An efficient high-yield synthesis for perfluorinated tertiary alkyl amines

Journal of Fluorine Chemistry

Volumn 123, Issue 2, 2003, Pages 233-236

  Felling, Kyle W ^a   Lagow, Richard J ^a  

^a University of Texas at Austin   (United States)

Author keywords

Direct fluorination; Perfluorinated amines; Perfluoro N,N,N ,N tetramethylethylenediamine; Perfluorotri n pentylamine; Perfluorotri n butylamine; Perfluorotri n propylamine; Perfluorotriethylamine

Indexed keywords

ALIPHATIC AMINE; HYDROCARBON; PERFLUORO COMPOUND; TERTIARY ALKYL GROUP; TERTIARY AMINE;

ARTICLE; CHEMICAL REACTION; CONTROLLED STUDY; FLUORINATION; METHODOLOGY; PURIFICATION; SYNTHESIS;

EID: 0141613588     PISSN: 00221139     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-1139(03)00146-5     Document Type: Article

References (15)

1. Simons J.H. J. Electrochem. Soc. 95 1949 47-67
2. Furin G.G. Cambaretto C. Direct Fluorination of Organic Compounds, Padova, CLEUP, 1996, p. 40.
3. Adcock J.L. Evans W.D. J. Org. Chem. 49 1984 2719-2723
4. Lagow R.J. Margrave J.L. Direct fluorination: a "new" approach to fluorine chemistry, in: S.J. Lippard (Ed.), Progress in Inorganic Chemistry, Wiley/Interscience, New York, 1979, pp. 161-210.
5. Ishikawa N. (Ed.), Fluorine Compounds, Modern Technology and Application, Mir, Moscow, 1984, p. 592.
6. Clark L.C. Wesseler E.P. Kaplan S. Emory C. Moore R. Denson D. Intravenous infusion of cis-trans perfluorodecalin emulsions in the rhesus monkey, in: R. Filler (Ed.), Biochemistry Involving Carbon-Fluorine Bonds, vol. 28, American Chemical Society Symposium Series, Washington, DC, 1976.
7. Banks R.E. Barlow M.G. Fluorocarbon and Related Chemistry, vol. 2, The Chemical Society, London, 1974, pp. 98-99.
8. Denson D.D. Uyeno E.T. Simon R.L. Jr. Peters H.M. Preparation and physiological evaluation of some new fluorinated volatile anesthetics, in: R. Filler (Ed.), Biochemistry Involving Carbon-Fluorine Bonds, vol. 28, American Chemical Society Symposium Series, Washington, DC, 1976.
9. Chambers R.D. Fluorine in Organic Chemistry, Wiley, New York, 1973.
10. Moldavskii D.D. Bispen T.A. Kaurova G.I. Furin G.G. J. Fluorine Chem. 94 1999 157-167
11. Dimitrov A. Pfeifer D. Jonethal U. Seppelt K. J. Fluorine Chem. 82 1997 143-150
12. Huang H. Persico D.F. Lagow R.J. J. Org. Chem. 53 1988 78-85
13. Velayutham D. Jayaraman K. Noel M. Krishnamoorthy S. Sartori P. J. Fluorine Chem. 115 2002 21-26
14. Bierschenk T.R. Juhlke T.J. Lagow R.J. Kawa H. US Patent 5,093,432 (1992).
15. Lagow R.J. Bierschenk T.R. Juhlke T.J. J. Am. Chem. Soc. 103 1981 7340