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Volumn 38, Issue 15, 1982, Pages 2279-2283

Retroaldol-aldol isomerization of perhydroazulenic hydroxyketones

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Indexed keywords


EID: 0042225745     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(82)87003-8     Document Type: Article
Times cited : (9)

References (17)
  • 8
    • 84918082726 scopus 로고    scopus 로고
    • The obtained product proved to be identical with a side-product originating from the Wittig reaction on 1, when DMSO was used as a solvent; previously we have assigned erroneously the structure of this product to the olefin which would result from attack at the C-6 carbonyl group (cfr. product 8 in ref. 3a). Apparently equilibration occurs under these circumstances (DMSO) and the cis-fused diketone 2 is the more reactive isomer.
  • 10
    • 0001239367 scopus 로고
    • For examples of preferred formation of trans-fused hydroazulenones under equilibration conditions, see
    • (1978) J. Org. Chem. , vol.43 , pp. 2153
    • House1    Sayer2    Yau3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.