Preparation and crystal structures of dirhenium face-sharing bioctahedral complexes Re2(μ-SR)3X4(PR3)2, R = methyl, ethyl or phenyl, and X = Cl or Br

Polyhedron

Volumn 22, Issue 18, 2003, Pages 2625-2632

  Chaney, Christopher P ^a   Hibbard, Lori E T ^a   Horne, Keri T ^a   Howe, Tiffeny L C ^a   Powell, Gregory L ^a   Thurman, Derek W ^a  

^a ABILENE CHRISTIAN UNIVERSITY   (United States)

Author keywords

Crystal structures; Dirhenium complexes; Face sharing bioctahedral complexes; Metal metal multiple bonds; Phosphine ligands; Thiolate ligands

Indexed keywords

BINARY ALLOYS; CHEMICAL BONDS; CRYSTAL STRUCTURE; CRYSTALS; LIGANDS; PHOSPHORUS COMPOUNDS; RHENIUM COMPOUNDS; SULFUR COMPOUNDS; X RAY CRYSTALLOGRAPHY;

COMPLEX DISPLAYS; CRYSTALLOGRAPHIC STUDIES; CRYSTALS STRUCTURES; DIRHENIUM COMPLEX; FACE-SHARING BIOCTAHEDRAL COMPLEX; METAL-METAL MULTIPLE BOND; METHYL DISULFIDES; MULTIPLE BONDS; PHOSPHINE LIGANDS; THIOLATE LIGANDS;

ACETONE;

BENZENE DERIVATIVE; BROMINE; CHLORINE; METAL; METHYL GROUP; PHOSPHINE DERIVATIVE; RHENIUM COMPLEX;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; MAGNETISM; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0041765674     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(03)00352-8     Document Type: Article

References (14)

1. M.J. Bennett, F.A. Cotton, R.A. Walton, J. Am. Chem. Soc. 88 (1966) 3866.
2. F.A. Cotton, C. Oldham, R.A. Walton, Inorg. Chem. 6 (1967) 214.
3. B.J. Heyen, J.G. Jennings, G.L. Powell, Inorg. Chim. Acta 229 (1995) 241.
4. B.J. Heyen, J.G. Jennings, G.L. Powell, W.B. Roach, D.W. Thurman, L.M. Daniels, Polyhedron 20 (2001) 783.
5. F.A. Cotton, R.A. Walton, Multiple Bonds Between Metal Atoms, 2nd ed., Clarendon, Oxford, 1993, pp. 72-75, 80-94.
6. B.J. Heyen, G.L. Powell, Inorg. Chem. 29 (1990) 4574.
7. F.A. Cotton, K.R. Dunbar, Inorg. Chem. 26 (1987) 1305.
8. T.J. Barder, R.A. Walton, Inorg. Synth. 23 (1985) 116.
9. A.B. Brignole, F.A. Cotton, Inorg. Synth. 13 (1972) 81.
10. J.R. Ebner, R.A. Walton, Inorg. Chem. 14 (1975) 1987.
11. F.A. Cotton, G.L. Powell, J. Am. Chem. Soc. 106 (1984) 3371.
12. J.L. Deavenport, R.T. Stubbs, G.L. Powell, E.L. Sappenfield, D.F. Mullica, Inorg. Chim. Acta 215 (1994) 191.
13. Crystal data for compound 5: dark red, thin flake 0.20 × 0.10 × 0.012 mm, a = 18.404, b = 21.271, c = 21.369, α = β = γ = 90, Space group: Pbca, R (all data) = 0.35, Re-Re distance = 2.5(1) Å.
14. F.A. Cotton, R.A. Walton, Multiple Bonds Between Metal Atoms, 2nd ed., Clarendon, Oxford, 1993, pp. 600-606.