Homocalixpyridines: Ligands exhibiting high selectivity in extraction and sensor processes

Chemistry - A European Journal

Volumn 4, Issue 3, 1998, Pages 434-440

  Stephan, Holger ^a   Krüger Rambusch, Torsten ^a   Gloe, Rarsten ^a   Hasse, Wolfgang ^c   Ahlers, Benedikt ^c   Cammann, Karl ^c   Rissanen, Kari ^d   Brodesser, Gisela ^b   Vögtle, Fritz ^b  

^a DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

^b UNIVERSITY OF BONN   (Germany)

^c ICB Institut fur Chemo und Biosensorik GmbH   (Germany)

^d UNIVERSITY OF JYVÄSKYLÄ   (Finland)

Author keywords

Homocalixarenes; Host guest chemistry; Mercury; Molecular modeling; Silver

Indexed keywords

EID: 0141650257     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3765(19980310)4:3<434::aid-chem434>3.3.co;2-n     Document Type: Article

References (35)

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17. T. W. Bell, S. K. Sahni, in Inclusion compounds: Key Organic Host Systems (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol), Oxford University Press, Oxford-New York-Tokyo, 1991, pp. 325-390; T. Nabeshima, T. Inaba, T. Sagae, N. Furukawa, Tetrahedron Lett. 1990, 31, 3919-3922; Y. Okada, Y. Kasai, F. Ishii, J. Nishimura, J. Chem. Soc. Chem. Commun. 1993, 976-978; O. Heitzsch, K. Gloe, H. Stephan, E. Weber, Solvent Extr. Ion Exch. 1994, 12, 475-496; K. Matsumodo, M. Hashimoto, M. Toda, H. Tsukube, J. Chem. Soc. Perkin Trans 1 1995, 2497-2502; H. Sakamoto, S. Ito, M. Otomo, Chem. Lett. 1995, 37-38.
18. T. W. Bell, S. K. Sahni, in Inclusion compounds: Key Organic Host Systems (Eds.: J. L. Atwood, J. E. D. Davies, D. D. MacNicol), Oxford University Press, Oxford-New York-Tokyo, 1991, pp. 325-390; T. Nabeshima, T. Inaba, T. Sagae, N. Furukawa, Tetrahedron Lett. 1990, 31, 3919-3922; Y. Okada, Y. Kasai, F. Ishii, J. Nishimura, J. Chem. Soc. Chem. Commun. 1993, 976-978; O. Heitzsch, K. Gloe, H. Stephan, E. Weber, Solvent Extr. Ion Exch. 1994, 12, 475-496; K. Matsumodo, M. Hashimoto, M. Toda, H. Tsukube, J. Chem. Soc. Perkin Trans 1 1995, 2497-2502; H. Sakamoto, S. Ito, M. Otomo, Chem. Lett. 1995, 37-38.
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21. The stoichiometry of the extracted species in two-phase distributions were determined by multiple regression analysis of the experimental data with a modified Marquardt procedure. See M. Petrich, L. Beyer, K. Gloe, P. Mühl, Anal. Chim. Acta 1990, 228, 229-234.
22. The usefulness of the DFT method is proven by calculation of the ligands and comparison with the X-ray structure.
23. The calculation of the charge density of the pyridine nitrogen with the DFT method gave markedly higher values for 3 and 7 compared with 1.
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26. 2) and included in the final structure factor calculations, but were not refined. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100756. Copies of the data can be obtained free of charge on application to CCDC. 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336033; E-mail: deposit@ccdc.cam.ac.uk).
27. 4 anion connects two silver atoms. The bond lengths of Ag2-F24-Ag3 are 260 and 259 pm, respectively.
28. The result of a search at the Cambridge Structural Data Centre.
29. See also Ag-Ag distances in other silver complexes: K. Hirotsu, I. Miyahara, T. Higuchi, M. Toda, H. Tsukube, K. Matsumoto, Chem. Lett. 1992, 699-702; J. dc Mendoza, E. Mesa, X-C. Rodriguez-Ubis, P. Vázquez, F. Vögtle, P.-M. Windscheif, K. Rissanen, J.-M. Lehn, D. Lilienbaum, R. Ziessel, Angew, Chem. 1991, 103, 1365-1367; Angew. Chem. Int. Ed. Engl. 1991, 30, 1331-1333.
30. See also Ag-Ag distances in other silver complexes: K. Hirotsu, I. Miyahara, T. Higuchi, M. Toda, H. Tsukube, K. Matsumoto, Chem. Lett. 1992, 699-702; J. dc Mendoza, E. Mesa, X-C. Rodriguez-Ubis, P. Vázquez, F. Vögtle, P.-M. Windscheif, K. Rissanen, J.-M. Lehn, D. Lilienbaum, R. Ziessel, Angew, Chem. 1991, 103, 1365-1367; Angew. Chem. Int. Ed. Engl. 1991, 30, 1331-1333.
31. See also Ag-Ag distances in other silver complexes: K. Hirotsu, I. Miyahara, T. Higuchi, M. Toda, H. Tsukube, K. Matsumoto, Chem. Lett. 1992, 699-702; J. dc Mendoza, E. Mesa, X-C. Rodriguez-Ubis, P. Vázquez, F. Vögtle, P.-M. Windscheif, K. Rissanen, J.-M. Lehn, D. Lilienbaum, R. Ziessel, Angew, Chem. 1991, 103, 1365-1367; Angew. Chem. Int. Ed. Engl. 1991, 30, 1331-1333.
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