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Volumn 119, Issue 3, 2003, Pages 1611-1622

Role of cyclic sets of transition dipoles in the pump-probe polarization anisotropy: Application to square symmetric molecules and perpendicular chromophore pairs

Author keywords

[No Author keywords available]

Indexed keywords

ANISOTROPY; CHROMOPHORES; LIGHT POLARIZATION; MATHEMATICAL MODELS; MOLECULES;

EID: 0042767592     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1581854     Document Type: Article
Times cited : (42)

References (50)
  • 29
    • 0041648785 scopus 로고
    • IUPAC Chemistry in the 21st Century, edited by M. A. El-Sayed, I. Tanaka, and Y. Molin (Blackwell Scientific, Oxford)
    • D. M. Jonas and G. R. Fleming, in Ultrafast Processes in Chemistry and Photobiology, IUPAC Chemistry in the 21st Century, edited by M. A. El-Sayed, I. Tanaka, and Y. Molin (Blackwell Scientific, Oxford, 1995), p. 225.
    • (1995) Ultrafast Processes in Chemistry and Photobiology , pp. 225
    • Jonas, D.M.1    Fleming, G.R.2
  • 31
    • 0042149700 scopus 로고    scopus 로고
    • note
    • 3.
  • 33
    • 0042650608 scopus 로고    scopus 로고
    • note
    • The projection operator proof that the transition dipole product must be real in Ref. 25 does not apply to four-wave mixing when all four polarizations are different. The time reversal invariance proof applies even in this case.
  • 35
    • 0041648786 scopus 로고    scopus 로고
    • note
    • The rectangular 2D box transition dipoles are not equal, but this inequality has no effect on the pump-probe signal to first order when the box size simultaneously changes by +ε( -ε) along x(y). In contrast, the level splitting is first order in ε. Use of a common transition dipole magnitude is justified as equivalent to a first-order expansion in the deformation, which is accurate only for small deformations.
  • 40
    • 0000088041 scopus 로고
    • edited by E. Marx (Akademische Verlagsgesellschaft, Leipzig
    • G. Placzek, in Handbuch der Radiologie, edited by E. Marx (Akademische Verlagsgesellschaft, Leipzig, 1934), Vol. VI, Part 2, p. 209.
    • (1934) Handbuch der Radiologie , vol.6 , Issue.PART 2 , pp. 209
    • Placzek, G.1
  • 41
    • 0042149698 scopus 로고    scopus 로고
    • note
    • When two components of a single degenerate level are involved, the vibrational wave functions for each component must be the same (or else the degeneracy would be lifted) so that the product of overlap integrals has the form «AB»«BC»«CB»«BA», which is always real and positive.
  • 42
    • 0002312013 scopus 로고
    • edited by D. Dolphin (Academic, New Yor)
    • M. Gouterman, in The Porphyrins, edited by D. Dolphin (Academic, New York, 1978), Vol. 3, p. 1.
    • (1978) The Porphyrins , vol.3 , pp. 1
    • Gouterman, M.1
  • 43
    • 0042149699 scopus 로고    scopus 로고
    • note
    • If the nondegenerate ground state is not totally symmetric, this statement must be modified: the Jahn-Teller distortion symmetry must match the change in symmetry between the ground state and the two doubly excited states with common symmetry to cause anisotropy decay.
  • 44
    • 0000347927 scopus 로고
    • Topics in Applied Physics edited by K. Shimoda (Springer, New York)
    • S. Haroche, in High Resolution Laser Spectroscopy, Topics in Applied Physics Vol. 13, edited by K. Shimoda (Springer, New York, 1976), p. 253.
    • (1976) High Resolution Laser Spectroscopy , vol.13 , pp. 253
    • Haroche, S.1
  • 46
    • 0043151634 scopus 로고    scopus 로고
    • It is assumed that coupling between the singly and doubly excited states can be neglected
    • It is assumed that coupling between the singly and doubly excited states can be neglected.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.