Nitrogen atom insertion into IR - S and C - S bonds initiated by photolysis of iridium(III) - azido-dithiocarbamato complexes

Journal of the American Chemical Society

Volumn 125, Issue 35, 2003, Pages 10514-10515

  Suzuki, Takayoshi ^a,b   DiPasquale, Antonio G ^a   Mayer, James M ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AZIDE; CARBON; DITHIOCARBAMIC ACID DERIVATIVE; IRIDIUM COMPLEX; NITROGEN; SULFUR;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; PHOTOCHEMISTRY; PHOTOLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY ANALYSIS;

EID: 0042856832     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0365779     Document Type: Article

References (26)

1. (a) Woo, L. K. Chem. Rev. 1993, 93, 1125-1136.
2. (b) Holm, R. H Chem. Rev. 1987, 87, 1401-1449.
3. (a) Laplaza, C. E.; Johnson, M. J. A.; Peters, J. C.; Odom, A. L.; Kim, E.; Cummins, C. C.; George, G. N.; Pickering, I. J. J. Am. Chem. Soc. 1996, 118, 8623-8638.
4. (b) Yandulov, D. V.; Schrock, R. R.; Rheingold, A. L.; Ceccarelli, C.; Davis, W. M. Inorg. Chem. 2003, 42, 796-813.
5. (c) Du Bois, J.; Tomooka, C. S.; Hong, J.; Carreira, E. M. Acc. Chem. Res. 1997, 30, 364.
6. (d) Huynh, M. H. V.; Baker, R. T.; Jameson, D. L.; Labouriau, A.; Meyer, T. J. J. Am. Chem. Soc. 2002, 124, 4580.
7. (e) Brown, S. N. J. Am. Chem. Soc. 1999, 122, 9752.
8. (f) Che, C.-M. Pure Appl. Chem. 1995, 67, 225.
9. (g) Crevier, T. J.; Bennett, B. K.; Soper, J. D.; Bowman, J. A.; Dehestani, A.; Hrovat, D. A.; Lovell, S.; Kaminsky, W.; Mayer, J. M. J. Am. Chem. Soc. 2001, 123, 1059.
10. (a) Grapperhaus, C. A.; Mienert, B.; Bill, E.; Weyhermüller, T.; Wieghardt, K. Inorg. Chem. 2000, 39, 5306.
11. (b) Tsuchimoto, M.; Yoshioka, N.; Ohba, S. Eur. J. Inorg. Chem. 2001, 1045.
12. Serpone, N.; Jamieson, M. A. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.; Pergamon: New York; 1987; Vol. 4, pp 1097-1179.
13. (a) Gafney, H. D.; Reed, J. L.; Basolo, F. J. Am. Chem. Soc. 1973, 95, 7998-8005.
14. (b) Weaver, T. R.; Basolo, F. Inorg. Chem. 1974, 13, 1535-1538.
15. Freedman, D. A.; Mann, K. R. Inorg. Chem. 1991, 30, 836.
16. 3).
17. int = 0.061), R1{I > 2δ(I/)} = 0.051, wR2(all data) = 0.123.
18. The structure of 1 is described in the Supporting Information.
19. (a) Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G.; Taylor, R. J. Chem. Soc., Dalton Trans. 1989, S1.
20. (b) Suzuki, T.; Rude, M.; Simonsen, K. P.; Morooka, M.; Tanaka, H.; Ohba, S.; Galsbøl, F.; Fujita, J. Bull. Chem. Soc. Jpn. 1994, 67, 1013.
21. Raston, C.; White, A. H. J. Chem. Soc., Dalton Trans. 1976, 32.
22. Xi, R.; Abe, M.; Suzuki, T.; Nishioka, T.; Isobe, K. J. Organomet. Chem. 1997, 549, 117.
23. Related M-S=N-C(R)-S- complexes: (a) Kato, A.; Tono, M.; Hisamatsu, N.; Nozawa, S.; Ninomiya, K.; Sugihama, T.; Kajitani, M.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1994, 473, 313-321. (b) Goodman, T. B.; Rauchfuss, T. B. Angew. Chem., Int. Ed. Engl. 1997, 36, 2083-2085.
24. Related M-S=N-C(R)-S- complexes: (a) Kato, A.; Tono, M.; Hisamatsu, N.; Nozawa, S.; Ninomiya, K.; Sugihama, T.; Kajitani, M.; Akiyama, T.; Sugimori, A. J. Organomet. Chem. 1994, 473, 313-321. (b) Goodman, T. B.; Rauchfuss, T. B. Angew. Chem., Int. Ed. Engl. 1997, 36, 2083-2085.
25. 15N-NMR Spectroscopy; Springer-Verlag: Berlin, 1981.)
26. Banthorpe, D. V. in The Chemistry of the Azide Group; Patai, S., Ed.; Wiley; New York; 1971; pp 397-440.