Mechanistic insight gained into the ligand substitution reactions of bis(o-benzosemiquinonediiminato)(triphenylphosphane)cobalt(III) - Kinetic, solvent, and volume profile studies

European Journal of Inorganic Chemistry

Volumn , Issue 16, 2003, Pages 2972-2978

  Alzoubi, Basam M ^a   Hamza, Mohamed S A ^a,b   Dücker Benfer, Carlos ^a   Van Eldik, Rudi ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b Ain Shams University   (Egypt)

Author keywords

Cobalt; Kinetics; Ligand substitution; Mechanism; Pressure dependence; Solvent effects

Indexed keywords

CHEMICAL ACTIVATION; COBALT COMPOUNDS; KINETICS; LIGANDS; SOLVENTS; SUBSTITUTION REACTIONS;

4-DIMETHYLAMINOPYRIDINE; ACTIVATION PARAMETER; FORWARD REACTIONS; IMIDAZOL; LIGAND SUBSTITUTION; LIGAND SUBSTITUTION REACTIONS; MECHANISTICS; PRESSURE DEPENDENCE; REVERSE REACTIONS; SOLVENT EFFECTS;

NUCLEOPHILES;

4 DIMETHYLAMINOPYRIDINE; BIS(2 BENZOSEMIQUINONEDIIMINATO)(TRIPHENYLPHOSPHANE)COBALT; COBALT DERIVATIVE; IMIDAZOLE; UNCLASSIFIED DRUG;

ARTICLE; LIGAND BINDING; PRESSURE; REACTION ANALYSIS; SOLVENT EFFECT; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 0042322587     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300107     Document Type: Article

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