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We reinvestigated the solid-state structure of IV, due to the high residual electron density found in the first structure analysis, and collected a much better data set, which shows only very small variations in bond lengths and distances.
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0042313321
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Several data sets were obtained for 2, 4, and 5 which could not be refined due to the same disorder problem. The asymmetric unit contains two half-occupied molecules with a noncrystallographic mirror plane between and the group 13 atom (B, 2; Ga, 4; In, 5) and one C atom of the t-BuP group on the plane (occupancy 1). However, the connectivity of all compounds (P coordination!) was confirmed without any doubts.
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47
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0041812564
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note
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36 using the room-temperature lattice parameters (see the Experimental Section), and the atomic parameters were obtained by a single-crystal structure analysis (data set taken at 123(2) K; see Table 1 in the Supporting Information).
-
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-
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56
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0041311966
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note
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However, these distances are shorter than the rest of the Li⋯ H distances, which are longer than 3.0 Å.
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