Allosteric manipulation of photoexcited state relaxation in a series of RuII(bpy)2(bipyridine-crown ethers)

European Journal of Inorganic Chemistry

Volumn , Issue 15, 2003, Pages 2812-2819

  Dutta, Subodh K ^a   Gan, Daqing ^a   Perkovic, Marc W ^a  

^a WESTERN MICHIGAN UNIVERSITY   (United States)

Author keywords

Lead; Luminescence; Photophysics; Sensors

Indexed keywords

CROWN ETHERS; ETHERS; HEAVY METALS; INDIUM COMPOUNDS; LIGANDS; METAL IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM COMPOUNDS; X RAY CRYSTALLOGRAPHY;

BIPYRIDINES; CROWN-ETHERS; HEAVY METAL ION; LEAD; LUMINESCENT SENSORS; PHOTOEXCITED STATE; PHOTOPHYSICS; PYRIDINE RINGS; RU COMPLEXES; SPACE GROUPS;

LUMINESCENCE;

BIPYRIDINE DERIVATIVE; CROWN ETHER DERIVATIVE; LEAD; RUTHENIUM COMPLEX;

ALLOSTERISM; ARTICLE; COMPLEX FORMATION; CRYSTALLIZATION; LUMINESCENCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOSTIMULATION; SENSOR; X RAY CRYSTALLOGRAPHY;

EID: 0043237709     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200200654     Document Type: Article

References (28)

1. Portions of this manuscript were submitted in partial fulfillment for the degree of Master of Arts, Western Michigan University, 1999.
2. See the excellent series of reviews in: L. Fabbrizzi (Ed.). Coord. Chem. Rev. 2000, vol. 205, pp. 3-228.
3. A. W. Czarnick (Ed.), Fluorescent Chemosensors for Ion and Molecule Recognition; American Chemical Society: Washington DC, ACS Symposium Series 538, 1992.
4. A. P. de Silva, H. Q. Gunaratne, T. Gunnlaugsson, A. J. Huxley, C. P. McCoy, J. T. Rademacher, T. E. Rice, Chem. Rev. 1997, 97, 1515.
5. [5a] O. S. Wolfbeis (Ed.), Fiber Optic Chemical Sensors and Biosensors; CRC Press: Boca Raton, Florida, 1991, vol. I & II.
6. [5b] R. A. Bissell, A. P. de Silva, H. Q. N. Gunaratne, P. L. Lynch, G. E. M Maguire, C. P. McCoy, K. R. A. S. Sandanayake, Chem. Soc. Rev. 1992, 21, 187.
7. [5c] R. A. Bissell, A. P. de Silva, H. Q. N. Gunaratne, P. L. Lynch, G. E. M. Maguire, K. R. A. S. Sandanayake, Top. Curr. Chem. 1993, 168, 223.
8. [5d] A. P. de Silva, H. Q. Gunaratne, T. Gunnlaugsson, A. J. M. Huxley, C. P. McCoy, J. T. Rademacher, T. E. Rice, Adv. Supramol. Chem. 1997, 4, 127.
9. [6a] V. Balzani, F. Scandola, Supramolecular Photochemistry; Ellis-Horwood: Chichester, 1991.
10. [6b] V. Balzani, A. Credi, F. Scandola, "Supramolecular Photochemistry and Photophysics. Energy-Conversion and Information-Processing Devices Based on Transition Metal Complexes" in: Transition Metals in Supramolecular Chemistry (Eds.: L. Fabbrizzi, A. Poggi), Kluwer: Dorecht, 1994.
11. [6c] "Perspectives in Supramolecular Chemistry-from Molecular Recognition towards Molecular Information Processing and Self-Organization": J. M. Lehn, Angew. Chem. Int. Ed. Eng. 1990, 29, 1304.
12. [6d] L. Fabbrizzi, A. Poggi (Eds.), Transition metals in Supramolecular Chemistry; Kluwer: Dorecht, 1994.
13. M. H. Keefe, K. D. Benkenstein, J. T. Hupp, Coord. Chem. Rev. 2000, 205, 201.
14. [8a] W. Szulbinski, J. Kincaid, Inorg. Chem. 1998, 37, 859.
15. [8b] M. Sykora, J. Kincaid, Inorg. Chem. 1995, 34, 5852.
16. [8c] S. Bélanger, M. Gilbeertson, D. Yoon, C. Stern, X. Dang, J. Hupp, J. Chem. Soc., Dalton 1999, 19, 3407.
17. [8dl L. Fabrizzi, A. Poggi, Chem. Soc., Rev. 1995, 24, 197.
18. L. Fabrizzi, M. Licchelli, P. Pallavicini, D. Sacchi, A. Taglietti, Analyst 1996, 121, 1763.
19. M. W. Perkovic, Inorg. Chem. 2000, 39, 4962.
20. We have determined the X-ray structure of the four oxygen crown and calculated the geometry of the four, five and six oxygen crowns. In the solid state the four oxygen crown has an inter-pyridine angle of 87°. These results will be pubished elsewhere.
21. International Tables for X-ray Crystallography; Kynoch: Birmingham, 1965.
22. SIR92: A. Altomore, G. Casscarano, C. Giacovazzo, A. Guggliandi, M. C. Burla, G. Polidori, G. M. Camalli, J. Appl. Cryst. 1994, 27, 435.
23. G. Sheldrick, SHELXL-97 crystal structure refinement package, Unix release 97-2.
24. M. Chiba, K. Ogawa, K. Tsuge, M. Abe, H.-B. Kim, Y. Sasaki, N. Kitamura, Chem. Lett. 2001, 7, 692.
25. J. Rebek, T. Costello, L. Marshall, R. Watley, R. C. Gadwood, K. Onan, J. Am. Chem. Soc. 1985, 107, 7481.
26. S. V. Luis, J. C. Frías, M. I. Burguete, M. Bolte, Acta Crystallogr., Sect. C 1998, 54, 1093.
27. B. P. Sullivan, D. J. Salmon, T. J. Meyer, Inorg. Chem. 1978, 17, 3334.
28. J. Rebek Jr., J. E. Trend, R. V. Watley, A. Chakravorti, J. Am. Chem. Soc. 1979, 101, 4333.