The C2 selective nucleophilic substitution reactions of 2,3-epoxy alcohols mediated by trialkyl borates: The first endo-mode epoxide-opening reaction through an intramolecular metal chelate

Organic Letters

Volumn 5, Issue 10, 2003, Pages 1789-1791

  Sasaki, Minoru ^a   Tanino, Keiji ^a   Hirai, Atsushi ^a   Miyashita, Masaaki ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; BORIC ACID; EPOXIDE; METAL CHELATE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; REACTION ANALYSIS; RING OPENING; STRUCTURE ANALYSIS; SUBSTITUTION REACTION;

EID: 0141674890     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol034455f     Document Type: Article

References (25)

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25. Calculations were performed with the GAUSSIAN 98 program at the B3LYP/6-31G*//HF/3-21G level. For details, see the Supporting Information.