Extension of the cubic-plus-association equation of state to glycol-water cross-associating systems

Industrial and Engineering Chemistry Research

Volumn 42, Issue 7, 2003, Pages 1470-1477

  Derawi, Samer O ^a   Kontogeorgis, Georgios M ^a   Michelsen, Michael L ^a   Stenby, Erling H ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

GLYCOLS; PHASE EQUILIBRIA; STATISTICAL METHODS; WATER;

CROSS-ASSOCIATING COMPOUNDS;

ASSOCIATION REACTIONS;

CYCLOHEXANE; CYCLOHEXANE DERIVATIVE; DIETHYLENE GLYCOL; GLYCOL; HYDROCARBON; METHANOL; METHYLCYCLOHEXANE; TRIETHYLENE GLYCOL; UNCLASSIFIED DRUG; WATER;

EQUATION OF STATE;

ARTICLE; CORRELATION ANALYSIS; CUBIC PLUS ASSOCIATION; ENERGY; LIQUID; MOLECULAR INTERACTION; PREDICTION; SOLVATION; THERMODYNAMICS; VAPOR;

EID: 0041413337     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0206103     Document Type: Article

References (23)

1. Derawi, S. O.; Michelsen, M. L.; Kontogeorgis, G. M.; Stenby, E. H. Application of the CPA equation of state to glycol/hydrocarbns liquid-liquid equilibria. AIChE J. 2003, submitted for publication.
2. Kontogeorgis, G. M.; Yakoumis, I. V.; Meijer, H.; Hendriks, E. M.; Moorwood, T. Multicomponent phase equilibrium calculations for water-methanol-alkane mixyures. Fluid Phase Equilib. 1999, 158-160, 201-209.
3. Huang, S. H.; Radosz, M. Equation of state for small, large, polydisperse, and associating molecules. Ind. Eng. Chem. Res. 1990, 29, 2284-2294.
4. Suresh, J.; Beckman, E. J. Prediction of liquid-liquid equilibria in ternary mixtures from binary data. Fluid Phase Equilib. 1994, 99, 219-240.
5. Fu, Y.-H.; Sandler, S. I. A simplified SAFT equation of state for associating compounds and mixtures. Ind. Eng. Chem. Res. 1995, 34, 1897-1909.
6. Voutsas, E. C.; Yakoumis, I. V.; Tassios, D. P. Prediction of phase equilibria in water/alcohol/alkane systems. Fluid Phase Equilib. 1999, 158-160, 151-163.
7. Suresh, S. J.; Elliott, J. R. Multiphase equilibrium analysis via a generalized equation of state. Ind. Eng. Chem. Res. 1992, 31, 2783-2794.
8. Butler, J. A. V.; Thomson, D. W.; McLennan, W. H. J. Chem. Soc. 1933, 674.
9. Kurihara, K.; Minoura, T.; Takeda, K.; Kojima, K. J. Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water. J. Chem. Eng. Data 1995, 40, 679-684.
10. Chiavone-Filho, O.; Proust, P.; Rasmussen, P. Vapor-liquid equilibria for glycol ether + water systems. J. Chem. Eng. Data 1993, 38, 128-131.
11. Klyucheva, E. S.; Yarym-Agaev, N. L. Experimental study of liquid-vapor equilibrium in the system diethylene glycol-water. Zh. Prikl. Khim. 1980, 53 (5), 794-796.
12. Herskowitz, M.; Gottlieb, M. Vapor-liquid equilibrium in aqueous solutions of various glycols and poly(ethylene glycols), 1. Triethylene glycol. J. Chem. Eng. Data 1984, 29, 173-175.
13. Parrish, W. R.; Won, K. W.; Baltatu, M. E. Phase behaviour of the triethylene glycol-water system and dehydration/regeneration design for extremely low dew point requirements. Proceedings of the Sixty-Fifth Gas Processors Association Annual Convention, Mar 10-12, 1986; pp 202-210.
14. Chen, C. J.; Ng, H.-J.; Robinson, D. B. The solubility of methanol or glycol in water-hydrocarbon systems. Gas Processors Association (GPA) Research Report 117; DB Robinson Research Ltd.: Canada, 1988.
15. Simulation software & Database SPECS, version 4.1; IVC-SEP: Lyngby, Denmark.
16. Yarym-Agaev, N. L.; Sinyavskaya, R. P.; Koliushko, I. I.; Levinton, L. Ya. Zh. Prikl. Khim. (Leningrad) 1985, 58, 165.
17. Richon, D.; Laugier, S.; Renon, H. High-pressure vapor-liquid equilibria for binary mixtures containing a light paraffin and an aromatic compound or a naphthene in the range 313-473 K. J. Chem. Eng. Data 1991, 36, 104-111.
18. Jou, F.-Y.; Otto, F. D.; Marther, A. E. Solubility of methane in glycols at elevated pressures. Can. J. Chem. Eng. 1994, 72, 130-133.
19. Tsonopoulos, C.; Wilson, G. M. High-temperature mutual solubilities of hydrocarbons and water. AIChE J. 1983, 29 (6), 990-999.
20. Derawi, S. O.; Kontogeorgis, G. M.; Stenby, E. H.; Haugum, T.; Fredheim, A. O. Liquid-liquid equilbria for glycols + hydrocarbons: Data and correlation. J. Chem. Eng. Data 2002, 47, 169-173.
21. Prausnitz, J. M.; Lichtenthaler, R. N.; Gomes de Azevedo, E. Molecular thermodynamics of fluid phase equilibria; Prentice Hall: Englewood Cliffs, NJ, 1999.
22. Economou, I. G.; Donohue, M. D. Chemical, quasi-chemical and perturbation theories for associating fluids. AIChE J. 1991, 37 (12), 1875-1894.
23. Kontogeorgis, G. M.; Voutsas, E. C.; Yakoumis, I. V.; Tassios, D. P. An equation of state for associating fluids. Ind. Eng. Chem. Res. 1996, 35, 4310-4318.