Catalytic properties of lipases immobilized on various mesoporous silicates

Bioscience, Biotechnology and Biochemistry

Volumn 67, Issue 1, 2003, Pages 203-206

  Kato, Katsuya ^a   Irimescu, Roxana ^a   Saito, Takao ^a   Yokogawa, Yoshiyuki ^a   Takahashi, Haruo ^a,b  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b Rd Management Section   (Japan)

Author keywords

Enantioselective acetylation; Immobilization; Lipase; Mesoporous silica; Secondary alcoho

Indexed keywords

IMMOBILIZED ENZYME; SILICATE; SOLVENT; TRIACYLGLYCEROL LIPASE;

ACETYLATION; ADSORPTION; ARTICLE; CATALYSIS; CHEMISTRY; DRUG STABILITY; HEAT; ISOLATION AND PURIFICATION; POROSITY; STEREOISOMERISM; THERMODYNAMICS;

ACETYLATION; ADSORPTION; CATALYSIS; DRUG STABILITY; ENZYMES, IMMOBILIZED; HEAT; LIPASE; POROSITY; SILICATES; SOLVENTS; STEREOISOMERISM; THERMODYNAMICS;

EID: 0042352320     PISSN: 09168451     EISSN: 13476947     Source Type: Journal    
DOI: 10.1271/bbb.67.203     Document Type: Article

References (14)

1. Bickerstaff, G. F., “Immobilization of Enzymes and Cells”, Humana Press, N.J. (1997).
2. Hata, H., Saeki, S., Kimura, T., Sugahara, Y., and Kuroda, K., Adsorption of taxol into ordered mesoporous silicas with various pore diameters. Chem. Mater., 11, 1110-1119 (1999).
3. Murata, S., Hata, H., Kimura, T., Sugahara, Y., and Kuroda, K., Effective adsorption of chlorophyll a by FSM-type mesoporous silica modified with 1,4-butanediol. Langmuir, 16, 7106-7108 (2000).
4. Deere, J., Magner, E., Wall, J. G., and Hodnett, B. K., Adsorption and activity of cytochrome c on mesoporous silicates. J. Chem. Soc. Chem. Commun., 465-466 (2001).
5. Washmon-Kriel, L., Jimenez, V. L., and Balkus, K. J. Jr., Cytochrome c immobilization into mesoporous molecular sieves. J. Mol. Catal. B: Enzymatic, 10, 453-469 (2000).
6. Yiu, H. H. P., Wright, P. A., and Botting, N. P., Enzyme immobilisation using SBA-15 mesoporous molecular sieves with functionalised surfaces. J. Mol. Catal. B: Enzymatic, 15, 81-92 (2001).
7. Takahashi, H., Li, B., Sasaki, T., Miyazaki, C., Kajino, T., and Inagaki, S., Catalytic activity in organic solvents and stability of immobilized enzymes depend on the pore size and surface characteristics of mesoporous silica. Chem. Mater., 12, 3301-3305 (2000).
8. Han, Y., Watson, J. T., Stucky, G. D., and Butler, A., Catalytic activity of mesoporous silicate-immobilized chloroperoxidase. J. Mol. Catal. B: Enzymatic, 17, 1-8 (2002).
9. Bornscheuer, U. T., and Kazlauskas, R. J., “Hydrolases in Organic Chemistry”, Wiley-VCH, Weinheim (1999).
10. Faber, K., “Biotransformation in Organic Chemistry” 4th ed., Springer-Verlag, Berlin (2000).
11. Kato, K., Gong, Y., Tanaka, S., Katayama, M., and Kimoto, H., Lipase-catalyzed optical resolution of trifluoro(aryl)ethanols. J. Mol. Catal. B: Enzymatic, 11, 287-294 (2001).
12. Kato, K., Gong, Y., Saito, T., and Yokogawa, Y., Preparation and catalytic performance of lipases encapsulated in sol-gel materials. Biosci. Biotechnol. Biochem., 66, 221-223 (2002).
13. Freemantle, M., Novel mesoporous hybrids prepared. Chem. Engineer. News, 78, 33-35 (2000).
14. Chen, C. S., Fujimoto, Y., Girdaukas, G., and Sih, C. J., Quantitative analysis of biochemical kinetic resolutions of enantiomers. J. Am. Chem. Soc., 104, 7294-7299 (1982)