One-step, enantiospecific transformation of cyclic, five-membered-1, 2-diols into their respective 1,2-bis(phenylsulfanyl) derivatives

Synlett

Volumn , Issue 11, 2003, Pages 1615-1618

  Skarzewski, Jacek ^a   Gupta, Anil ^a   Wojaczyńska, Elzbieta ^a   Siedlecka, Renata ^a  

^a WROCLAW UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

Diols; Mitsunobu reaction; Stereoselective synthesis; Thioethers

Indexed keywords

BENZENE; BENZENE DERIVATIVE; HYDROXYL GROUP; SULFIDE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL MODIFICATION; CHEMICAL REACTION; ENANTIOMER; MITSUNOBU REACTION; STEREOSPECIFICITY; SUBSTITUTION REACTION; TEMPERATURE;

EID: 0042781489     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-41015     Document Type: Article

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26. 4. After evaporation, the crude product was purified by chromatography on silica gel. Selected data for the obtained products are given below.
27. +.
28. 3P (2 equiv) in dry benzene. Mp 66-67 °C (EtOH).
29. 3): δ = 45.47, 50.55, 72.46, 126.13, 127.58, 127.73, 128.16, 128.39, 128.92, 128.96, 129.11, 132.86, 134.89, 141.77, 144.65.