Diastereoselective cyclization in chiral diarylethene crystals: Polymorphism and selectivity

Organic Letters

Volumn 5, Issue 10, 2003, Pages 1769-1772

  Yamamoto, Satoshi ^a   Matsuda, Kenji ^a   Irie, Masahiro ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1 (2 METHYL 5 PHENYL 3 THIENYL) 2 [2 METHYL 5 [4 (3 METHYL 1 PENTEN 1 YL)PHENYL] 3 THIENYL]PERFLUOROCYCLOPENTENE; CYCLOPENTENE DERIVATIVE; ETHYLENE DERIVATIVE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CHIRALITY; CRYSTAL STRUCTURE; CRYSTALLIZATION; DIASTEREOISOMER; PHOTOCHEMISTRY; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0141518144     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol034440h     Document Type: Article

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24. For details of the synthesis, see Supporting Information.
25. 2: C, 65.76; H, 4.68. Found: C, 65.79; H, 4.75.
26. max (ε) 586 (20 000), 344 (27 000).
27. 2 (all data) = 0.0833, χ = -0.02(5).
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29. 2 (all data) = 0.2971, χ = -0.09(16).
30. We obtained the (S,S,S)-1b crystal by separating the closed-ring isomer photogenerated in solution. The result of the X-ray crystallography is shown in Supporting Information.
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