Gas-solid equilibrium in mixtures containing supercritical CO2 using a modified regular solution model

Industrial and Engineering Chemistry Research

Volumn 42, Issue 16, 2003, Pages 3857-3864

  Valderrama, José O ^a,b   González, Nelson A ^a   Alvarez, Victor H ^b  

^a DEPARTAMENTO DE BIOLOGÍA   (Chile)

^b Center for Technological Information CIT   (Chile)

Author keywords

[No Author keywords available]

Indexed keywords

BINARY MIXTURES; CARBON DIOXIDE; CONCENTRATION (PROCESS); EQUATIONS OF STATE OF GASES; GIBBS FREE ENERGY; HYDROGEN BONDS; PHASE EQUILIBRIA; SUPERCRITICAL FLUIDS;

POLAR SOLUTIONS;

CHEMICAL ENGINEERING;

2,3 DIMETHYLNAPHTHALENE; 2,6 DIMETHYLNAPHTHALENE; ANTHRACENE; BENZOIC ACID; CAFFEINE; CARBON DIOXIDE; CHOLESTEROL; NAPHTHALENE DERIVATIVE; PHENANTHRENE; PYRENE; UNCLASSIFIED DRUG;

EQUILIBRIUM; GAS-SOLID MIXING; MATHEMATICAL ANALYSIS; MODELING; SOLUTION (CHEMICAL); SUPERCRITICAL CARBON DIOXIDE;

ARTICLE; CONCENTRATION RESPONSE; ENERGY; HYDROGEN BOND; MATHEMATICAL MODEL; MOLECULAR INTERACTION; PHASE SEPARATION; SUPERCRITICAL FLUID;

EID: 0043271095     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020797y     Document Type: Article

References (44)

1. Soave, G. Equilibrium Constants from a Modified Redlich-Kwong Equation of State. Chem. Eng. Sci. 1972, 27, 1197-1203.
2. Peng, D. Y.; Robinson, D. B. A New Two-Constant Equation of State. Ind. Eng. Chem. Fundam. 1976, 15 (1), 59-64.
3. Valderrama, J. O. A Generalized Patel-Teja Equation of State for Polar and Nonpolar Fluids and Mixtures. J. Chem. Eng. Jpn. 1990, 23 (1), 87-91.
4. Wilson, G. M. Calculation of Enthalpy and Data from a Modified Redlich-Kwong Equation of State. Adv. Cryog. Eng. 1966, 11, 392-400.
5. Mihajlov, A.; Djordjevic, B.; Tasic, A. Calculation of Enthalpy and Entropy of Gases by Modified R. K. Equation of State. Hung. J. Ind. Chem. 1981, 9, 407-416.
6. Trebble, M. A.; Bishnoi, P. R. Accuracy and Consistency Comparisons of Ten Cubic Equations of State for Polar and Non-Polar Compounds. Fluid Phase Equilib. 1986, 29, 465-474.
7. Danesh, A.; Xu, D.; Todd, A. C. Comparative Study of Cubic Equations of State for Predicting Phase Behavior and Volumetric Properties of Injection Gas-Reservoir Oil Systems. Fluid Phase Equilib. 1991, 63, 259-278.
8. Zudkevitch, D.; Joffe, J. Correlation and Prediction of Vapor-Liquid Equilibria with the Redlich-Kwong Equation of State. AIChE J. 1970, 16 (1) 112-119.
9. Adachi, Y.; Lu, B. C. Y.; Sugie, H. Development of van der Waals type of Equations of State. J. Chem. Eng. Jpn. 1985, 18 (1), 20-25.
10. Trebble, M. A. Correlation of VLE Data for Binary Mixtures of 1-Alkanols and Normal Hexane with the Trebble-Bishnoi Equation of State. Fluid Phase Equilib. 1988, 42, 117-128.
11. Shibata, S.; Sandler, S. Critical Evaluation of Equation of State Mixing Rules for the Prediction of High-Pressure Phase Equilibria. Ind. Eng. Chem. Res. 1989, 28 (12), 1893-1898.
12. Kwak, T. Y.; Mansoori, G. A. Van der Waals Mixing Rules for Cubic Equations of State. Applications for Supercritical Fluid Extraction Modeling. Chem. Eng. Sci. 1986, 41 (5), 1303-1309.
13. Trebble, M. A.; Bishnoi, P. R. Extension of the Trebble-Bishnoi Equation of State to Fluid Mixtures. Fluid Phase Equilib. 1988, 40, 1-21.
14. Heyen, G. A Cubic Equation of State with Extended Range of Application. In Chemical Engineering Thermodynamics; Newman, S. A., Ed.; Ann Arbor Science Publishers: Ann Arbor, MI, 1983; p 175.
15. Huron, M. J.; Vidal, J. New Mixing Rules in Simple Equations of State for Representing Vapor-Liquid Equilibria of Strongly Non-Ideal Solutions. Fluid Phase Equilib. 1979, 3, 255-271.
16. Panagiotopoulos, A. Z.; Reid, R. C. A New Mixing Rule for Cubic Equations of State for Highly Polar, Asymmetric System. Presented at the 189th American Chemical Society Meeting, Miami Beach, FL, Apr 29-May 3, 1985.
17. Stryjek, R.; Vera, J. H. PRSV: An Improved Peng-Robinson Equation of State with New Mixing Rules for Strongly Nonideal Mixtures. Can. J. Chem. Eng. 1986, 64, 334-340.
18. Adachi, Y.; Sugie, H. A New Mixing Rule. Modified Conventional Mixing Rule. Fluid Phase Equilib. 1986, 23, 103-118.
19. Valderrama, J. O.; Vargas, D.; Arce, P. F.; Aznar, M. A General Non-Quadratic Mixing Rule and its Application to Mixtures which Contain a Supercritical Fluid. 6° World Congress of Chemical Engineering, Melbourne, Australia, September 2001.
20. Ewald, A. H.; Jepson, W. B.; Rowlinson, J. S. The Solubility of Solids in Gases. Discuss. Faraday Soc. 1953, 15, 238.
21. Kurnik R. T.; Holla, S. J.; Reid, R. C. Solubility of Solids in Supercritical Carbon Dioxide and Ethylene. J. Chem. Eng. Data 1981, 26 (1), 47-51.
22. Hess, B. S. Supercritical Fluids: Measurement and Correlation Studies of Model Coal Compound Solubility and the Modeling of Solid-Liquid-Fluid Equilibria. Ph.D. Thesis, University of Illinois, Urbana, IL, 1987.
23. Caballero, A. C.; Hernandez, L. N.; Estevez, L. A. Calculation of Interaction Parameters for Binary Solid-SCF Equilibria Using Several EoS and Mixing Rules. J. Supercrit. Fluids 1992, 5, 283-295.
24. Walas, S. M. Phase Equilibria in Chemical Engineering; Butterworth Publishing: Stoneham, MA, 1985.
25. Prausnitz, J. M.; Lichtenthaler, R. N.; Gomes de Azevedo, E. Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed.; Prentice Hall Inc.: Englewood Cliffs, NJ, 1999.
26. Kurihara, K.; Tochigi, K.; Kojima, K. Mixing Rule Containing Regular Solution and Residual Excess Free Energy. J. Chem. Eng. Jpn. 1987, 20 (3) 227-231.
27. Michelsen, M. L.; Kistenmacher, H. On Composition-Dependent Interaction Coefficients. Fluid Phase Equilib. 1990, 58 (1-2), 229-230.
28. Martin, R. A.; Hoy, K. L. Tables of Solubility Parameters; Research and Development Department, Union Carbide: Tarrytown, NY, 1975.
29. Arai, T.; Nishiumi, H. Correlation of the Binary Interaction Parameter of the Peng-Robinson Equation of State; Bulletin of the College of Engineering; Hosei University, 1987; Vol. 20, pp 1-20.
30. Graboski, M. S.; Daubert, T. E. A Modified Soave Equation of State for Phase Equilibrium Calculations. 3. Systems Containing Hydrogen. Ind. Eng. Chem. Process Des. Dev. 1979, 18 (2), 300-306.
31. 2/hydrocarbons using SRK Equation of State. Fluid Phase Equilib. 1994, 102, 31-60.
32. Reilly, M. Computer Programs for Chemical Engineering Education; Sterling Swift: TX, 1972; Vol. 2, pp 276-295.
33. Valderrama J. O.; Arce, P. F. The Isofugacity Criterion to Determine Interaction Parameters in Equations of State. In Proceedings EQUIFASE Congress; Tojo, J., Arce, A., Eds.; Solucion's Publishers: Vigo, Spain, 1999; p 301.
34. 2. In Computers Applied to the Process Industry; Valderrama, J. O., Rojas, C. J., Eds.; Editorial del Norte: La Serena, Chile, 2001; p 322.
35. 2 Extraction to Microalgae and Plants. J. Chem. Technol. Biotechnol. 1995, 62, 53-59.
36. Daubert, T. E.; Danner, R. P.; Sibul, H. M.; Stebbins, C. C. Physical and Thermodynamic Properties of Pure Chemicals. Data Compilation; Taylor & Francis: London, UK, 1996.
37. Xu, G.; Scurto, A. M.; Castier, M.; Brennecke, J. F.; Stadtherr, M. A. Reliable Computation of High-Pressure Solid-Fluid Equilibrium. Ind. Eng. Chem. Res. 2000, 39, 1624-1636.
38. Weast, R.; Astle, M., Editors. CRC Handbook of Chemistry and Physics, 63rd ed.; CRC Press Inc.: Boca Raton, FL, 1982.
39. Singh, H.; Jimmy Yun, S. L.; Macnaughton, S. J.; Tomasko, D. L.; Foster, N. R. Solubility of Cholesterol in Supercritical Ethane and Binary gas Mixtures Containing Ethane. Ind. Eng. Chem. Res. 1993, 32, 2841-2848.
40. th ed.; The McGraw-Gill Company: New York, 2001.
41. Johannsen, M.; Brunner, G. Solubilities of the Xanthines Caffeine, Theophylline and Theobromine in Supercritical Carbon Dioxide. Fluid Phase Equilib. 1994, 95, 215-226.
42. Yun, S. L. J.; Liong, K. K.; Gurdial, G. S.; Foster, N. R. Solubility of Cholesterol in Supercritical Carbon Dioxide. Ind. Eng. Chem. Res. 1991, 30 (11), 2476-2482.
43. Johnston, K. P.; Ziger, D. H.; Eckert, C. A. Solubilities of Hydrocarbon Solids in Supercritical Fluids. The Augmented van der Waals Treatment. Ind. Eng. Chem. Fundam. 1982, 21 (3), 191-197.
44. Newman, S. A.; Ed. Chemical Engineering Thermodynamics; Ann Arbor Science Publishers: Ann Arbor, MI, 1983.