.: Environmental Applications of Interfacially-Modified Mesoporous Ceramics. In: Proceedings of the 101st National Meetings of the American Ceramic Society (1999).
30. Kemner, K. M., Feng, X., Liu, J., Fryxell, G. E., Wang, L. Q., Kim, A. Y., Gong, M., Mattigod, S. V.: Investigation of the local chemical interactions between Hg and self-assembled monolayers on mesoporous supports. J. Synchrotron Rad. 6, 633 (1999).
31. Liu, J., Fryxell, G. E., Mattigod, S. V., Gong, M., Nie, Z., Feng, X., Raymond, K. N.: Self-Assembled Monolayers on Mesoporous Support (SAMMS) Technology for Contaminant Removal and Stabilization. PNL-12006. Pacific Northwest National Laboratory, Richland, Washington (1998).
32. Liu, J., Fryxell, G. E., Mattigod, S. V., Zemanian, T. S., Shin, Y., Wang, L. Q.: Synthesis and applications of functionalized nanoporous materials for specific adsorption. Stud. Surf. Sci. Catal. 129, 729 (2000).
33. Mattigod, S. V., Feng, X., Fryxell, G. E., Liu, J., Gong, M., Ghormley, C., Baskran, S., Nie, Z., Klasson, K. T.: Mercury Separation from Concentrated Potassium Iodide/Iodine Leachate Using Self-Assembled Mercaptan on Mesoporous Silica Technology. PNNL-11714. Pacific Northwest National Laboratory, Richland, Washington (1997).
34. Mattigod, S. V., Liu, J., Fryxell, G. E., Baskaran, S., Gong, M., Nie, Z., Feng, X., Klasson, K. T.: Fabrication and Testing of Engineered Forms of Self Assembled Monolayers on Mesoporous Silica (SAMMS) Material. PNNL-12007. Pacific Northwest National Laboratory, Richland, Washington (1998).
35. Giles, C. H., MacEwan, T. H., Nakhwa, S. N., Smith, D.: Studies in adsorption. Part XI. A system of classification of adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. J. Chem. Soc. (London) 3973 (1960).
36. Giles, C. H., Smith, D., Huitson, A.: A general treatment and classification of the solute adsorption isotherm. J. Coll. Interface Sci. 47, 755 (1974).
37. Sposito, G.: The Surface Chemistry of Soils. Oxford University Press, New York (1984) p. 234.
38. Baes, C. F., Mesmer, R. E.: The Hydrolysis of Cations. John Wiley and Sons, New York (1976).
39. Smith, R. M., Martell, A. E.: Critical Stability Constants. Plenum Press, New York (1976).