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Volumn 9, Issue 3, 1998, Pages 205-222

Homogeneous and Solid-Gas Hydrogenation of Alkynes and of 1,4-Cyclohexadiene in the Presence of the Hydrido Acetylide Cluster HRu3(CO)9(⊥-C2But)

Author keywords

Homogeneous catalysis; Hydrogenation reactions; Ruthenium acetylide cluster; Solid gas reactions

Indexed keywords


EID: 0042824855     PISSN: 10407278     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1022618724979     Document Type: Article
Times cited : (12)

References (31)
  • 6
    • 0041322205 scopus 로고    scopus 로고
    • A review on the chemistry and catalytic behaviour of clusters with alkynes coordinated in parallel or perpendicular fashion
    • S. Deabate, R. Giordano, and E. Sappa (1997). A review on the chemistry and catalytic behaviour of clusters with alkynes coordinated in parallel or perpendicular fashion. J. Cluster Sci. 8, 407.
    • (1997) J. Cluster Sci. , vol.8 , pp. 407
    • Deabate, S.1    Giordano, R.2    Sappa, E.3
  • 10
    • 0041299182 scopus 로고    scopus 로고
    • t to neo-hexane was achieved [Refs. 11, 21] and reaction intermediates important to the understanding of the reaction mechanisms were identified. We have now examined the behaviour of this alkyne under homogeneous catalytic conditions
    • t to neo-hexane was achieved [Refs. 11, 21] and reaction intermediates important to the understanding of the reaction mechanisms were identified. We have now examined the behaviour of this alkyne under homogeneous catalytic conditions.
  • 11
    • 0041799739 scopus 로고    scopus 로고
    • 2 at 120°C for 45 min. After cooling, a large amount of t-stilbene was observed again
    • 2 at 120°C for 45 min. After cooling, a large amount of t-stilbene was observed again.
  • 15
    • 0042300825 scopus 로고    scopus 로고
    • 2) was also observed
    • 2) was also observed.
  • 20
    • 0041799738 scopus 로고    scopus 로고
    • 1H and D-NMR spectra for the same (non-deuterated and deuterated) products
    • 1H and D-NMR spectra for the same (non-deuterated and deuterated) products.
  • 21
    • 0042300828 scopus 로고    scopus 로고
    • 2 is not volatile enough to be used as a substrate in these experiments
    • 2 is not volatile enough to be used as a substrate in these experiments.
  • 22
    • 0041299187 scopus 로고    scopus 로고
    • The presence of benzene has been confirmed by GC-MS. A solid-gas hydrogenation experiment with cluster 1 and benzene at 95°
    • 12 could be observed).
    • 12 Could be Observed)
  • 29
    • 0042801968 scopus 로고    scopus 로고
    • Attempts at hydrogenating diphenylacetylene in the presence of clusters 2b and 5b under the conditions described in the experimental section were unsuccessful
    • Attempts at hydrogenating diphenylacetylene in the presence of clusters 2b and 5b under the conditions described in the experimental section were unsuccessful.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.