Ag13OsO6: A silver oxide with interconnected icosahedral Ag134+ clusters and dispersed [OsO 6]4- octahedra

Angewandte Chemie - International Edition

Volumn 42, Issue 36, 2003, Pages 4322-4325

  Ahlert, Sascha ^a   Klein, Wilhelm ^a   Jepsen, Ove ^a   Gunnarsson, Olle ^a   Andersen, Ole Krogh ^a   Jansen, Martin ^a  

^a MAX PLANCK INSTITUT FÜR FESTKÖRPERFORSCHUNG   (Germany)

Author keywords

Cluster compounds; Molecular orbital theory; Osmium; Silver; Subvalent compounds

Indexed keywords

AGGLOMERATION; ATOMS; IONS;

CLUSTERS;

SILVER COMPOUNDS;

OSMIUM DERIVATIVE; OXYGEN DERIVATIVE; SILVER; SILVER DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; COVALENT BOND; CRYSTAL STRUCTURE; DISPERSION; ELECTRON; ENERGY; PRESSURE; REACTION ANALYSIS; SOLID STATE; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0141757431     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200351740     Document Type: Article

References (26)

1. C. Linke, M. Jansen, Z. Anorg. Allg. Chem. 1997, 623, 1441.
2. M. Jansen, Habilitationsschrift, Universiät Gießen, 1978.
3. M. Jansen, J. Less-Common Met. 1980, 76, 285.
4. M. Jansen, Angew. Chem. 1987, 99, 1136; Angew. Chem. Int. Ed. Engl. 1987, 26, 1098.
5. M. Jansen, Angew. Chem. 1987, 99, 1136; Angew. Chem. Int. Ed. Engl. 1987, 26, 1098.
6. C. Friebel, M. Jansen, Z. Naturforsch. B 1984, 39, 739.
7. B. U. Köhler, M. Jansen, W. Weppner, J. Solid State Chem. 1985, 57, 227.
8. P. Behrens, S. Aßmann, U. Bilow, C. Linke, M. Jansen, Z. Anorg. Allg. Chem. 1999, 625, 111.
9. G. Argay, F. Naray-Szabo, Acta Chim. Acad. Sci. Hung. 1966, 329.
10. W. Beesk, P. G. Jones, H. Rumpel, E. Schwarzmann, G. M. Sheldrick, J. Chem. Soc. Chem. Commun. 1981, 644.
11. C. Linke, M. Jansen, Inorg. Chem. 1994, 33, 2614.
12. M. Jansen, C. Linke, Angew. Chem. 1992, 104, 618; Angew. Chem. Int. Ed. Engl. 1992, 31, 653.
13. M. Jansen, C. Linke, Angew. Chem. 1992, 104, 618; Angew. Chem. Int. Ed. Engl. 1992, 31, 653.
14. M. Jansen, C. Linke, Z. Anorg. Allg. Chem. 1992, 616, 95.
15. H. G. von Schnering, K. Häusler, Rev. Chim. Miner. 1976, 13, 71.
16. M. Schreyer, M. Jansen, Angew. Chem. 2002, 114, 665; Angew. Chem. Int. Ed. 2002, 41, 643.
17. M. Schreyer, M. Jansen, Angew. Chem. 2002, 114, 665; Angew. Chem. Int. Ed. 2002, 41, 643.
18. 2 = 0.0650, GOF = 1.360. Further details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crys-data@fiz-karlsruhe.de), on quoting the depository number CSD-413193.
19. T. Betz, R. Hoppe, Z. Anorg. Allg. Chem. 1985, 524, 17.
20. K. E. Stitzer, M. D. Smith, H.-C. zur Loye, Solid State Sci. 2002, 4, 311.
21. a) J. A. A. Ketelaar, J. Chem. Phys. 1937, 5, 668;
22. b) E. Zintl, W. Hauke, Nature 1937, 139, 717;
23. c) D. P. Shoemaker, R. E. March, F. J. Ewing, L. Pauling, Acta Crystallogr. 1952, 5, 637.
24. d∼0.3 eV into a lower fourfold and an upper twofold degenerate band.
25. +0.24).
26. R. Dronskowski, P. E. Blöchl, J. Phys. Chem. 1993, 97, 8617.