An exceptional hydroboration of substituted fluoroolefins providing tertiary alcohols

Organic Letters

Volumn 3, Issue 23, 2001, Pages 3789-3790

  Ramachandran, P Veeraraghavan ^a   Jennings, Michael P ^a  

^a PURDUE UNIVERSITY   (United States)

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ARTICLE;

EID: 0042704182     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol016779e     Document Type: Article

References (16)

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3. (a) Brown, H. C.; Chen, G.-M.; Jennings, M. P.; Ramachandran, P. V. Angew. Chem., Intl. Ed. 1999, 38, 2052.
4. (b) Ramachandran, P. V.; Jennings, M. P.; Brown, H. C. Org. Lett. 1999, 1, 1399.
5. Jennings, M. P.; Cork, E. A.; Ramachandran, P. V. J. Org. Chem. 2000, 65, 8763.
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7. (b) Hayase, T.; Sugiyama, T.; Suzuki, M.; Shibata, T.; Soai, K. J. Fluorine Chem. 1997, 84, 1.
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10. (c) Ramachandran, P. V. Teodorovic, A. V.; Brown, H. C. Tetrahedron 1993, 49, 1725.
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12. (b) Rong, G.; Keese, R. Tetrahedron Lett. 1990, 31, 5617.
13. The hydroboration of α-methylstyrene with catecholborane catalyzed by [Rh(acac)(DPPB)] providing 95:5 regioselectivity in favor of the 3°-derivative has been reported. Westcott, S. A.; Marder, T. B.; Baker, R. T. Organometallics 1993, 12, 975.
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15. Brown, H. C: Chandrasekharan, J. J. Org. Chem. 1983, 48, 644.
16. Contribution no.14 from the Herbert C. Brown Center for Borane Research