Palladium-catalyzed stereoselective synthesis of (E)-β,γ -unsaturated amides

Tetrahedron Letters

Volumn 44, Issue 39, 2003, Pages 7249-7251

  Luo, Fen Tair ^a   Lu, Ting Yi ^b   Xue, Cuihua ^a  

^a INSTITUTE OF CHEMISTRY   (Taiwan)

^b NATIONAL CHUNG CHENG UNIVERSITY   (Taiwan)

Author keywords

2 bromo N,N dimethylacetamide; Alkenylborane; Suzuki coupling reactions

Indexed keywords

2 BROMO N,N DIMETHYLACETAMIDE; ACETAMIDE DERIVATIVE; BORANE DERIVATIVE; PALLADIUM; PHOSPHINE DERIVATIVE; TRICYCLOHEXYLPHOSPHINE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; OXIDATION; STEREOCHEMISTRY; SUZUKI REACTION; SYNTHESIS;

LATEOLABRAX JAPONICUS;

EID: 0042381846     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.08.011     Document Type: Article

References (12)

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11. 3 (10 mmol) and cyclohexene (20 mmol) at 0°C. The reaction mixture was stirred for another 3 h at 0°C. Terminal acetylene (10 mmol) was then slowly added to the above white reaction mixture at 0°C. The reaction mixture was stirred for another 3 h at rt until it became clear.
12. 3, TMS) δ 15.86, 35.48, 37.41, 37.94, 122.66, 126.59, 126.68, 131.94, 134.06, 137.42, 170.90 ppm.