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(b) Sekiguchi, A.; Ishida, Y.; Kabe, Y.; Ichinohe, M. J. Am. Chem. Soc. 2002, 124, 8776.
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0036499893
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Bemdt, A.9
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9
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0037138633
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Compound 1 as a mixture of two stereoisomers (1:1) was prepared by the reaction of 3-bromo-1,2,3-tris(tri-tert-butylsilyl)cyclotrigermene with phenylacetylene. For halogen-substituted cyclotrigermenes, see: Sekiguchi, A.; Ishida, Y.; Fukaya, N.; Ichinohe, M.; Takagi, N.; Nagase, S. J. Am. Chem. Soc. 2002, 124, 1158.
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Sekiguchi, A.1
Ishida, Y.2
Fukaya, N.3
Ichinohe, M.4
Takagi, N.5
Nagase, S.6
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0000844613
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Lambert, J. B.; Zhang, S.; Stem, C. L.; Huffman, J. C. Science 1993, 260, 1917.
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0141492966
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note
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-, see the Supporting Information.
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12
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0141827654
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note
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w = 0.2235 for all data, 31382 reflections), GOF = 1.034.
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13
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0034602038
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The Ge⋯C interatomic distance in 5-mesityl-2-phenyl-1,4,5-tris(tri-tert-butylsilyl)-1,4,5-trigermabicyclo[2.1.0] pent-2-ene, which has a C=C double bond length of 1.357(4) Å, is ca. 3.2 Å, see: Fukaya, N.; Ichinohe, M.; Sekiguchi, A. Angew. Chem., Int. Ed. 2000, 39, 3881.
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Fukaya, N.1
Ichinohe, M.2
Sekiguchi, A.3
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14
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0006073669
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The calculations were carried out using the Gaussian 98 program with effective core potentials and double-ζ (DZ) basis sets on Ge and Si (Wadt, W. R.; Hay, P. J. J. Chem. Phys. 1985, 82, 284) augmented by d-type polarization functions (d exponents 0.255 (Ge), 0.310 (Si)), and 6-31G(d) basis set for C and H.
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Wadt, W.R.1
Hay, P.J.2
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16
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(b) Prakash, G. K. S.; Farnia, M.; Keyanian, S.; Olah, G. A.; Kuhn, H. J.; Schaffner, K. J. Am. Chem. Soc. 1987, 109, 911.
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Kuhn, H.J.5
Schaffner, K.6
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17
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0011083499
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The natural bond orbital analysis was performed at the NBO-B3LYP/6-31G(d)//B3LYP/DZd level of theory. Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899.
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Reed, A.E.1
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18
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0011190497
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The nucleus-independent chemical shift (NICS) was computed at GIAO-B3LYP/6-31G(d)//B3LYP/DZd level of theory. (a) Schleyer, P. v. R.; Maecker, C.; Dransfeld, A.; Jiao, H.; Nicolaas, J. R. v. E. H. J. Am. Chem. Soc. 1996, 118, 6317.
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Schleyer, P.V.R.1
Maecker, C.2
Dransfeld, A.3
Jiao, H.4
Nicolaas, J.R.V.E.H.5
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19
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0000662399
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(b) Schleyer, P. v. R.; Jiao, H.; Nicolaas, J. R. v. E. H.; Malkin, V. G.; Malkina, O. L. J. Am. Chem. Soc. 1997, 119, 12669.
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Schleyer, P.V.R.1
Jiao, H.2
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Malkin, V.G.4
Malkina, O.L.5
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20
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0041911106
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(a) Lösslein, W.; Pritzkow, H.; Schleyer, P. v. R.; Schmitz, L. R., Siebelt, W. Angew. Chem., Int. Ed. 2000, 39, 1276.
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Lösslein, W.1
Pritzkow, H.2
Schleyer, P.V.R.3
Schmitz, L.R.4
Siebelt, W.5
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21
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0034922345
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(b) Lösslein, W.; Pritzkow, H.; Schleyer, P. v. R.; Schmitz, L. R., Siebelt, W. Eur. J. Inorg. Chem. 2001, 1949.
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Lösslein, W.1
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Schleyer, P.V.R.3
Schmitz, L.R.4
Siebelt, W.5
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