Sandwich and half-sandwich niobium imido complexes: X-ray crystal structure of [Nb(=NAr)Cp′2Cl] (Cp′=η5-C5H4SiMe3, Ar=C6H4OMe-4)

Journal of Organometallic Chemistry

Volumn 585, Issue 1, 1999, Pages 154-161

  Antiñolo, Antonio ^a   Fajardo, Mariano ^b   Huertas, Carmen ^a   Otero, Antonio ^a   Prashar, Sanjiv ^a   Rodriguez, Ana M ^a  

^a Organ Y Bioquim   (Spain)

^b UNIVERSITY OF ALCALÁ   (Spain)

Author keywords

Allyl; Half sandwich; Imido; Niobium; Niobocene

Indexed keywords

EID: 0042760445     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(99)00208-9     Document Type: Article

References (33)

1. See for example: (a) D.N. Williams, J.P. Mitchell, A.D. Poole, U. Siemeling, W. Clegg, D.C.R. Hockless, P.A. O'Neil, V.C. Gibson, J. Chem. Soc. Dalton Trans. (1992) 739.
2. (b) V.C. Gibson, D.N. Williams, W. Clegg, D.C.R. Hockless, Polyhedron 8 (1989) 1819.
3. (c) U. Siemeling, V.C. Gibson, J. Organomet. Chem. 426 (1992) C25.
4. (d) V.C. Gibson, A.D. Poole, U. Siemeling, D.N. Williams, W. Clegg, D.C.R. Hockless, J. Organomet. Chem. 462 (1993) C12.
5. (e) T.C. Baldwin, S.R. Huber, M.A. Bruck, D.E. Wigley, Inorg. Chem. 32 (1993) 5682.
6. (f) A.D. Poole, V.C. Gibson, W. Clegg, J. Chem. Soc. Chem. Commun. (1992) 237.
7. (g) J.K. Cockcroft, V.C. Gibson, J.A.K. Howard, A.D. Poole, U. Siemeling, C. Wilson, J. Chem. Soc. Chem. Commun. (1992) 1668.
8. (h) M.C.W. Chan, J.M. Cole, V.C. Gibson, J.A.K. Howard, C. Lehmann, A.D. Poole, U. Siemeling, J. Chem. Soc. Dalton Trans. (1998) 103.
9. (i) M.L.H. Green, J.T. James, J.F. Saunders, J. Souter, J. Chem. Soc. Dalton Trans. (1997) 1281.
10. A. Antiñolo, P. Espinosa, M. Fajardo, P. Gómez-Sal, C. López-Mardomingo, A. Martin-Alonso, A. Otero, J. Chem. Soc. Dalton Trans. (1995) 1007.
11. (a) A.N. Chernega, M.L.H. Green, A.G. Suarez, J. Chem. Soc. Dalton Trans. (1993) 3031.
12. (b) S. Schmidt, J. Sundermeyer, J. Organomet. Chem. 472 (1994) 127.
13. M.L.H. Green, J.T. James, A.N. Chernega, J. Chem. Soc. Dalton Trans. (1997) 1719.
14. (a) W.A. Hermann, W. Baratta, E. Herdtweck, Angew. Chem. Int. Ed. Engl. 35 (1996) 1951.
15. (b) W.A. Hermann, W. Baratta, E. Herdtweck, J. Organomet. Chem. 541 (1997) 445.
16. (c) A.N. Chernega, M.L.H. Green, A.G. Suarez, Can. J. Chem. 73 (1995) 1157.
17. Korolev A.V., Rheingold A.L., Williams D.S. Inorg. Chem. 36:1997;2647.
18. Heinseiman K.S., Miskowski V.M., Geib S.J., Wang L.C., Hopkins M.D. Inorg. Chem. 36:1997;5530.
19. Sundermeyer J., Putterlik J., Foth M., Field J.S., Ramesar N. Chem. Ber. 127:1994;1201.
20. (a) G. Parkin, A. van Asselt, D.J. Leahy, L.R. Whinnery, N.G. Hua, R.W. Quan, L.M. Henling, W.P. Schaefer, B.D. Santarsiero, J.E. Bercaw, Inorg. Chem. 31 (1992) 82.
21. (b) K.A. Jørgensen, Inorg. Chem. 32 (1993) 1521.
22. S.C Dunn, P. Mountford, D.A. Robson, J. Chem. Soc. Dalton Trans. (1997) 293.
23. J.C. Green, M.L.H. Green, J.T. James, P.C. Konidaris, G.H. Maunder, P. Mountford, J. Chem. Soc. Chem. Commun. (1992) 1361.
24. Osborne J.H., Rheingold A.L., Trogler W.C. J. Am. Chem. Soc. 107:1985;7945.
25. Schofield M.H., Kee T.P., Anhaus J.T., Schrock R.R., Johnson K.H., Davis W.M. Inorg. Chem. 30:1991;3595.
26. A. Antiñolo, F. Carrillo-Hermosilla, A. Otero, M. Fajardo, A. Garcés, P. Gómez-Sal, C. López-Mardomingo, A. Martín, C. Miranda, J. Chem. Soc. Dalton Trans. (1998) 59.
27. Antiñolo A., Otero A., Prashar S., Rodriguez A.M. Organometallics. 17:1998;5454.
28. N.J. Bailey, J.A. Cooper, H. Gailus, M.L.H. Green, J.T. James, M.A. Leech, J. Chem. Soc. Dalton Trans. (1997) 3579.
29. A. Antiñolo, J.M. de Ilarduya, A. Otero, P. Royo, A.M.M. Lanfredi, A. Tiripicchio, J. Chem. Soc. Dalton Trans. (1988) 2685.
30. A.M.M. Lanfredi, A. Tiripicchio, M. Kapon, G.M. Reisner, J. Chem. Soc. Dalton Trans. (1990) 375.
31. Antiñolo A., Huertas C., del Hierro I., Lappert M.F., Otero A., Prashar S., Rodriguez A.M., Villaseñor E. Organometallics. 17:1998;5874.
32. A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, M.C. Burla, G. Polidori, M. Camalli, J. Appl. Cryst. (1994) 435.
33. G.M. Sheldrick, Program for the Refinement of Crystal Structures from Diffraction Data, University of Göttingen, Germany, 1997.