-
3
-
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84988137049
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M. Menges, R. Brückner, Synlett 1994, 809-813; M. Menges, R. Brückner, Liebigs Ann. 1995, 365-384; H. Priepke, R. Brückner, Liebigs Ann. 1997, 1645-1655; S. Weigand, R. Brückner, Liebigs Ann. 1997, 1657-1666; S. Allerheiligen, R. Brückner, Liebigs Ann. 1997, 1667-1676.
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(1994)
Synlett
, pp. 809-813
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-
Menges, M.1
Brückner, R.2
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4
-
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84988119534
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M. Menges, R. Brückner, Synlett 1994, 809-813; M. Menges, R. Brückner, Liebigs Ann. 1995, 365-384; H. Priepke, R. Brückner, Liebigs Ann. 1997, 1645-1655; S. Weigand, R. Brückner, Liebigs Ann. 1997, 1657-1666; S. Allerheiligen, R. Brückner, Liebigs Ann. 1997, 1667-1676.
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(1995)
Liebigs Ann.
, pp. 365-384
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-
Menges, M.1
Brückner, R.2
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5
-
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33748720666
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-
M. Menges, R. Brückner, Synlett 1994, 809-813; M. Menges, R. Brückner, Liebigs Ann. 1995, 365-384; H. Priepke, R. Brückner, Liebigs Ann. 1997, 1645-1655; S. Weigand, R. Brückner, Liebigs Ann. 1997, 1657-1666; S. Allerheiligen, R. Brückner, Liebigs Ann. 1997, 1667-1676.
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(1997)
Liebigs Ann.
, pp. 1645-1655
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-
Priepke, H.1
Brückner, R.2
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6
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33748734790
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M. Menges, R. Brückner, Synlett 1994, 809-813; M. Menges, R. Brückner, Liebigs Ann. 1995, 365-384; H. Priepke, R. Brückner, Liebigs Ann. 1997, 1645-1655; S. Weigand, R. Brückner, Liebigs Ann. 1997, 1657-1666; S. Allerheiligen, R. Brückner, Liebigs Ann. 1997, 1667-1676.
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(1997)
Liebigs Ann.
, pp. 1657-1666
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-
Weigand, S.1
Brückner, R.2
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7
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-
33748740116
-
-
M. Menges, R. Brückner, Synlett 1994, 809-813; M. Menges, R. Brückner, Liebigs Ann. 1995, 365-384; H. Priepke, R. Brückner, Liebigs Ann. 1997, 1645-1655; S. Weigand, R. Brückner, Liebigs Ann. 1997, 1657-1666; S. Allerheiligen, R. Brückner, Liebigs Ann. 1997, 1667-1676.
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(1997)
Liebigs Ann.
, pp. 1667-1676
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Allerheiligen, S.1
Brückner, R.2
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8
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0000811010
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J. S. Mynderse, R. E. Moore, Phytochemistry 1979, 18, 1181-1183; S. Carmeli, R. E. Moore, G. M. L. Patterson, Y. Mori, M. Suzuki, J. Org. Chem. 1990, 55, 4431-4438; Y. Mori, Y. Kohchi, M. Suzuki, S. Carmeli, R. E. Moore, G. M. L. Patterson, J. Org. Chem. 1991, 56, 631-637.
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Mynderse, J.S.1
Moore, R.E.2
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9
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0001600261
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J. S. Mynderse, R. E. Moore, Phytochemistry 1979, 18, 1181-1183; S. Carmeli, R. E. Moore, G. M. L. Patterson, Y. Mori, M. Suzuki, J. Org. Chem. 1990, 55, 4431-4438; Y. Mori, Y. Kohchi, M. Suzuki, S. Carmeli, R. E. Moore, G. M. L. Patterson, J. Org. Chem. 1991, 56, 631-637.
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J. Org. Chem.
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Carmeli, S.1
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Mori, Y.4
Suzuki, M.5
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10
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0000020581
-
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J. S. Mynderse, R. E. Moore, Phytochemistry 1979, 18, 1181-1183; S. Carmeli, R. E. Moore, G. M. L. Patterson, Y. Mori, M. Suzuki, J. Org. Chem. 1990, 55, 4431-4438; Y. Mori, Y. Kohchi, M. Suzuki, S. Carmeli, R. E. Moore, G. M. L. Patterson, J. Org. Chem. 1991, 56, 631-637.
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J. Org. Chem.
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Mori, Y.1
Kohchi, Y.2
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Carmeli, S.4
Moore, R.E.5
Patterson, G.M.L.6
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11
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0001525650
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Ed.: S. Omura, Academic Press, Inc., Orlando
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S. Omura, H. Tanaka in Macrolide Antibiotics, (Ed.: S. Omura), Academic Press, Inc., Orlando. 1984, pp. 351-404.
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, pp. 351-404
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Omura, S.1
Tanaka, H.2
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12
-
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0015185660
-
-
Isolation: R. Schlegel, R. Fugner, G. Bradler, H. Thrum, Z. Allg. Mikrobiol. 1971, 11, 661-670; stereostructure: S. D. Rychnovsky, G. Griegraber, R. Schlegel, J. Am. Chem. Soc. 1994, 116, 2623-2624; J. Am. Chem Soc 1995, 117, 197-210.
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-
Schlegel, R.1
Fugner, R.2
Bradler, G.3
Thrum, H.4
-
13
-
-
0028211625
-
-
Isolation: R. Schlegel, R. Fugner, G. Bradler, H. Thrum, Z. Allg. Mikrobiol. 1971, 11, 661-670; stereostructure: S. D. Rychnovsky, G. Griegraber, R. Schlegel, J. Am. Chem. Soc. 1994, 116, 2623-2624; J. Am. Chem Soc 1995, 117, 197-210.
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J. Am. Chem. Soc.
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-
Rychnovsky, S.D.1
Griegraber, G.2
Schlegel, R.3
-
14
-
-
0001052792
-
-
Isolation: R. Schlegel, R. Fugner, G. Bradler, H. Thrum, Z. Allg. Mikrobiol. 1971, 11, 661-670; stereostructure: S. D. Rychnovsky, G. Griegraber, R. Schlegel, J. Am. Chem. Soc. 1994, 116, 2623-2624; J. Am. Chem Soc 1995, 117, 197-210.
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(1995)
J. Am. Chem Soc
, vol.117
, pp. 197-210
-
-
-
15
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-
0022472782
-
-
Early synthetic efforts: B. H. Lipshutz, H. Kotsuki, W. Lew, Tetrahedron Lett. 1986, 27, 4825-4828; B. H. Lipshutz, R. Moretti, R. Crow, Tetrahedron Lett. 1989, 30, 15-18; S. D. Rychnovsky, G. Griegraber, R. Schlegel, J. Am. Chem. Soc. 1994, 116, 2621-2622.
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Tetrahedron Lett.
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-
-
Lipshutz, B.H.1
Kotsuki, H.2
Lew, W.3
-
16
-
-
0024593835
-
-
Early synthetic efforts: B. H. Lipshutz, H. Kotsuki, W. Lew, Tetrahedron Lett. 1986, 27, 4825-4828; B. H. Lipshutz, R. Moretti, R. Crow, Tetrahedron Lett. 1989, 30, 15-18; S. D. Rychnovsky, G. Griegraber, R. Schlegel, J. Am. Chem. Soc. 1994, 116, 2621-2622.
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(1989)
Tetrahedron Lett.
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-
-
Lipshutz, B.H.1
Moretti, R.2
Crow, R.3
-
17
-
-
0028353225
-
-
Early synthetic efforts: B. H. Lipshutz, H. Kotsuki, W. Lew, Tetrahedron Lett. 1986, 27, 4825-4828; B. H. Lipshutz, R. Moretti, R. Crow, Tetrahedron Lett. 1989, 30, 15-18; S. D. Rychnovsky, G. Griegraber, R. Schlegel, J. Am. Chem. Soc. 1994, 116, 2621-2622.
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(1994)
J. Am. Chem. Soc.
, vol.116
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-
-
Rychnovsky, S.D.1
Griegraber, G.2
Schlegel, R.3
-
18
-
-
0030928918
-
-
Total synthesis: S. D. Rychnovsky, U. R. Khire, G. Yang, J. Am. Chem. Soc. 1997, 119, 2058-2059.
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(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 2058-2059
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-
Rychnovsky, S.D.1
Khire, U.R.2
Yang, G.3
-
19
-
-
0001074831
-
-
Synthesis of 7 from L-glutamic acid: Step 1: U. Ravid, R. M. Silverstein, L. R. Smith, Tetrahedron 1978, 34, 1449-1452; step 2: C. Herdeis, Synthesis 1986, 232-233; step 3: S. Hanessian, P. J. Murray, Tetrahedron 1987, 43, 5055-5072; steps 4-8: S. Hanessian, S. P. Sahoo, P. J. Murray, Tetrahedron Lett. 1985, 76, 5631-5634.
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(1978)
Tetrahedron
, vol.34
, pp. 1449-1452
-
-
Ravid, U.1
Silverstein, R.M.2
Smith, L.R.3
-
20
-
-
0022577931
-
-
Synthesis of 7 from L-glutamic acid: Step 1: U. Ravid, R. M. Silverstein, L. R. Smith, Tetrahedron 1978, 34, 1449-1452; step 2: C. Herdeis, Synthesis 1986, 232-233; step 3: S. Hanessian, P. J. Murray, Tetrahedron 1987, 43, 5055-5072; steps 4-8: S. Hanessian, S. P. Sahoo, P. J. Murray, Tetrahedron Lett. 1985, 76, 5631-5634.
-
(1986)
Synthesis
, pp. 232-233
-
-
Herdeis, C.1
-
21
-
-
0000905924
-
-
Synthesis of 7 from L-glutamic acid: Step 1: U. Ravid, R. M. Silverstein, L. R. Smith, Tetrahedron 1978, 34, 1449-1452; step 2: C. Herdeis, Synthesis 1986, 232-233; step 3: S. Hanessian, P. J. Murray, Tetrahedron 1987, 43, 5055-5072; steps 4-8: S. Hanessian, S. P. Sahoo, P. J. Murray, Tetrahedron Lett. 1985, 76, 5631-5634.
-
(1987)
Tetrahedron
, vol.43
, pp. 5055-5072
-
-
Hanessian, S.1
Murray, P.J.2
-
22
-
-
1542535165
-
-
Synthesis of 7 from L-glutamic acid: Step 1: U. Ravid, R. M. Silverstein, L. R. Smith, Tetrahedron 1978, 34, 1449-1452; step 2: C. Herdeis, Synthesis 1986, 232-233; step 3: S. Hanessian, P. J. Murray, Tetrahedron 1987, 43, 5055-5072; steps 4-8: S. Hanessian, S. P. Sahoo, P. J. Murray, Tetrahedron Lett. 1985, 76, 5631-5634.
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(1985)
Tetrahedron Lett.
, vol.76
, pp. 5631-5634
-
-
Hanessian, S.1
Sahoo, S.P.2
Murray, P.J.3
-
23
-
-
33748725444
-
-
A 4-step sequence for the conversion of (S)-glycidol into the enantiomer of lactone 7 was described by ourselves: H. Priepke, S. Weigand, R. Bruckner, Liebigs Ann. 1997, 1635-1644. From (R)-glycidol, the same sequence would lead to 7.
-
(1997)
Liebigs Ann.
, pp. 1635-1644
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-
Priepke, H.1
Weigand, S.2
Bruckner, R.3
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24
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-
33751500471
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S. D. Rychnovsky, G. Griesgraber, S. Zeller, D. J. Skalitzky, J. Org. Chem. 1991, 56, 5161-5169.
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J. Org. Chem.
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Rychnovsky, S.D.1
Griesgraber, G.2
Zeller, S.3
Skalitzky, D.J.4
-
25
-
-
33751157286
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-
2(dppe) was obtained as described by H. Felkin, E. Jampel-Costa, G. Swierczewski, J. Organomet. Chem. 1977, 134, 265-279.
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(1994)
J. Org. Chem.
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Cai, D.1
Payack, J.F.2
Bender, D.R.3
Hughes, D.L.4
Verhoeven, T.R.5
Reider, P.J.6
-
26
-
-
1542449323
-
-
2(dppe) was obtained as described by H. Felkin, E. Jampel-Costa, G. Swierczewski, J. Organomet. Chem. 1977, 134, 265-279.
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(1977)
J. Organomet. Chem.
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Felkin, H.1
Jampel-Costa, E.2
Swierczewski, G.3
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27
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0001501146
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S. L. Schreiber, M. T. Goulet, G. Schulte, J. Am. Chem. Soc. 1987, 109, 4718-4720.
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J. Am. Chem. Soc.
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Schreiber, S.L.1
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28
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0022530439
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-
[14a] C. Greek, P. Grice, S. V. Ley, A. Wonnacott, Tetrahedron Lett. 1986, 27, 5277-5280.
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(1986)
Tetrahedron Lett.
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Greek, C.1
Grice, P.2
Ley, S.V.3
Wonnacott, A.4
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29
-
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0024377665
-
-
[14b] S. V. Ley, N. J. Anthony, A. Armstrong, M. G. Brasca, T. Clarke, D. Culshaw, C. Greek, P. Grice, A. B. Jones, B. Lygo, A. Madin. R. N. Sheppard, A. M. Z. Slawin, D. J. Williams, Tetrahedron 1989, 45, 7161-7194.
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(1989)
Tetrahedron
, vol.45
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-
Ley, S.V.1
Anthony, N.J.2
Armstrong, A.3
Brasca, M.G.4
Clarke, T.5
Culshaw, D.6
Greek, C.7
Grice, P.8
Jones, A.B.9
Lygo, B.10
Madin, A.11
Sheppard, R.N.12
Slawin, A.M.Z.13
Williams, D.J.14
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30
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-
85007739437
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D. Díez-Martín. P. Grice, H. C. Kolb, S. V. Ley, A. Madin, Synlett 1990, 326-328.
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(1990)
Synlett
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Díez-Martín, D.1
Grice, P.2
Kolb, H.C.3
Ley, S.V.4
Madin, A.5
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31
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0000471518
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Preparation of 2-bromo-1,5-hexadiene: P. E. Peterson, D. J. Nelson, R. Risener, J. Org. Chem 1986, 51, 2381-2382.
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(1986)
J. Org. Chem
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-
Peterson, P.E.1
Nelson, D.J.2
Risener, R.3
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32
-
-
0010843566
-
-
Method: M. T. Reetz, N. Harmat, R. Mahrwald, Angew. Chem. 1992, 104, 333-334; Angew. Chem., Int. Ed. Engl 1992, 31, 342-344.
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(1992)
Angew. Chem.
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-
Reetz, M.T.1
Harmat, N.2
Mahrwald, R.3
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33
-
-
33748888247
-
-
Method: M. T. Reetz, N. Harmat, R. Mahrwald, Angew. Chem. 1992, 104, 333-334; Angew. Chem., Int. Ed. Engl 1992, 31, 342-344.
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(1992)
Angew. Chem., Int. Ed. Engl
, vol.31
, pp. 342-344
-
-
-
34
-
-
2742599085
-
-
Preparation of 2-(tributylstannyl)-1,5-hexadiene: Ref.[10]
-
Preparation of 2-(tributylstannyl)-1,5-hexadiene: Ref.[10].
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-
-
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35
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0002714675
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W. C. Still, M. Kahn, A. Mitra, J. Org. Chem 1978, 43, 2923-2925.
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J. Org. Chem
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Still, W.C.1
Kahn, M.2
Mitra, A.3
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37
-
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0028212735
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-
Method: S.-K. Kang, J.-H. Jeon, K.-S. Nam, C.-H. Park, H.-W. Lee, Synth. Commun. 1994, 24, 305-312.
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(1994)
Synth. Commun.
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-
Kang, S.-K.1
Jeon, J.-H.2
Nam, K.-S.3
Park, C.-H.4
Lee, H.-W.5
-
38
-
-
2742525516
-
-
Method: Ref.[10]
-
Method: Ref.[10].
-
-
-
-
39
-
-
33845278140
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-
Method: D. A. Evans, K. T. Chapman, E. M. Carreira, J. Am. Chem. Soc. 1988, 110, 3560-3578.
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(1988)
J. Am. Chem. Soc.
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-
Evans, D.A.1
Chapman, K.T.2
Carreira, E.M.3
-
40
-
-
2742574927
-
-
Method: K. C. Nicolaou, E. A. Couladouros, P. G. Nantermet, J. Renaud, R. K. Guy, W. Wrasidlo, Angew. Chem. 1994, 106, 1669-1671; Angew. Chem., Int. Ed. Engl 1994, 33, 1581-1583.
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Angew. Chem.
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-
Nicolaou, K.C.1
Couladouros, E.A.2
Nantermet, P.G.3
Renaud, J.4
Guy, R.K.5
Wrasidlo, W.6
-
41
-
-
33750085801
-
-
Method: K. C. Nicolaou, E. A. Couladouros, P. G. Nantermet, J. Renaud, R. K. Guy, W. Wrasidlo, Angew. Chem. 1994, 106, 1669-1671; Angew. Chem., Int. Ed. Engl 1994, 33, 1581-1583.
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(1994)
Angew. Chem., Int. Ed. Engl
, vol.33
, pp. 1581-1583
-
-
-
42
-
-
2742596909
-
-
Procedure: Ref.[11]
-
Procedure: Ref.[11].
-
-
-
-
43
-
-
2742613532
-
-
Procedure: Ref.[14b]
-
Procedure: Ref.[14b].
-
-
-
-
44
-
-
0030714971
-
-
Method: C. Narayana, M. R. Reddy, M. Hair, G. W. Kabalka, Tetrahedron Lett. 1997, 38, 7705-7708.
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(1997)
Tetrahedron Lett.
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Narayana, C.1
Reddy, M.R.2
Hair, M.3
Kabalka, G.W.4
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45
-
-
0002842495
-
-
Method: K. Narasaka, F.-C. Pai, Chem. Lett 1980, 1415-1418; K. Narasaka, F.-C. Pai, Tetrahedron 1984, 40, 2233-2238; K.-M. Chen, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Tetrahedron Lett. 1987, 26, 2951-2954; K.-M. Chen, K. G. Gunderson, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Chem. Lett. 1987, 1923-1926.
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(1980)
Chem. Lett
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-
Narasaka, K.1
Pai, F.-C.2
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46
-
-
0000425224
-
-
Method: K. Narasaka, F.-C. Pai, Chem. Lett 1980, 1415-1418; K. Narasaka, F.-C. Pai, Tetrahedron 1984, 40, 2233-2238; K.-M. Chen, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Tetrahedron Lett. 1987, 26, 2951-2954; K.-M. Chen, K. G. Gunderson, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Chem. Lett. 1987, 1923-1926.
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(1984)
Tetrahedron
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-
Narasaka, K.1
Pai, F.-C.2
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47
-
-
1542653849
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-
Method: K. Narasaka, F.-C. Pai, Chem. Lett 1980, 1415-1418; K. Narasaka, F.-C. Pai, Tetrahedron 1984, 40, 2233-2238; K.-M. Chen, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Tetrahedron Lett. 1987, 26, 2951-2954; K.-M. Chen, K. G. Gunderson, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Chem. Lett. 1987, 1923-1926.
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(1987)
Tetrahedron Lett.
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-
Chen, K.-M.1
Hardtmann, G.E.2
Prasad, K.3
Repic, O.4
Shapiro, M.J.5
-
48
-
-
0001633976
-
-
Method: K. Narasaka, F.-C. Pai, Chem. Lett 1980, 1415-1418; K. Narasaka, F.-C. Pai, Tetrahedron 1984, 40, 2233-2238; K.-M. Chen, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Tetrahedron Lett. 1987, 26, 2951-2954; K.-M. Chen, K. G. Gunderson, G. E. Hardtmann, K. Prasad, O. Repic, M. J. Shapiro, Chem. Lett. 1987, 1923-1926.
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(1987)
Chem. Lett.
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-
Chen, K.-M.1
Gunderson, K.G.2
Hardtmann, G.E.3
Prasad, K.4
Repic, O.5
Shapiro, M.J.6
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49
-
-
0000264754
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Method: M. Georges, T. -F. Tam, B. Fraser-Reid, J. Org. Chem. 1985, 50, 5747-5753.
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(1985)
J. Org. Chem.
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, pp. 5747-5753
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Georges, M.1
Tam, T.F.2
Fraser-Reid, B.3
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50
-
-
0029078897
-
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Method: P. Camps, X. Farrés, M. L. García, J. Ginesta, J. Pascual, D. Mauleón, G. Carganico, Tetrahedron. Asymmetry 1995, 6, 1283-1294.
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(1995)
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Camps, P.1
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García, M.L.3
Ginesta, J.4
Pascual, J.5
Mauleón, D.6
Carganico, G.7
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51
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-
0025058974
-
-
S. D. Rychnovsky, D. J. Skalitzky, Tetrahedron Lett. 1990, 31, 945-948. S. D. Rychnovsky, B. Rogers, G. Yang, J. Org. Chem. 1993, 58, 3511-3515. - D. A. Evans, D. L. Rieger, J. R Gage, Tetrahedron Lett. 1990, 31, 7099-7100.
-
(1990)
Tetrahedron Lett.
, vol.31
, pp. 945-948
-
-
Rychnovsky, S.D.1
Skalitzky, D.J.2
-
52
-
-
33751385878
-
-
S. D. Rychnovsky, D. J. Skalitzky, Tetrahedron Lett. 1990, 31, 945-948. - S. D. Rychnovsky, B. Rogers, G. Yang, J. Org. Chem. 1993, 58, 3511-3515. - D. A. Evans, D. L. Rieger, J. R Gage, Tetrahedron Lett. 1990, 31, 7099-7100.
-
(1993)
J. Org. Chem.
, vol.58
, pp. 3511-3515
-
-
Rychnovsky, S.D.1
Rogers, B.2
Yang, G.3
-
53
-
-
0025608552
-
-
S. D. Rychnovsky, D. J. Skalitzky, Tetrahedron Lett. 1990, 31, 945-948. - S. D. Rychnovsky, B. Rogers, G. Yang, J. Org. Chem. 1993, 58, 3511-3515. - D. A. Evans, D. L. Rieger, J. R Gage, Tetrahedron Lett. 1990, 31, 7099-7100.
-
(1990)
Tetrahedron Lett.
, vol.31
, pp. 7099-7100
-
-
Evans, D.A.1
Rieger, D.L.2
Gage, J.R.3
-
54
-
-
2742542097
-
-
For the numbering used in the description of the NMR spectra of this compound cf. Scheme 7
-
For the numbering used in the description of the NMR spectra of this compound cf. Scheme 7.
-
-
-
-
55
-
-
2742559520
-
-
note
-
minor = 77.20; 94:6).
-
-
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