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60 product as an exclusive product remains a mystery. One can speculate however two possibilities: an equilibrium between the 1,2- and the 1,4-carbo-cupration product favors the latter, or the latter compound decomposes faster than the former to overcome unfavorable equilibrium constant.
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60H (16) was produced in a moderate yield. This experiment also supports the structural assignment.
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42
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0141576089
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The most obvious difference is found in the shorter C(3)-C(4) bond length (1.39 ̊)
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The most obvious difference is found in the shorter C(3)-C(4) bond length (1.39 ̊).
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46
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0141464448
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note
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70 cage.
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47
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