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Volumn 22, Issue 17, 2003, Pages 3526-3532

Structural diversity of pentafluorophenylcopper complexes. First evidence of π-coordination of unsupported arenes to organocopper aggregates

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; NUCLEAR MAGNETIC RESONANCE; STRUCTURE (COMPOSITION); TOLUENE;

EID: 0041877138     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0302490     Document Type: Article
Times cited : (59)

References (60)
  • 43
    • 0001238047 scopus 로고    scopus 로고
    • π-Coordination has been encountered for arylcopper species in which chelation places the aryl group close to the Cu(I) center, thereby supporting the bonding interaction. This motif is present in the dimeric structure of (2,6-dimesitylphenyl)copper and the related trimer (2,6-diphenylphenyl)copper. Interestingly, the trimeric (2,6-diphenylphenyl)copper cocrystallizes with deuterated benzene, but the latter does not show any close contacts to the copper centers: Niemeyer, M. Organometallics 1998, 17, 4649.
    • (1998) Organometallics , vol.17 , pp. 4649
    • Niemeyer, M.1
  • 44
    • 37049128256 scopus 로고
    • This feature is unusual, but meta-coordination has, for example, been previously observed in the related bis(cyclohexylbenzene)silver(I) perchlorate complex: Hall, E. A.; Amma, E. L. Chem. Commun. 1968, 622.
    • (1968) Chem. Commun. , pp. 622
    • Hall, E.A.1    Amma, E.L.2
  • 48
    • 0042777250 scopus 로고    scopus 로고
    • note
    • 4 core.
  • 50
    • 0000228689 scopus 로고
    • For applications of other arylcopper species in main group organometallic chemistry, see: (a) van Koten, G.; Noltes, J. G. J. Am. Chem. Soc. 1976, 98, 5393.
    • (1976) J. Am. Chem. Soc. , vol.98 , pp. 5393
    • Van Koten, G.1    Noltes, J.G.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.