Quantitative correlation between steric defects and thermal behavior in highly syndiotactic polystyrene: A study based on DSC and 13C NMR spectroscopy

Macromolecular Chemistry and Physics

Volumn 204, Issue 11, 2003, Pages 1428-1438

  Abbondanza, Luigi ^a   Abis, Luigi ^a   Cardi, Nicoletta ^a   Garbassi, Fabio ^a,b   Po, Riccardo ^a  

^a Polimeri Europa SpA   (Italy)

^b NONE   (Italy)

Author keywords

Crystallization; Differential scanning calorimetry (DSC); Melting point; NMR; Structure property relations; Syndiotactic

Indexed keywords

CATALYSTS; DIFFERENTIAL SCANNING CALORIMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS (CHEMICAL); THERMODYNAMICS;

STERIC DEFECTS;

POLYSTYRENES;

POLYSTYRENE; POLYSTYRENE DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CRYSTALLIZATION; DIFFERENTIAL SCANNING CALORIMETRY; POLYMERIZATION; STEREOCHEMISTRY; STRUCTURE ACTIVITY RELATION; SYNTHESIS;

EID: 0041669240     PISSN: 10221352     EISSN: None     Source Type: Journal    
DOI: 10.1002/macp.200350009     Document Type: Article

References (42)

1. N. Tomotsu, N. Ishihara, T. H. Newman, M. T. Malanga, J. Mol. Catal. A: Chem. 1998, 128, 167.
2. R. Po, N. Cardi, Progr. Polym. Sci. 1996, 21, 47.
3. P. Ammendola, C. Pellecchia, P. Longo, A. Zambelli, Gazz. Chim. Ital. 1987, 117, 65.
4. A. Grassi, C. Pellecchia, P. Longo, A. Zambelli, Gazz. Chim. Ital. 1987, 117, 249.
5. C. Pellecchia, P. Longo, A. Grassi, P. Ammendola, A. Zambelli, Makromol. Chem. Rapid Commun. 1987, 8, 277.
6. G. Minieri, P. Corradini, A. Zambelli, G. Guerra, L. Cavallo, Macromolecules 2001, 34, 2459.
7. P. Longo, A. Proto, A. Zambelli, Macromol. Chem. Phys. 1995, 196, 3015.
8. J. C. W. Chien, Z. Salajka, J. Polym. Sci. Part A: Polym. Chem. 1991, 29, 1253.
9. N. Ishihara, T. Seimiya, M. Kuramoto, M. Uoi, Macromolecules 1986, 19, 2464.
10. H. Sato, Y. Tanaka, K. Hatada, Makromol. Chem. Rapid Commun. 1982, 3, 181.
11. T. Kawamura, N. Toshima, Makromol. Chem. Rapid Commun. 1994, 15, 479.
12. H. J. Harwood, T. Chen, F. Lin, in: "NMR and Macromolecules", J. C. Randall, Ed., ACS Symposium Series, Washington 1984, Vol. 247, p. 197.
13. A. Tonelli, Macromolecules 1983, 16, 604.
14. N. Cardi, R. Fusco, L. Longo, R. Po, S. Spera, G. Bacchilega, "Proceedings of the Internatational Symposium on Ionic Polymerization", Paris 1997, p. 378.
15. J. Xu, J. Onyang, Z. Fan, D. Chen, L. Feng, Y. Yang, Polymer J. 1998, 30, 720.
16. E. M. Woo, Y. S. Sun, C. P. Yang, Progr. Polym. Sci. 2001, 26, 945.
17. C. Wang, Y. C. Hsu, C. F. Lo, Polymer 2001, 42, 8447.
18. N. Ishihara, M. Kuramoto, M. Uoi, Macromolecules 1987, 21, 3356.
19. G. Xu, Macromolecules 1998, 31, 586.
20. A. Kucht, H. Kucht, S. Barry, J. C. W. Chien, M. D. Rausch, Organometallics 1993, 12, 3075.
21. J. C. W. Chien, Z. Salajka, J. Polym. Sci. Part A: Polym. Chem. 1991, 29, 1243.
22. E. B. Bond, J. E. Spruiell, J. S. Lin, J. Polymer Sci. Part B: Polym. Phys. 1999, 37, 3050.
23. G. Allegra, S. V. Meille, in: "Crystallization of Polymers", M. Dosière, Ed., Kluwer, Dordrecht 1993, p. 263.
24. S. Z. D. Cheng, J. J. Janimak, A. Zhang, E. T. Hsieh, Polymer 1991, 32, 648.
25. H. Kucht, A. Kucht, J. C. W. Chien, M. D. Rausch, Appl. Organomet. Chem. 1994, 8, 393.
26. T. E. Ready, R. O. Day, J. C. W. Chien, M. D. Rausch, Macromolecules 1993, 26, 5822.
27. W. Kaminsky, S. Lenk, Makromol. Chem. Phys. 1994, 195, 2093.
28. US Pat. 5,629,391 (1997), EniChem SpA, invs.: N. Cardi, R. Po, R. Santi, G. Cometti; Chem. Abstr. 1997, 126, 144667.
29. US Pat. 5,721,327 (1998), EniChem SpA, invs.: R. Santi, G. Cometti, R. Po, N. Cardi; Chem. Abstr. 1997, 127, 278596.
30. R. D. Wesson, Polym. Eng. Sci. 1994, 34, 1157.
31. Z. Yuan, R. Song, D. Shen, Polym. Int. 2000, 49, 1337.
32. C. DeRosa, M. Rapacciuolo, G. Guerra, V. Petraccone, P. Corradini, Polymer 1992, 33, 1423.
33. G. Guerra, C. DeRosa, V. M. Vitagliano, V. Petraccone, P. Corradini,J. Polymer Sci. Part B: Polym. Phys. 1991, 29, 265.
34. S. Cimmino, E. DiPace, E. Martuscelli, C. Silvestre, Polymer 1991, 32, 1080.
35. PC Spartan Pro User's Guide, release 1.0, Wavefunction Inc., Irvine 1999.
36. T. A. Halgren, J. Comput. Chem. 1996, 17, 490.
37. HyperChem, release 6.03, HyperCube Inc. 2000.
38. R. Po, N. Cardi, L. Abis, Polymer 1998, 39, 959.
39. A. J. Pasztor, Jr., B. G. Landes, P. J. Karjala, Thermochim. Acta 1991, 177, 187.
40. B. Wunderlich, "Macromolecular Physics", Academic Press, New York 1980, Vol. 3, p. 30.
41. J. I. Lauritzen, Jr., J. D. Hoffman, J. Appl. Phys. 1973, 44, 4340.
42. V. B. F. Mathot, in: "Calorimetry and Thermal Analysis of Polymers", V. B. F. Mathot, Ed., Hanser/Gardner, Cincinnati 1994, Ch. 5, p. 136.