A metal coordination polymer with hexagonal diamondoid (or Lonsdaleite) network topology

Crystal Growth and Design

Volumn 3, Issue 5, 2003, Pages 635-637

  Sreenivasulu, Bellam ^a   Vittal, Jagadese J ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; WATER;

ARCHITECTURE; ARTICLE; CRYSTAL STRUCTURE; CRYSTALLIZATION; EVAPORATION; HYDROGEN BOND; MOLECULAR DYNAMICS; PRECIPITATION; SOLID STATE;

EID: 0141739802     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg034052m     Document Type: Article

References (20)

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3. Batten, S. R. CrystEngComm 2001, 18, 1-7.
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5. Wuest, J. D. In Mesomolecules: From Molecules to Materials; Mendenhall, G. D., Greenberg, A., Liebman, J. F., Eds.; Chapman & Hall: New York, 1995; pp 107-131.
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8. The formulation of 1 is supported by analytical data (see Experimental Section) and TG data (Supporting Information). 1 forms light green microtubular crystals; however, they are not suitable for single-crystal intensity data collection. In the absence of a crystal structure, it is not proved that the two water molecules are bound to the metal atom.
9. 2, the model converged at R1 = 0.0417, wR2 = 0.147, and GOF = 1.046 for 2364 reflections with Fo > 2σ(Fo) and 177 parameters. The hydrogen bond parameters are N(1)-H(1) 0.81(4) Å, H(1)⋯O(2a) 2.09(4) Å, N(1)⋯O(2a) 2.844(4) Å and N(1)-H(1)⋯O(2) 155(3)° (where a refers to symmetry operator, y - 1/4, -x + 1/4, z + 7/4).
10. Wells, A. F. Further Studies of Three-dimensional Nets; ACA Monograph: Washington, DC, 1979; Vol. 8, p 10.
11. 2) net derived from S lattice complexes. For details see O'Keeffe, M.; Hyde, B. G. Crystal Structures I. Patterns and Symmetry; Mineralogical Society of America: Washington, DC, 1996; p 320.
12. Zawarotko, M. J. Chem. Commun. 2001, 1-9.
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14. Ranford, J. D.; Vittal, J. J.; Wu, D. Angew. Chem., Int. Ed. 1998, 37, 1114-1116.
15. Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. 1999, 38, 3498-3501.
16. Abourahma, H.; Moulton, B.; Kravtsoy, V.; Zawarotko, M. J. J. Am. Chem. Soc. 2002, 124, 9990-9991.
17. Spek, A. L. Acta Crystallogr. 1990, A46, C34.
18. 2, the model converged at R1 = 0.0434, wR2 = 0.0866, and GOF = 1.022 for 3613 reflections with Fo > 2σ(Fo) and 222 parameters. Relevant hydrogen bond parameters are O(4)-H(4a) 0.70(3) Å, 0(4)-H(4b) 0.69(3) Å, H(4a)⋯O(5) 2.11(4) Å, H(4b)⋯.O(3a) 2.13-(3) Å, O(4)⋯O(5) 2.812(4) Å, O(4)⋯O(3a) 2.818(3) Å, O(4)-H(4a)⋯O(5) 170(3)°, O(4)-H(4b)⋯O(3a) 174(3)°, N(1)-H(1) 0.89(3) Å, H(1)⋯O(2a) 2.56(3) Å, N(1)⋯O(2a) 3.237(3) Å and N(1)-H(1)⋯O(2a) 133(2)° (where O(3a) and O(2a) are related by symmetry operations x - 1, y, z, and 2 - x, 1 - y, 1 - z, respectively).
19. Vittal, J. J.; Yang, X. Cryst. Growth Des. 2002, 2, 259-262.
20. Steed, J. W. CrystEngComm 2003, 5, 169-179.