Synthesis of two potentially heptadentate (N4O3) Schiff-base ligands derived from condensation of tris(3-aminopropyl)-amine and salicylaldehyde or 4-hydroxysalicylaldehyde. Nickel(II) and copper(II) complexes of the former ligand

Molecules

Volumn 7, Issue 2, 2002, Pages 140-144

  Keypour, Hassan ^a   Salehzadeh, Sadegh ^a   Parish, R V ^b  

^a BU ALI SINA UNIVERSITY   (Iran)

^b UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

Potentially heptadentate complexes; Schiff base; Tripodal ligands

Indexed keywords

4 HYDROXYSALICYLALDEHYDE; BETA RESORCYLIC ACID; COPPER COMPLEX; LIGAND; METHANOL; NICKEL COMPLEX; NITROGEN OXIDE; PROPYLAMINE; SALICYLALDEHYDE; SCHIFF BASE; SODIUM CHLORIDE; TRIS(3 AMINOPROPYL)AMINE; TRIS[3 (4' HYDROXYSALICYLIDENEIMINO)PROPYL]AMINE; TRIS[3 (SALICYLIDENEIMINO)PROPYL]AMINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; FAST ATOM BOMBARDMENT MASS SPECTROMETRY; INFRARED SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; SUBSTITUTION REACTION; SYNTHESIS;

EID: 0042620446     PISSN: 14203049     EISSN: None     Source Type: Journal    
DOI: 10.3390/70200140     Document Type: Article

References (11)

1. Costes, J.-P.; Dupuis, A.; Commenges, G.; Lagrave, S.; Laurent, J.-P. Mononuclear lanthanide complexes of tripodal ligands: synthesis and spectroscopic studies. Inorg. Chim. Acta 1999, 285, 49-54.
2. Costes, J.-P.; Dahan, F.; Dupuis, A.; Lagrave, S.; Laurent, J.-P. Homo- (4f, 4f) and hetrodimethallic (4f, 4f′) Complexes. The first structurally characterized example of a hetrodimethalic (Yb, La) complex(1′). Magnetic properties of 1′ and of a homodinuclear (Gd, Gd) analogue. Inorg. Chem. 1998, 37, 153-155.
3. Bhattacharyya, P.; Parr, J.; Ross, A. T.; Slawin. A. M. Z. First synthesis of a unique dilead Schiff base complex. J. Chem. Soc., Dalton Trans. 1998, 3149-3150.
4. Kanesato, M.; Yokoyama, T.; Itabashi, O.; Suzuki, T. M.; Shiro, M. Synthesis and Structural Characterization of praseodymium(III) and Neodymium(III) complexes of tripodal tris[2-(salicylideneamino)ethyl]amine. Bull. Chem. Soc. Jpn. 1996, 69, 1297-1302.
5. Aguiari, A.; Bullita, E.; Casellato, U.; Guerriero, P.; Tamburini, S.; Vigato, P. A. Preparation, properties and coordination behaviour of planar or tridimentional compartmental Schiff bases. Inorg. Chim. Acta 1994, 219, 135-146.
6. 3 amine phenol logands with phenolate oxygen bridges: evidence for very weak magnetic exchange between lanthanide Ions. J. Am. Chem. Soc. 1992, 114, 6081-6087.
7. Keypour, H.; Salehzadeh, S.; Pritchard, R. G.; Parish, R. V. Nickel(II) complexes of fully and partially condensed Schiff-base ligands derived from tris(3-aminopropyl)amine and acetylpyridine. Transition. Met. Chem. 1998, 23, 605-607.
8. 3. Coord. Chem. Rev. 1987, 77, 89-163.
9. Jäntti, A.; Wagner, M.; Sountamo, R.; Kolehmainen, E.; Rissanen, K. Schiff-base podates - X-ray, NMR and Ab initio molecular-orbital studies of the cadmium(II) complexes of linear and three-armed podads in solution and solid state. Eur. J. Inorg. Chem. 1998, 1555-1562.
10. Keypour, H.; Salehzadeh, S.; Pritchard, R. G.; and Parish, R. V. Cadmium(II) complexes of fully condensed Schiff-base ligands derived from two different symmetrical and asymmetrical tripodal tetraamines and 2-acetylpyridine; the novel observations for heptadentate mono-capped trigonal antiprismatic Schiff-base complexes. Polyhedron 2000, 19, 1633-1637.
11. 3S coordination. Inorg. Chim. Acta 1979, 33, L149-151.