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For complexes previously prepared in our laboratories, the chemical shift of H2 has consistently appeared more upfield for the major ct isomer than for the corresponding minor β isomer (see Table S1, Supporting Information). The syn axial stereochemical assignments are based on the chemical shifts of the dithiane methine; the syn diastereomers (i.e., general type C in Figure 1) show a significant downfield shift. For a related example, see Kamikawa, K.; Tachibana, A.; Sugimoto, S.; Uemura, M. Org. Lett. 2001, 3, 2033.
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0141601958
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note
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For thiophene analogues, see Supporting Information.
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15
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0031585045
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0141713720
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note
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See Supporting Information.
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