Nickel(II) Complexes of Chiral Tripodal N,O,S-Ligands: Square-Planar vs. pseudo-Octahedral Coordination in the Solid State and in Solution, Metal-Induced Racemization of the Ligand

Chemische Berichte

Volumn 130, Issue 7, 1997, Pages 891-897

  Berkessel, Albrecht ^a,c   Bats, Jan W ^a,b   Bolte, Michael ^a,b   Neumann, Thomas ^a,b   Seidel, Lutz ^a,b  

^a UNIVERSITY OF HEIDELBERG   (Germany)

^b GOETHE UNIVERSITY   (Germany)

^c UNIVERSITY OF COLOGNE   (Germany)

Author keywords

Bioinorganic chemistry; Ligands; Nickel; Racemization; Thioethers; Tridentate

Indexed keywords

EID: 0042987383     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19971300713     Document Type: Article

References (17)

1. A. Berkessel, J. W. Bats, M. Hüber, W. Haase, T. Neumann, L. Seidel, Chan. Ber. 1995, 128, 125-129.
2. A. Berkessel, M. Bolte, M. Frauenkron, T. Nowak, T. Schwenkreis, L. Seidel, A. Steinmetz, Clieiu. Ber. 1996, 729, 59-68.
3. [3a] S. P. J. Albracht, Biochim. Biophys. Acta 1994, 1188, 167-204.
4. [3b] A. Volbeda, M.-H. Charon, C. Piras, E. C. Hatchikian, M. Frey, J. C. Fontecilla-Camps, Nature 1995, 373, 580-587.
5. [3c] A. Berkessel, G. Hermann, O.-T. Rauch, M. Büchner, A. Jacobi, G. Huttner, Client. Ber. 1996, 729, 1421-1423.
6. [3d] A. Berkessel, J. W. Bats, M. Hüber, W. Haase, T. Neumann, L. Seidel, Client. Ber. 1995, 128, 125-129.
7. K. Fries, W. Pfafiendorf, Ber. Dtsch. Cliem. Ges. 1910, 43, 212-219.
8. [5a] L. Sacconi, F. Mani, A. Bencini in Comprehensive Coordination Chemistry (Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty), Pergamon, Oxford, 1987, Vol. 5, p. 45.
9. [5b] M. A. Halcrow, G. Christou, Client Rev. 1994, 94, 2421-2481.
10. For a discusion of the formation of nieso- and wc-complexes of nickel(II) derived from chiral (2-pyridyl)phenyImethanol, see: C. Tissier, Bull. Soc. Chiin. Fr. 1991, 2308-2312.
11. A. Berkessel, M. Bolte, C. Griesinger, G. Huttner, T. Neumann, B. Schiemenz, H. Schwalbe, T. Schwenkreis, Augen: Cliem. 1993, 705, 1776-1780; Angew. Client Int. Ed. Engl. 1993, 32, 1777-1780.
12. [8a] R Noyori, Asymmetric Catalysis in Organic Synthesis, Wiley, New York, 1994.
13. [8b] I. Ojima (Ed.), Catalytic Asymmetric Synthesis, VCH, Weinheim, 1993.
14. [8c] R. Noyori, M. Kitamura, Angen: Client 1991,103, 34-55; Angen: Client. Int. Ed. Engl. 1991, 30, 49.
15. [9a] C. Bolm, Tetrahedron: Asymmetry 1991, 2, 701-704.
16. [9b] C. Bolm, M. Ewald, M. Felder, Client Ber. 1992, 725, 1205-1215.
17. S. Gehrina, P. Fleischhauer, H. Paulus, W. Haase, Inorg. Client 1993, 32, 54-60.