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Volumn 5, Issue 13, 2003, Pages 2203-2206

A transient N-O-linked Pauson-Khand strategy for the synthesis of the deschloro carbocyclic core of the palau'amines and styloguanidines

Author keywords

[No Author keywords available]

Indexed keywords

AMINE; CHLORINE DERIVATIVE; GUANIDINE DERIVATIVE;

EID: 0141518620     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0344063     Document Type: Article
Times cited : (54)

References (39)
  • 28
    • 0141439722 scopus 로고    scopus 로고
    • Doctoral dissertation, Yale University, New Haven, Connecticut
    • Koenig, S. G. Doctoral dissertation, Yale University, New Haven, Connecticut, 2002.
    • (2002)
    • Koenig, S.G.1
  • 32
    • 0141439724 scopus 로고    scopus 로고
    • note
    • Stereochemistry of the major diastereomer was assigned as 18a on the basis of a NOE analysis of its subsequent ketone derivative 20 (see Supporting Information).
  • 34
    • 0141439723 scopus 로고    scopus 로고
    • note
    • Although the diastereomeric mixture (18a,b) was separated for compound characterization (see Supporting Information), 18 was used in subsequent reactions as a mixture of diastereomers. However, only one diastereomer was isolated from each of the transformations (18→19 and 18→20) and the products 19 and 20 correspond to that of the major diastereomer 18a. For this reason, the diastereochemistry of 18 is depicted as that corresponding to the major diastereomer 18a.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.