Novel 1-D Coordination Polymers Containing μ-[N(CN)2]- Bridging Ligands. Structure and Magnetic Properties of Mn[N(CN)2]2L (L = 2,2'-Bipyridine, 4,4'-Bipyridine)

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 334, Issue , 1999, Pages 605-613

  Manson, Jamie L ^a   Incarvito, Christopher D ^b   Arif, Atta M ^a   Rheingold, Arnold L ^b   Miller, Joel S ^a  

^a UNIVERSITY OF UTAH   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

Antiferromagnetic coupling; Coordination polymers; Dicyanamide

Indexed keywords

EID: 0042726768     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587259908023355     Document Type: Article

References (24)

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20. 8Mn: C, 48.99; H, 2.34; N, 32.65. Found: C, 48.90; H, 2.31; N, 32.73.
21. 2: C, 45.42; H, 2.99; N, 30.27. Found: C, 45.40; H, 2.98; N, 30.18.
22. int = 0.0364), and 692 were observed [I > 2σ(I)]. The structure was solved by direct methods and refined using the Siemens SHELXTL© (Version 5.0) Software Package. All nonhydrogen atoms were refined anisotropically and hydrogen atoms were treated as idealized contributions, R(F) = 0.0514, R(wF) = 0.1218, GOF = 1.742. The X-ray data was deposited with the Cambridge Crystallographic Data Centre as supplementary publication no, CCDC-102608. Copies of the data can be obtained free of charge upon application to CCDC, 12 Union Road, Cambridge CB2 1EZ [fax: (+44) 1223-336-033; email deposit6@ccdc.cam.ac.uk].
23. int = 0.0000), and 3008 were observed [1 > 2σ(1)]. The structure was solved by direct methods and refined using the Siemens SHELXTL97© Software Package. Disordered water molecules with O(1), 0(2), O(1)′ and O(2)′ atoms were refined as 0.5 occupancy each. All nonhydrogen atoms were refined anisotropically and hydrogen atoms were treated as idealized contributions, R(F) = 0.0384, R(wF) = 0.0861, GOF = 1.033. All illustrations were drawn with Crystal Maker©.
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