New routes to transition metal-carbido species: Synthesis and characterization of the carbon-centered trigonal prismatic clusters [W 6CCl18]n- (n = 1, 2, 3)

Journal of the American Chemical Society

Volumn 125, Issue 38, 2003, Pages 11464-11465

  Welch, Eric J ^a   Crawford, Nathan R M ^a   Bergman, Robert G ^a   Long, Jeffrey R ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; CARBON; CARBON TETRACHLORIDE; METAL DERIVATIVE; TUNGSTEN;

ARTICLE; ATMOSPHERE; CHEMICAL STRUCTURE; CRYSTALLIZATION; OXIDATION; PHASE TRANSITION; REACTION ANALYSIS; REDUCTION; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0141757493     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja035962v     Document Type: Article

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13. 6: C, 17.71; H, 3.24; N, 1.25. Found: C, 18.08; H, 3.36; N, 1.07.
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23. DFT calculations (HCTH407/LANL2DZ) utilized: HPCCG's NWChem. A Computational Chemistry Package for Parallel Computers, version 4.5; PNNL: Richland, WA, 2003. See Supporting Information for details,
24. See ref 14b for another analysis of the bonding in this structure type.
25. 6: C, 10.23; H, 1.82; N, 0.70. Found: C, 10.35; H, 1.74; N, 0.73.
26. 6: C, 21.28; H, 3.41; N, 1.15. Found: C, 21.08; H, 3. 53; N, 1.11.
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