Natural 1.1 and 1.4 nm tobermorites from Fuka, Okayama, Japan: Chemical analysis, cell dimensions, 29Si NMR and thermal behavior

Cement and Concrete Research

Volumn 33, Issue 10, 2003, Pages 1515-1523

  Maeshima, Takayuki ^a   Noma, Hiroaki ^b   Sakiyama, Masato ^c   Mitsuda, Takeshi ^d  

^a Technical Development Laboratory   (Japan)

^b NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^c A and A Material Corporation   (Japan)

^d Graduate School of Integrated Science and Art   (Japan)

Author keywords

Characterization; Natural mineral; NMR; Tobermorite; X ray diffraction

Indexed keywords

DIFFERENTIAL THERMAL ANALYSIS; HEATING; METAMORPHIC ROCKS; OPTICAL MICROSCOPY; THERMOGRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; X RAY POWDER DIFFRACTION;

TOBERMORITES;

CONCRETES;

EID: 0041692416     PISSN: 00088846     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0008-8846(03)00099-1     Document Type: Article

References (43)

1. Heddle M.F. Preliminary notice of substances which may prove to be new minerals. Mineral. Mag. 4:1880;117-123.
2. Taylor H.F.W. Crestmoreite and riversideite. Mineral. Mag. 30:1953;155-165.
3. Claringbull G.F., Hey M.H. A re-examination of tobermorite. Mineral. Mag. 29:1952;960-962.
4. Murdoch J. Crestmore, past and present. Am. Mineral. 46:1961;245-257.
5. McConnell J.D.C. The hydrated calcium silicates riversideite, tobermorite, and plombierite. Mineral. Mag. 30:1954;293-305.
6. Farmer V.C., Jeevaratnam J., Speakman K., Taylor H.F.W. Thermal decomposition of 14 Å tobermorite from Crestmore. Symp. Struct. Portland Cem. Paste Concr. Spec. Rep. 90. 1966;291-299 U.S. Highway Res. Board, Washington.
7. Stephens J.D., Bray E. Occurrence and infrared analysis of unusual zeolitic minerals from Bingham, Utah. Mineral. Rec. 4:1973;67-72.
8. Mitsuda T., Kusachi I., Henmi K. Mixtures of 14 Å and 11 Å tobermorite from Fuka, Japan. Cem. Assoc. Jpn. Rev. Gen. Meet. 26:1972;64-68. (in Japanese).
9. Merlino S., Bonaccorsi E., Kampf A.R. Tobermorite 14 Å: crystal structure and OD character. Rammlmair D., Mederer J., Oberthür Th., Heimann R.B., Pentinghaus H. Applied Mineralogy. vol. 2:2000;859-861 A.A. Balkema, Rotterdam.
10. Mitsuda T. Paragenesis of 11 Å tobermorite and poorly crystalline hydrated magnesium silicate. Cem. Concr. Res. 3:1973;71-80.
11. Sweet J.M. Tacharanite and other hydrated calcium silicates from Portree, Isle of Skye. Mineral. Mag. 32:1961;745-753.
12. Gard J.A., Taylor H.F.W. A further investigation of tobermorite from Loch Eynort Scotland. Mineral. Mag. 31:1957;361-370.
13. Kusachi I., Henmi C., Henmi K. An oyelite-bearing vein at Fuka, the town of Bitchu, Okayama Prefecture. J. Jpn. Assoc. Miner. Petrol. Econ. Geol. 79:1984;267-275.
14. Heller L., Taylor H.F.W. Crystallographic Data for the Calcium Silicates. 1956;37-38 HMSO, London.
15. 2O, a new mineral from Fuka, Okayama Prefecture, Japan. Mineral. Mag. 56:1992;353-358.
16. 2O, a natural C-S-H (I) type cement mineral: determination of the substructure. Z. Kristallogr. 212:1997;864-873.
17. Merlino S., Bonaccorsi E., Armbruster T. The real structures of clinotobermorite and tobermorite 9: OD character, polytypes, and structural relationships. Eur. J. Mineral. 12:2000;411-429.
18. Megaw H.D., Kelsey C.H. Crystal structure of tobermorite. Nature. 177:1956;390-391.
19. 2O. Z. Kristallogr. 154:1981;189-198.
20. 29Si NMR spectroscopy of synthetic 14 Å, 11 Å, and 9 Å tobermorite. Cem. Concr. Res. 12:1982;333-339.
21. 29Si magic angle spinning nuclear magnetic resonance spectroscopy of Al-substituted tobermorites. J. Mater. Sci. 20:1985;4209-4214.
22. 29Si MASNMR spectroscopy and cation exchange properties. Cem. Concr. Res. 17:1987;891-895.
23. 17O NMR investigation of the structure of some crystalline calcium silicate hydrates. Adv. Cem. Based Mater. 3:1996;133-143.
24. Sakiyama M., Maeshima T., Mitsuda T. Synthesis and crystal chemistry of Al-substituted 11 Å tobermorite. J. Soc. Inorg. Mater. Jpn. 7:2000;413-419.
25. 29Si MASNMR, cation exchange, and water sorption studies. J. Am. Ceram. Soc. 74:1991;274-279.
26. 29Si NMR spectroscopy of silicate anions in hydrothermally formed C-S-H. J. Am. Ceram. Soc. 77:1994;765-768.
27. 29Si MAS NMR spectroscopy of poorly-crystalline calcium silicate hydrate (C-S-H). Colombet P., Grimmer A.-R., Zanni H., Sozzani P. Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials. 1998;159-168 Springer-Verlag, Berlin.
28. Mitsuda T., Toraya H., Okada Y., Shimoda M. Synthesis of tobermorite: NMR spectroscopy and analytical electron microscopy. Young W.S., Mcvay G.L., Pike G.E. Ceramic Transactions. vol. 5:1989;206-213 Am. Ceram. Soc. Ohio.
29. Merlino S., Bonaccorsi E., Armbruster T. Tobermorites: their real structure and order-disorder (OD) character. Am. Mineral. 84:1999;1613-1621.
30. Merlino S., Bonaccorsi E., Armbruster T. The real structure of tobermorite 11 Å: normal and anomalous forms, OD character and polytypic modifications. Eur. J. Mineral. 13:2001;577-590.
31. Yamazaki S., Toraya H. Determination of positions of zeolitic calcium atoms and water molecules in hydrothermally formed aluminum-substituted tobermorite-1.1 nm using synchrotron radiation powder diffraction data. J. Am. Ceram. Soc. 84(11):2001;2685-2690.
32. Mitsuda T., Taylor H.F.W. Normal and anomalous obermorites. Mineral. Mag. 42:1978;229-235.
33. El-Hemaly S.A.S., Mitsuda T., Taylor H.F.W. Synthesis of normal and anomalous tobermorites. Cem. Concr. Res. 7:1977;429-438.
34. Mitsuda T., Sasaki K., Ishida H. Phase evolution during autoclaving process of aerated concrete. J. Am. Ceram. Soc. 75:1992;1858-1863.
35. Hara N., Inoue N. Thermal behaviour of 11 Å tobermorite and its lattice parameters. Cem. Concr. Res. 10:1980;53-60.
36. Kalousek G.L., Roy R. Crystal chemistry of hydrous calcium silicates: II. Characterization of interlayer water. J. Am. Ceram. Soc. 40:1957;236-239.
37. Hara N., Chan C.F., Mitsuda T. Formation of 14 Å tobermorite. Cem. Concr. Res. 8:1978;113-116.
38. Hara N., Inoue N. Formation of 14 Å tobermorite from silica glass. Ceram. Soc. Jpn. 84:1976;181-185. (in Japanese).
39. Hara N., Inoue N., Noma H. Formation of jennite and tobermorite and their relationship with C-S-H gel in hydrated cement paste. Cohen M., Mindess S., Skalny J. Materials Science of Concrete - The Sydney Diamond Symposium. 1998;71-80 The American Ceramic Society, Westerville (Ohio, USA).
40. Hara N., Inoue N. Hydrothermal reaction of silica glass with lime at 70°-100 °C. Ceram. Soc. Jpn. 87:1979;134-141. (in Japanese).
41. Yu P., Kirkpatrick R.J. Thermal dehydration of tobermorite and jennite. Concr. Sci. Eng. 1:1999;185-191.
42. 1H nuclei. Bull. Chem. Soc. Jpn. 64:1991;685-687.
43. Isu N., Sasaki K., Ishida H., Mitsuda T. Mechanical property evolution during autoclaving process of aerated concrete using slag: I. Tobermorite formation and reaction behavior of slag. J. Am. Ceram. Soc. 77:1994;2088-2092.