Kinetics and mechanism of oxidation of dimethyl sulphoxide by mono- and di-substituted N,N-dichlorobenzenesulphonamides in aqueous acetic acid

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Volumn 58, Issue 8, 2003, Pages 787-794

  Gowda, B Thimme ^a   Jayalakshmi, K L ^a   Jyothi, K ^a  

^a MANGALORE UNIVERSITY   (India)

Author keywords

Dimethyl Sulphoxide; Kinetics; N,N Dichloroarylsulphonamides; Oxidation

Indexed keywords

ACETIC ACID; ACTIVATION ENERGY; BENZENE; CHLORINE COMPOUNDS; DIMETHYL SULFOXIDE; ENZYME KINETICS; IONIC STRENGTH; KINETICS; OXIDANTS; PH; RADIOACTIVITY LOGGING; SOLVENTS;

AQUEOUS ACETIC ACID; ELECTRON WITHDRAWING GROUP; ENERGY OF ACTIVATION; FIRST ORDER KINETICS; ISO-KINETIC TEMPERATURE; KINETICS AND MECHANISM; KINETICS OF OXIDATION; SUBSTITUENT EFFECT;

OXIDATION;

ACETIC ACID; BENZENE; CHLORIDE ION; DIMETHYL SULFOXIDE; N,N DICHLORO 4 METHYLBENZENESULFONAMIDE; N,N DICHLOROBENZENESULFONAMIDE; OXIDIZING AGENT; REAGENT; SULFONAMIDE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL REACTION KINETICS; CORRELATION ANALYSIS; DIELECTRIC CONSTANT; DRUG EFFICACY; DRUG OXIDATION; DRUG SYNTHESIS; ELECTRON; ENERGY; ENTHALPY; IONIC STRENGTH; MATHEMATICAL ANALYSIS; REACTION ANALYSIS; SUBSTITUTION REACTION; TEMPERATURE; THERMODYNAMICS; VALIDATION PROCESS;

EID: 0141506021     PISSN: 09320776     EISSN: None     Source Type: Journal    
DOI: 10.1515/znb-2003-0811     Document Type: Article

References (23)

1. S. R. Sandler, W. Karo, Organic Functional Group Preparations, Vol. 3, Academic Press, London (1972).
2. M. M. Campbell, G. Johnson, Chem. Rev. 78, 65 (1978).
3. B. T. Gowda, D. S. Mahadevappa, Talanta 30, 359 (1983).
4. B. T. Gowda, D. S. Mahadevappa, J. Chem. Soc., Perkin Trans. 2 (1983) 323.
5. B. T. Gowda, B. S. Sherigara, D. S. Mahadevappa, Microchem. J. 34, 103 (1986).
6. M. C. Agrawal, S. K. Upadhyay, J. Sci. Ind. Res. 49, 13 (1990).
7. B. T. Gowda, A. Weiss, Z. Naturforsch. 49a, 695 (1994).
8. B. T. Gowda, S. Dou, A. Weiss, Z. Naturforsch. 51a, 627 (1996).
9. B. T. Gowda, D. K. Bhat, H. Fuess, A. Weiss, Z. Naturforsch. 54a, 261, 679 (1999).
10. B. T. Gowda, H. Paulus, H. Fuess, Z. Naturforsch. 55a, 711,791(2000); 56a, 386 (2001).
11. B. T. Gowda, H. Paulus, H. Fuess, Z. Naturforsch. 55a, 711,791(2000); 56a, 386 (2001).
12. B. T. Gowda, B. H. A. Kumar, H. Fuess, Z. Naturforsch. 55a, 721 (2000).
13. B. T. Gowda, K. Jyothi, J. D. D'Souza, Z. Naturforsch. 57a, 967 (2002).
14. B. T. Gowda, J. D. D'Souza, B. H. A. Kumar, Z. Naturforsch. 58a, 51 (2003).
15. B. T. Gowda, K. Jyothi, N. Damodara, Z. Naturforsch. 58a, xxx (2003).
16. R. K. Mohanty, M. Das, A. K. Das, Trans. Met. Chem., Chapman & Hall, London, 22, 487 (1997).
17. D. Oliveria, A. Lewis, E. H. Jona, Inorg. Nucl. Chem. Lett., 12, 195 (1976).
18. S. V. Rao, V. Jagannadhan, Indian J. Chem. 27A, 252 (1988).
19. Y. Ogata, T. Kazushige, Can. J. Chem. 59, 718 (1981).
20. B. T. Gowda, P. V. V. Nambiar, J. D. D'Souza, J. Indian Chem. Soc. 78, 273 (2001).
21. N. Damodara, K. Jyothi, B. T. Gowda, Oxid. Commun. 27, (2003).
22. B. T. Gowda, D. S. Mahadevappa, Microchem. J. 28, 374 (1983).
23. E. Stahl, Thin Layer Chromatography. A Laboratory Hand Book, Springer, New York (1969).