Novel pyridine-catalyzed reaction of dimethyl acetylenedicarboxylate with aldehydes and N-tosylimines: Efficient synthesis of 2-benzoylfumarates and 1-azadienes

Synthesis

Volumn , Issue 12, 2003, Pages 1895-1902

  Nair, Vijay ^a   Sreekanth, A R ^a   Abhilash, N ^a   Biju, A T ^a   Rema Devi, B ^a   Menon, Rajeev S ^a   Rath, Nigam P ^b   Srinivas, R ^c  

^a REGIONAL RESEARCH LABORATORY CSIR   (India)

^b UNIVERSITY OF MISSOURI ST LOUIS   (United States)

^c INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

1,4 Dipolar cycloadditions; Aldehyde; Dimethyl acetylenedicarboxylate; Nucleophilic additions; Pyridine

Indexed keywords

CATALYSIS; CONDENSATION; NITROGEN COMPOUNDS; SUBSTITUTION REACTIONS;

FACILE SYNTHESIS;

SYNTHESIS (CHEMICAL);

1 AZADIENE; 2 BENZOYLFUMARATE; ACETYLENEDICARBOXYLIC ACID DIMETHYL ESTER; ALDEHYDE; ALKADIENE; DICARBOXYLIC ACID; FUMARIC ACID DERIVATIVE; N TOSYLIMINE; OXAZINE DERIVATIVE; PYRIDINE DERIVATIVE; SPIROPYRIDO[2,1 B][1,3]OXAZINO DERIVATIVE; TOLUENESULFONIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; ELIMINATION REACTION; POLYMERIZATION; REACTION ANALYSIS; SYNTHESIS;

EID: 0141519416     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-41000     Document Type: Article

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