Solid state structure of P(o-(CF3)Ph)3 substituted Rh2(CO)4(μ-Cl)2. Formation of dimeric [Rh2(CO)3(μ-Cl)2{P(o-(CF 3)Ph)3}]2

Journal of Organometallic Chemistry

Volumn 633, Issue 1-2, 2001, Pages 69-70

  Jääskeläinen, Sirpa ^a   Suomalainen, Pekka ^a   Haukka, Matti ^a   Riihimäki, Helena ^b   Pursiainen, Jouni T ^b   Pakkanen, Tapani A ^a  

^a UNIVERSITY OF EASTERN FINLAND   (Finland)

^b UNIVERSITY OF OULU   (Finland)

Author keywords

Carbonyl; Crystal structures; Phosphane; Rhodium

Indexed keywords

EID: 0042370260     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(01)01037-3     Document Type: Article

References (7)

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4. P-Rh=195 Hz). Owing to the presence of small amounts of free ligand, as evidenced by NMR spectroscopy, there were slight deviations from theoretical values in the results of the elemental analysis.
5. -3): 0.854 and -0.852. An orange plate-like crystal with dimensions 0.30×0.20×0.05 mm was used. Data was collected on a Nonius-Kappa CCD diffractometer. All non-hydrogen atoms were refined anisotropically and phenyl hydrogens were refined isotropically.
6. Walz L., Scheer P. Acta Crystallogr. Sect. C. 47:1991;640.
7. Bonnet J.J., Jeannin Y., Kalck P., Maisonnat A., Poilblanck R. Inorg. Chem. 14:1975;743.