Solubility and solution structure of cellulose derivatives

Cellulose

Volumn 10, Issue 3, 2003, Pages 213-225

  Burchard, Walther ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DISSOLUTION; ENTHALPY; HYDROPHOBICITY; SOLUBILITY; SOLUTIONS; SOLVENTS;

CELLULOSE CHAINS;

CELLULOSE;

CELLULOSE; SOLUBILITY;

EID: 0141723650     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1025160620576     Document Type: Article

References (42)

1. Ballauff M. 1986. Phase equilibria in rod-like systems with flexible chain molecules. Macromolecules 19: 1366-1374.
2. Bethe H. 1935. Proc. Roy. Soc. (London) A150: 552.
3. Burchard W. 1965. Über die Abweichungen von der idealen Knäuelstatistik bei Amylose- und Cellulose-tricarbanilaten in einem θ-Lösungsmittel. Makromol. Chem. 88: 11-28.
4. Burchard W. 1983. Static and dynamic light scattering from branched polymers and biopolymers. Adv. Polym. Sci. 48: 1-124 (see pp. 85-92).
5. Burchard W. 1985. New aspects of polymer characterization by dynamic light scattering. Chimia 39: 10-18.
6. Burchard W. 1986. Theory of cyclic macromolecules. In: Semlyen J.A. (ed.) Cyclic Polymers. Elsevier, London and New York, pp. 43-64, Eq. 93.
7. Burchard W. and Schmidt M. 1979. The diffusion coefficient of branched poly(vinyl-acetate) and poly(vinylacetate) microgels measured by quasi-elastic light scattering. Ber. Bunsenges. Phys. Chem. 83: 388-391.
8. Burchard W. and Schulz L. 1989. Lösungsstruktur von Cellulose 2.5-Acetaten. Papier 43: 665-674.
9. Burchard W., Schmidt M. and Stockmayer W.H. 1980. Information on poly-dispersity and branching from combined quasi-elastic light scattering. Macromolecules 13: 1265-1272.
10. De Gennes P.-G. 1979. Scaling Concepts in Polymer Physics. Cornell University Press, Ithaca, NY.
11. Demeter J., Mormann W., Schmidt J. and Burchard W. 2003. Structure in solution of trimethylsilyl cellulose in dependence on the degree of substitution. Macromolecules (submitted).
12. Einstein A. 1905a. On the movement of small particles suspended in stationary liquids required by the molecular kinetics theory of heat. Ann. Phys. 17: 549-560.
13. Einstein A. 1905b. Eine neue Bestimmung der Moleküldimensionen. Ph.D. Thesis, ETH Zürich, Switzerland.
14. Engelskirchen K. 1987. Polysaccharidderivate. In: Bartl H. and Falbe J. (eds) Makromolekulare Stoffe, Houben-Weyl E20: 2047-2136.
15. Flory P.J. 1942. Thermodynamics of high polymer solutions. J. Chem. Phys. 10: 51-61.
16. Flory P.J. 1953. Principles of Polymer Chemistry. Cornell University Press, Ithaca, NY.
17. Flory P.J. 1956a. Statistical thermodynamics of semi-flexible chain molecules. Proc. Roy. Soc. (London) A 234: 60-73.
18. Flory P.J. 1956b. Phase equilibria in solutions of rod-like particles. Proc. Roy. Soc (London) A 234: 73-88.
19. Frank H.S. and Evans M.W. 1945. J. Chem. Phys. 13: 507.
20. Freed K.F. 1987. Renormalization Group Theory of Macromolecules. John Wiley, New York.
21. Gagnaire D., Saint-Germain J. and Vincedon M. 1983. NMR evidence of hydrogen bonds in cellulose solutions. J. Appl. Polym. Symp. 37: 261-275.
22. Huggins M.L. 1942. J. Phys. Chem. 46: 151.
23. Huglin M.B. 1972. Light Scattering from Polymer Solutions. Academic Press, London.
24. Kamide K. and Saito M. 1984. Effect of total degree of substitution on molecular parameters of cellulose acetate. Eur. Polym. J. 20: 903-914.
25. Kirkwood J.G. and Riseman J. The intrinsic viscosities and diffusion constants of flexible macromolecules in solution. J. Chem. Phys. 16: 565-573.
26. Klemm D., Heinze T.J., Philipp B. and Wagenknecht W. 1997. New approach to advanced polymers by selective functionalization. Acta Polym. 48: 277-297.
27. Klohr E. and Zugenmaier P. 1997. Polymer-solvent interaction of molecular dispersed and supramolecular structures of cellulose urethanes. Macromol. Symp. 120: 219-230.
28. Kötz J., Bogen I., Heinze U., Heinze T.J. and Klemm D. 1998. Colloidal properties of statistically, block-like and regio-selectively substituted carboxymethyl celluloses. Papier 52: 704-712.
29. Mann G., Kunze J., Loth F. and Fink H.-P. 1998. Cellulose ethers with a block-like distribution of the substituents by structure-selective derivatization of cellulose. Polymer 39: 3155-3165.
30. Mormann W. and Demeter J. 1999. Silylation of cellulose with hexamethyldisilazane in liquid ammonia. First examples of completely trimethylsilylated cellulose. Macromolecules 32: 1706-1710.
31. Mormann W. and Demeter J. 2000. Controlled desilation of cellulose with stoichiometric amounts of water in the presence of ammonia. Macromol. Chem. Phys. 201: 163-168.
32. Nerger D. 1978 Synthese und Eigenschaften von Pol(vinylacetate)-Mikrogelen und ihre Kopplung zu Radial-Blockcopolymeren und Netzwerken. Ph.D. Thesis, University of Freiburg, Germany.
33. Petzold D., Klemm D., Savin G. and Burchard W. 2003. Investigations on structure of regio-selectively functionalized celluloses in solution, examplified by 3-O-alkyl ethers and using light scattering. Cellulose (to be published).
34. Potthast A., Rosenau T., Buchner R., Roeder T., Ebner G., Bruglachner H., Sixta H. and Kosma P. 2002. The cellulose solvent N,N-dimethylacetaminide/lithium chloride revisited: The effect of water on physico-chemical properties and chemical stability. Cellulose 9: 41-53.
35. Rahn K., Heinze T.J., Schmidt J. and Burchard W. 2003. Structure and solubility in THF of cellulose tosylates of various degrees of substitution. Cellulose (manuscript in preparation).
36. Schmidt M., Nerger D. and Burchard W. 1979. Quasi-elastic light scattering on branched polymers: Part: I. Branched poly(vinylacetates) and poly(vinylacetate) microgels. Polymer 20: 582-588.
37. Schulz L. and Burchard W. 1993. Lösungsstruktur verschiedener Cellulose Derivate. Polysaccharidforschung, Ergebnisberichte 1987-1993, pp. 9-30.
38. Schulz L., Seger B. and Burchard W. 2000. Structures of cellulose in solution. Macromol. Chem. Phys. 201: 208-222.
39. Tanford C. 1973. The Hydrophobic Effect. Wiley, New York.
40. Wegner G. 1992. Photochemistry and photophysics of nanocomponents prepared from rod-like macromolecules by LB-technique. Mol. Cryst. Liq. Cryst. 216: 7-12.
41. Wenzel M., Burchard W. and Schätzel K. 1986. Dynamic light scattering from semidilute cellulose tri-carbanilate solutions. Polymer 27: 195-201.
42. Zugenmaier P. and Derleth Ch. 1998. Phase behavior, structure and properties of regio-selectively substituted cellulose derivatives in the liquid-crystalline state. ACS Symp. Ser. 688: 239-252.