Organic solid state reaction: Direct upper rim isopropylation of calix[4]arene

New Journal of Chemistry

Volumn 20, Issue 7-8, 1996, Pages 913-915

  Yao, B ^a   Bassus, J ^a   Lamartine, R ^a  

^a UNIVERSITÉ LYON 1   (France)

Author keywords

Direct upper rim alkylation; Heterogeneous catalysis; Isopropylation; Organic solid state reaction; P iso propylcalix 4 arene

Indexed keywords

EID: 0042207012     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (18)

1. (a) Gutsche C. D., Muthukrishnan R., J. Org. Chem., 1978, 43, 4905;
2. (b) Gutsche C. D., Iqbal M., Stewart D., J. Org. Chem., 1986, 51, 742.
3. Dhawan B., Chen S.-I., Gutsche C. D., Makromol. Chem., 1987, 188, 921.
4. Arduini A., Pochini A., Rizzi A., Sicuri A. R., Ugozzoli F., Ungaro R., Tetrahedron, 1992, 48, 905.
5. (a) Khomich A. N., Shokova E. A., Kovalev V. V., Synlett., 1994, 12, 1027;
6. (b) Kovalev V. V., Shokova E. A., Khomich A. N., Luzikov Y. N., New J. Chem., 1996, 20, 483.
7. The preparation of the catalyst is derived from the method described by Thor. The nickel sulfate was impregnated on γ-alumina in 20-80 proportion with about 100 mL of distilled water. The pasty solid was dried at 100°C and then calcined at 450-500 °C for 5 h in a stream of nitrogen. The dry solid obtained was ground to a powder.
8. Morawetz H., Science, 1966, 152, 705.
9. Perrin R., Lamartine R., Studies in Physical and Theoretical Chemistry, Structures and Properties of Molecular Crystals, Pierrot M., Ed, Elsevier, Amsterdam, 1990; vol. 69, p. 107.
10. Bassus J., Lamartine R., Lantéri P., Longeray R., New J. Chem., 1993, 17, 413.
11. (a) Tohr Y., Fumio N., Bull. Chem. Soc. Jpn., 1977, 50 (1), 10;
12. (b) Nitta M., Yamaguchi K., Aomura K., Bull. Chem. Soc. Jpn., 1974, 47, 2897;
13. Patkinson S. H., Friedman B. S., Friedel Crafts and Related Reactions, Olah G. A., Ed, Intersciences, New York, 1964, vol. 2, p. 3.
14. (a) Phan Than Luu R., Mathieu D., NEMROD (New Efficient Methodology for Research using Optimal Design) - software, L.P.R.A.I., Université Aix-Marseille III;
15. (b) Lantéri P., Longeray R., Chimie Industrielle, Perrin R., Scharff J. P., Eds, Masson, Paris, 1993, p. 259.
16. (a) Pritzker O.K., Petroleum Processing, 1946, 1, 58;
17. (b) Sullivan F. W., Science of Petroleum, Oxford University Press, 1938, vol. 4, p. 2664.
18. Gutsche C. D., Levine J. A., J. Am. Chem. Soc., 1982, 104, 2652.