μη2:2-SbS: An antimony-containing heterodiatomic ligand from Group 15 and 16 elements

Angewandte Chemie - International Edition

Volumn 42, Issue 30, 2003, Pages 3547-3549

  Brunner, Henri ^a   Kubicki, Marek M ^b   Lange, Andreas ^a   Wachter, Joachim ^a   Vigier, Estelle ^b   Zabel, Manfred ^a  

^a UNIVERSITY OF REGENSBURG   (Germany)

^b UNIVERSITÉ DE BOURGOGNE   (France)

Author keywords

Antimony; Hetroatomic ligands; Molybdenum; Structure elucidation; Sulfur

Indexed keywords

MOLECULAR STRUCTURE; NITROGEN OXIDES;

LIGANDS;

ANTIMONY COMPOUNDS;

ANTIMONY; LIGAND; MOLYBDENUM COMPLEX; NITRIC OXIDE;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; GEOMETRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0043032696     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200350931     Document Type: Article

References (33)

1. a) W. A. Herrmann, Angew. Chem. 1991, 103, 835-836; Angew. Chem. Int. Ed. Engl. 1991, 30, 818-819;
2. a) W. A. Herrmann, Angew. Chem. 1991, 103, 835-836; Angew. Chem. Int. Ed. Engl. 1991, 30, 818-819;
3. b) F. Murad, Angew. Chem. 1999, 111, 1976-1989; Angew. Chem. Int. Ed. 1999, 38, 1856-1868.
4. b) F. Murad, Angew. Chem. 1999, 111, 1976-1989; Angew. Chem. Int. Ed. 1999, 38, 1856-1868.
5. a) J. Wachter, Angew. Chem. 1998, 110, 782-800; Angew. Chem. Int. Ed. 1998, 37, 750-768;
6. a) J. Wachter, Angew. Chem. 1998, 110, 782-800; Angew. Chem. Int. Ed. 1998, 37, 750-768;
7. b) L. Sedes, J. H. Yamamoto, L. Brissieux, B. T. Herenberg, K. A. Udachin, A. J. Carty, Inorg. Chem. 2001, 40, 6731-6736.
8. B. K. Das, M. G. Kanatzidis, Inorg. Chem. 1995, 34, 6505-6508.
9. O. Blacque, H. Brunner, M. M. Kubicki, F. Leis, D. Lucas, Y. Mugnier, B. Nuber, J. Wachter, Chem. Eur. J. 2001, 7, 1342-1349.
10. Surveys on ternary and quaternary thioantimonates are given in a) G. W. Drake, J. W. Kolis, Coord. Chem. Rev. 1994, 137, 131-178; b) R. Stähler, W. Bensch, Eur. J. Inorg. Chem. 2001, 3073-3078.
11. Surveys on ternary and quaternary thioantimonates are given in a) G. W. Drake, J. W. Kolis, Coord. Chem. Rev. 1994, 137, 131-178; b) R. Stähler, W. Bensch, Eur. J. Inorg. Chem. 2001, 3073-3078.
12. G. A. Zank, T. B. Rauchfuss, S. R. Wilson, A. L. Rheingold, J. Am. Chem. Soc. 1984, 106, 7621-7623.
13. H. Brunner, F. Leis, J. Wachter, M. Zabel, J. Organomet. Chem. 2001, 627, 139-143.
14. H. Brunner, F. Leis, J. Wachter, M. Zabel, J. Organomet. Chem. 2001, 628, 39-45.
15. a) T. M. Martin, G. L. Schimek, W. T. Pennington, J. W. Kolis, J. Chem. Soc. Dalton Trans. 1995, 501-502;
16. b) T. M. Martin, P. T. Wood, J. W. Kolis, Inorg. Chem. 1994, 33, 1587-1588.
17. M. G. Kanatzidis, J.-H. Chou, J. Solid State Chem. 1996, 127, 186-201.
18. A Lange, J. Wachter, M. Zabel, unpublished results.
19. H. Brunner, H. Kauermann, J. Pfauntsch, J. Wachter, J. H. Enemark, C. G. Young, J. Organomet. Chem. 1987, 331, 45-52.
20. 6) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+ 44) 1223-336-033; or deposit@ccdc.cam.ac.uk).
21. a) O. J. Scherer, Angew. Chem. 1990, 102, 1137-1155; Angew. Chem. Int. Ed. Engl. 1990, 29, 1104-1122;
22. a) O. J. Scherer, Angew. Chem. 1990, 102, 1137-1155; Angew. Chem. Int. Ed. Engl. 1990, 29, 1104-1122;
23. b) J. R. Harper, A. L. Rheingold, J. Organomet. Chem. 1990, 390, C36-C38;
24. c) W. Clegg, N. A. Compton, R. J. Errington, G. A. Fisher, N. C. Norman, T. B. Marder J. Chem. Soc. Dalton Trans. 1991, 2887-2895;
25. d) J. E. Davies, L. C. Kerr, M. Mays, P. R. Raithby, P. K. Tompkin, A.D. Woods, Angew. Chem. 1998, 110, 1473-1475; Angew. Chem. Int. Ed. 1998, 37, 1428-1429.
26. d) J. E. Davies, L. C. Kerr, M. Mays, P. R. Raithby, P. K. Tompkin, A.D. Woods, Angew. Chem. 1998, 110, 1473-1475; Angew. Chem. Int. Ed. 1998, 37, 1428-1429.
27. N. Korber, F. Richter, Helv. Chim. Acta 2001, 84, 2368-2372.
28. Gaussian 98 (Revision A.7), M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian, Inc., Pittsburgh, PA, 1998.
29. R. G. Pearson, Inorg. Chem. 1988, 27, 734-740.
30. + are of the nido trigonal-bipyramidal structural type (12 electrons or 6 skeletal electron pairs (SEPs)). The atomically vacant (vertex) site is occupied by the electrons of the bent metal-metal bond.
31. + are of the nido trigonal-bipyramidal structural type (12 electrons or 6 skeletal electron pairs (SEPs)). The atomically vacant (vertex) site is occupied by the electrons of the bent metal-metal bond.
32. 3- could be optimized, but with a very long (≈2.55 Å) bond.
33. -: d(Fe-Fe) = 2.578, d(As-S) = 2.391 Å.