Kinetic isotope effect for hydrogen abstraction by .OH radicals from normal and carbon-deuterated ethyl alcohol and methylamine in aqueous solutions

Journal of Physical Chemistry B

Volumn 107, Issue 30, 2003, Pages 7268-7276

  Bonifačić, Marija ^a   Armstrong, David A ^b   Štefanić, Igor ^c   Asmus, Klaus Dieter ^d  

^a RUDER BO KOVI INSTITUTE   (Croatia)

^b UNIVERSITY OF CALGARY   (Canada)

^c Culver Academies   (United States)

^d ADAM MICKIEWICZ UNIVERSITY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

ETHANOL; FREE RADICALS; RATE CONSTANTS; SOLUTIONS; SUBSTITUTION REACTIONS;

PRIMARY RADICALS;

ISOTOPES;

EID: 0042698689     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp027790e     Document Type: Article

References (46)

1. Wardman, P. J. Phys. Chem. Ref. Data 1989, 18, 1637.
2. Das, S.; von Sonntag, C. Z. Naturforsch., B: Chem. Sci. 1986, 41, 505.
3. Bonifačić, M.; Štefanić, I.; Hug, G. L.; Asmus, K.-D.; Armstrong, D. A. J. Am. Chem. Soc. 1998, 120, 3139.
4. Bonifačić, M.; Armstrong, D. A.; Carmichael, I.; Asmus, K.-D. J. Phys. Chem. B 2000, 104, 643.
5. Štefanić, I.; Bonifačić, M.; Asmus, K.-D.; Armstrong, D. A. J. Phys. Chem. A 2001, 705, 8681.
6. Hug, G. L.; Fessenden, R. W. J. Phys. Chem. A 2000, 704, 7021.
7. Hug, G. L.; Bonifačić, M.; Asmus, K.-D.; Armstrong, D. A. J. Phys. Chem. B 2000, 104, 6674.
8. Yu, D.; Rauk, A.; Armstrong, D. A. J. Am. Chem. Soc. 1995, 117, 1789.
9. Bookman, T. M.; Hubig, S. M.; Kochi, J. K. J. Am. Chem. Soc. 1998, 120, 2826.
10. Getoff, N.; Schwoerer, F. Int. J. Radiat. Phys. Chem. 1971, 3, 429.
11. Buxton, G. V.; Greenstock, C. L.; Helman, W. P.; Ross, A. B. J. Phys. Chem. Ref. Data 1988, 17, 513.
12. Anbar, M.; Meyerstein, D.; Neta, P. J. Chem. Soc. B 1966, 742.
13. Asmus, K.-D.; Möckel, H.; Henglein, A. J. Phys. Chem. 1973, 77, 1218.
14. Zhao, F.; Ghezzo-Schöneich, E.; Aced, G. I.; Hong, J.; Milby, T.; Schöneich, C. J. Biol. Chem. 1997, 272, 9019.
15. Hug, G. L.; Wang, Y.; Schöneich, C.; Jiang, P.-Y.; Fessenden, R. W. Radiat. Phys. Chem. 1999, 54, 559.
16. von Sonntag, C. The Chemical Basis of Radiation Biology; Taylor and Francis: New York, 1987.
17. Schuler, R. H.; Hartzell, A. L.; Behar, B. J. Phys. Chem. 1981, 85, 192.
18. Janata, E.; Schuler, R. H. J. Phys. Chem. 1982, 86, 2078.
19. Getoff, N.; Schwoerer, F. Int. J. Radiat. Phys. Chem. 1970, 2, 81.
20. Wigger, A.; Gruenbein, W.; Henglein, A.; Land, E. J. Z. Naturforsch., B: Chem. Sci. 1969, 24, 1262.
21. Armstrong, D. A.; Sun, Q.; Schuler, R. H. J. Phys. Chem. 1996, 100, 9892.
22. Hug, G. L. Natl. Stand. Ref. Data Ser.; U.S. National Bureau of Standards, Report No. 69, 1981.
23. Mezyk, S. P.; Bartels, D. M. J. Phys. Chem. 1997, 101, 1329.
24. Solar, S.; Solar, W.; Getoff, N.; Holcman, J.; Sehested, K. J. Chem. Soc., Faraday Trans. 1 1982, 78, 2467.
25. Burchill, C. E.; Ginns, I. S. Can. J. Chem. 1970, 48, 2628.
26. Ellison, D. H.; Salmon, G. A.; Wilkinson, F. Proc. R. Soc. London, Ser. A 1972, 328, 23.
27. Paul, H.; Small, R. D., Jr.; Scaiano, J. C. J. Am. Chem. Soc. 1978, 100, 4520.
28. Gilbert, B. C.; Holmes, R. G. G.; Laue, H. A. H.; Norman, R. O. C. J. Chem. Soc., Perkin Trans. 2 1976, 1047.
29. van Leeuwen, J. W.; van Dijk, C.; Veeger, C. Eur. J. Biochem. 1983, 735, 601.
30. Neta, P.; Grodkowski, J.; Ross, A. B. J. Phys. Chem. Ref. Data 1996, 25, 709.
31. Hiller, K.-O.; Masloch, B.; Göbl, M.; Asmus, K.-D. J. Am. Chem. Soc. 1981, 103, 2734.
32. Wallington, T. J.; Dagaut, P.; Kurylo, M. J. J. Phys. Chem. 1988, 92, 5024.
33. Roberts, B. P.; Steel, A. J. J. Chem. Soc., Perkin Trans. 2 1994, 2155.
34. Garrett, B. C.; Schenter, G. K. In Structure and Reactivity in Aqueous Solution; Cramer, C. J., Truhler, D. G., Eds.; American Chemical Society; Washinton, DC, 1994; p 122.
35. Fokin, A. A.; Schreiner, P. R. Chem. Rev. 2002, 102, 1551.
36. Tully, F. P.; Droege, A. T.; Koszykowski, M. L.; Melius, C. F. J. Phys. Chem. 1986, 90, 691.
37. Dyke, J. M.; Groves, A. P.; Lee, E. P. F.; Zamanpour Niavaran, M. H. J. Phys. Chem. 1997, 101, 373.
38. Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. No. 1.
39. Pearson, R. G. J. Am. Chem. Soc. 1986, 108, 6109.
40. Berkowitz, J.; Ellison, G. B.; Gutman, D. J. Phys. Chem. B 1994, 98, 2744.
41. March, J. In Advanced Organic Chemistry; Wiley & Sons: New York, 1985; p 18.
42. Elford, P. E.; Roberts, B. P. J. Chem. Soc., Perkin Trans. 2 1996, 2247.
43. Zhao, Y.; Lu, Y.; Parker. V. D. J. Chem. Soc., Perkin Trans 2 2001, 1481, and references therein.
44. 2OH.
45. 25) and does not occur on the ∼200-μs time scale of this experiment.
46. .OH.