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Volumn 36, Issue 19, 2003, Pages 7027-7034

Selective and mild oxyfunctionalization of model polyolefins

Author keywords

[No Author keywords available]

Indexed keywords

FUNCTIONAL GROUPS; IMIDAZOLE; MANGANESETETRADICHLOROPHENYLPORPHYRIN ACETATE; OXIDANT; OXYFUNCTIONALIZATION; PHASE TRANSFER AGENTS; SQUALENE;

EID: 0141620382     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0347621     Document Type: Article
Times cited : (59)

References (65)
  • 39
    • 37049074605 scopus 로고
    • note
    • Previously, the formation of the active species has been observed by UV-vis spectroscopy and was reported to form only in the presence of a nitrogen base cocatalyst for most oxygen donors. Campestrini, S.; Furia, F. D.; Labat, G.; Novello, F. J. Chem. Soc., Perkin Trans. 2, 1994, 2175.
    • (1994) J. Chem. Soc., Perkin Trans. , vol.2 , pp. 2175
    • Campestrini, S.1    Furia, F.D.2    Labat, G.3    Novello, F.4
  • 44
    • 0141469260 scopus 로고    scopus 로고
    • U.S. Patent 5,700,878
    • Hucul, D. A.; Hahn, S. F. U.S. Patent 5,700,878, 1997.
    • (1997)
    • Hucul, D.A.1    Hahn, S.F.2
  • 55
    • 0141803345 scopus 로고    scopus 로고
    • note
    • The colored impurity can be reduced by passage through an alumina column.
  • 56
    • 0141692463 scopus 로고    scopus 로고
    • note
    • 13C NMR spectroscopy.
  • 57
    • 0141580906 scopus 로고    scopus 로고
    • note
    • Reactions were also performed in the absence of PEP to prove the new chemical shifts were not due to byproducts formed in the reaction.
  • 58
    • 0141804046 scopus 로고    scopus 로고
    • note
    • 1H NMR spectra. The standard deviation was calculated from these values and used as an estimate of the error for each sample.
  • 59
    • 0141692464 scopus 로고    scopus 로고
    • note
    • 3 and a longer relaxation delay time of 20 s; however, the carbonyl carbons could still not be distinguished.
  • 63
    • 0141468542 scopus 로고    scopus 로고
    • note
    • 0 > 0.25 and reactions performed at 50 °C resultued in products with a decreased number-average molecular weight and a broader PDI.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.