Regioselectivity of Meisenheimer complexation in reaction of oxygen-centred nucleophiles with picryl aryl ethers: Polar vs. SET mechanisms

Canadian Journal of Chemistry

Volumn 81, Issue 6, 2003, Pages 443-456

  Buncel, Erwin ^a   Dust, Julian M ^b   Manderville, Richard A ^c   Tarkka, Richard M ^d  

^a QUEEN S UNIVERSITY   (Canada)

^b MEMORIAL UNIVERSITY OF NEWFOUNDLAND   (Canada)

^c WAKE FOREST UNIVERSITY   (United States)

^d UNIVERSITY OF CENTRAL ARKANSAS   (United States)

Author keywords

Anionic Meisenheimer adducts; FMO; Kinetic thermodynamic control; Regioselectivity; Single electron transfer (SET); Stereoelectronic stabilization

Indexed keywords

COMPLEXATION; ISOMERS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXYGEN; REACTION KINETICS; THERMODYNAMICS;

REGIOSELECTIVITY;

ETHERS;

ETHER DERIVATIVE; OXYGEN;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; DENSITY; ELECTRON TRANSPORT; LOW TEMPERATURE; MOLECULAR INTERACTION; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

EID: 0043236008     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v03-014     Document Type: Article

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