1H-NMR and EPR studies of the electronic structure of low-spin ruthenium(III) isocyanide porphyrin complexes: Unusual (dxz,dyz)4 (dxy)1 configuration

Journal of Organometallic Chemistry

Volumn 629, Issue 1-2, 2001, Pages 145-152

  Galardon, Erwan ^a   Le Maux, Paul ^a   Paul, Christine ^b   Poriel, Cyril ^a   Simonneaux, Gérard ^a  

^a CNRS   (France)

^b INSA DE RENNES   (France)

Author keywords

Isocyanides complexes; Nuclear magnetic resonance; Paramagnetic complexes; Ruthenium porphyrins

Indexed keywords

EID: 0042370406     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(01)00830-0     Document Type: Article

References (44)

1. K.M. Kadish, K.M. Smith, R. Guilard, Biochemistry and Activation of Small Molecules, the Porphyrin Handbook, vol. 4, Academic Press, San Diego, USA, 2000.
2. Simonneaux G. Coord. Chem. Rev. 165:1997;447.
3. Antonini E., Brunori M. Hemoglobin and Myoglobin in their Reactions with Ligands. 1971;North-Holland, Amsterdam.
4. G. Simonneaux, A. Bondon, Isocyanides and Phosphines as Axial Ligands in Heme Proteins and Iron Porphyrin Models, The Porphyrin Handbook, vol. 5, p. 299, Academic Press, San Diego, USA, 2000.
5. Brothers P.J., Collman J.P. Acc. Chem. Res. 19:1986;209.
6. Simonneaux G., Schünemann V., Morice C., Carel L., Toupet L., Winkler H., Trautwein A.X., Walker F.A. J. Am. Chem. Soc. 122:2000;4366.
7. Walker F.A., Simonis U. Biol. Magn. Reson. 12:1993;133.
8. Simonneaux G., Hindré F., Le Plouzennec M. Inorg. Chem. 28:1989;823.
9. Safo M.K., Walker F.A., Raitsimring A.M., Walters W.P., Dolata D.P., Debrunner P.G., Scheidt W.R. J. Am. Chem. Soc. 116:1994;7760.
10. Chessman M.R., Walker F.A. J. Am. Chem. Soc. 118:1996;7373.
11. Walker F.A., Nasri H., Turowska-Tyrk I., Mohanrao K., Watson C.T., Shokhirev N.V., Debrunner P.G., Scheidt W.R. J. Am. Chem. Soc. 118:1996;12109.
12. M. Ke, S.J. Rettig, B.R. James, D. Dolphin, Chem. Soc. Chem. Commun. (1987) 1110.
13. Medhi O.K., Agarwala U. Inorg. Chem. 19:1980;1381.
14. Groves J.T., Bonchio M., Carofiglio T., Shalyaev K. J. Am. Chem. Soc. 118:1996;8961.
15. Rachlewicz K., Grzeszczuk M., Latos-Grazynski L. Polyhedron. 12:1993;821.
16. James B.R., Mikkelsen S.R., Leung T.W., Williams G.M., Wong R. Inorg. Chim. Acta B. 85:1984;209.
17. James B.R., Dolphin D., Leung T.W., Einstein F.W., Willis A.C. Can. J. Chem. 62:1984;1238.
18. Barley M., Becker J.Y., Domazetis G., Dolphin D., James B.R. Can. J. Chem. 61:1984;2389.
19. Taqui Khan M.M., Srinivas D., Kureshi R.I., Khan N.H. Inorg. Chem. 29:1990;2320.
20. Collman J.P., Barnes C.E., Brothers P.J., Collins T.J., Ozawa T., Gallucci J.C., Ibers J.A. J. Am. Chem. Soc. 106:1984;5151.
21. Morice C., Le Maux P., Moinet C., Simonneaux G. Inorg. Chim. Acta. 273:1998;142.
22. Brown G.M., Hopf F.R., Ferguson J.A., Meyer T.J., Whitten D.G. J. Am. Chem. Soc. 95:1973;5939.
23. Rillema D.P., Nagle J.K., Barringer L.F., Meyer T.J. J. Am. Chem. Soc. 103:1981;56.
24. Morishima I., Takamuki Y., Shiro Y. J. Am. Chem. Soc. 106:1984;7666.
25. Collman J.P., McElwee-White L., Brothers P.J., Rose E. J. Am. Chem. Soc. 108:1986;1332.
26. Ke M., Shista C., James B.R., Dolphin D., Sparapany J.W., Ibers J.A. Inorg. Chem. 30:1991;4766.
27. Bonnet J.J., Eaton S.S., Eaton G.R., Holm R.H., Ibers J.A. J. Am. Chem. Soc. 95:1973;2141.
28. Geze C., Legrand N., Bondon A., Simonneaux G. Inorg. Chim. Acta. 195:1992;73.
29. Galardon E., Lukas M., Le Maux P., Toupet L., Roisnel T., Simonneaux G. Acta Cryst. Sect. C. 56:2000;955.
30. Lee F.-W., Choi M.Y., Cheung K.K., Che C.M. J. Organomet. Chem. 595:2000;114.
31. Le Plouzennec M., Bondon A., Simonneaux G. Inorg. Chem. 23:1984;4398.
32. Le Plouzennec M., Bondon A., Sodano P., Simonneaux G. Inorg. Chem. 25:1986;1254.
33. M.H. Barley, D. Dolphin, B.R. James, J. Chem. Soc. (1984) 1499.
34. Sur S.K. J. Magn. Res. 82:1989;169.
35. D.F. Evans, J. Chem. Soc. (1959) 2003.
36. Rachlewicz K., Latos-Grazynski L. Inorg. Chim. Acta. 144:1988;213.
37. La Mar G.N., Del Gaudio J., Frye J.S. Biochim. Biophys. Acta. 498:1977;422.
38. Nakamura M., Ikeue T., Ikezaki A., Ohgo Y., Fujii H. Inorg. Chem. 38:1999;3857.
39. Nakamura M., Ikeue T., Neya S., Funasaki N., Nakamura N. Inorg. Chem. 35:1996;3731.
40. Shokhirev N., Walker F.A. J. Phys. Chem. 99:1995;17795.
41. La Mar G.N., Bold T.J., Satterlee J.D. Biochim. Biophys. Acta. 498:1977;189.
42. Morishima I., Shiro Y., Takamuki Y. J. Am. Chem. Soc. 105:1983;6168.
43. Taylor C.P.S. Biochim. Biophys. Acta. 491:1977;137.
44. Sullivan J., Strauss S.H. Inorg. Chem. 28:1989;3093.