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Volumn 22, Issue 15, 2003, Pages 3134-3142

Bis(alkylamino)phosphanes: Deprotonation reactions and reactivity of t-BuP(NH-t-Bu)2 toward group 13 metalloorganics

Author keywords

[No Author keywords available]

Indexed keywords

DEPROTONATION;

EID: 0042843374     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0301839     Document Type: Article
Times cited : (18)

References (63)
  • 1
    • 0041311968 scopus 로고
    • Initial reports go back to the early studies of Michaelis: (a) Michaelis, A.; von Soden, H. Ann. Chem. 1885, 229, 334.
    • (1885) Ann. Chem. , vol.229 , pp. 334
    • Michaelis, A.1    Von Soden, H.2
  • 35
    • 0042313323 scopus 로고    scopus 로고
    • note
    • We reinvestigated the solid-state structure of IV, due to the high residual electron density found in the first structure analysis, and collected a much better data set, which shows only very small variations in bond lengths and distances.
  • 46
    • 0042313321 scopus 로고    scopus 로고
    • note
    • Several data sets were obtained for 2, 4, and 5 which could not be refined due to the same disorder problem. The asymmetric unit contains two half-occupied molecules with a noncrystallographic mirror plane between and the group 13 atom (B, 2; Ga, 4; In, 5) and one C atom of the t-BuP group on the plane (occupancy 1). However, the connectivity of all compounds (P coordination!) was confirmed without any doubts.
  • 50
    • 0004196761 scopus 로고
    • Robinson, G. H., Ed.; VCH: Weinheim, Germany
    • The structural changes according to the adduct formation have been described by Haaland in detail. Haaland, A. In Coordination Chemistry of Aluminum; Robinson, G. H., Ed.; VCH: Weinheim, Germany, 1993.
    • (1993) Coordination Chemistry of Aluminum
    • Haaland, A.1
  • 55
    • 0041812564 scopus 로고    scopus 로고
    • note
    • 36 using the room-temperature lattice parameters (see the Experimental Section), and the atomic parameters were obtained by a single-crystal structure analysis (data set taken at 123(2) K; see Table 1 in the Supporting Information).
  • 56
    • 0041311966 scopus 로고    scopus 로고
    • note
    • However, these distances are shorter than the rest of the Li⋯ H distances, which are longer than 3.0 Å.
  • 61
    • 0000564722 scopus 로고
    • SHELXS-97, program for structure solution
    • Sheldriok, G. M. SHELXS-97, Program for Structure Solution. Acta Crystallogr., Sect. A 1990, 46, 467.
    • (1990) Acta Crystallogr., Sect. A , vol.46 , pp. 467
    • Sheldriok, G.M.1
  • 63
    • 0042814412 scopus 로고    scopus 로고
    • STOE & Cie GmbH, Darmstadt, Germany
    • STOE WinXPow 1.05; STOE & Cie GmbH, Darmstadt, Germany, 1999.
    • (1999) STOE WinXPow 1.05


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.