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Volumn 119, Issue 8, 2003, Pages 4283-4293

Spectroscopic characterization of collision-induced electronic deformation energy using sum rules

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON ENERGY LEVELS; EMISSION SPECTROSCOPY; ENTROPY; FOURIER TRANSFORMS; HAMILTONIANS; INFRARED SPECTROSCOPY; LAPLACE TRANSFORMS; POTENTIAL ENERGY; SPECTROSCOPIC ANALYSIS; THERMOMETERS;

EID: 0041379446     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1592510     Document Type: Article
Times cited : (10)

References (57)
  • 5
    • 0004033934 scopus 로고
    • edited by G. Berthier, M. J. S. Dewar, H. Fischer et al. (Springer, Berlin)
    • F. M. Fernandez and E. A. Castro, in Lecture Notes in Chemistry, edited by G. Berthier, M. J. S. Dewar, H. Fischer et al. (Springer, Berlin, 1987), Vol. 43.
    • (1987) Lecture Notes in Chemistry , vol.43
    • Fernandez, F.M.1    Castro, E.A.2
  • 11
    • 0010242016 scopus 로고
    • note
    • Our results are primarily sensitive to the dipole function for close-in collisions, where the potential V(R) is repulsive and detailed quantum mechanical computations [R. L. Matcha and R. K. Nesbet, Phys. Rev. 160, 72 (1967)] are available for that region of R.
    • (1967) Phys. Rev. , vol.160 , pp. 72
    • Matcha, R.L.1    Nesbet, R.K.2
  • 39
    • 0000757103 scopus 로고
    • note
    • α) can be written as the vector sum of the contribution of the atoms. This must be so obvious that we could find no reference to it. The nearest is the casual remark by Buckingham [A. D. Buckingham, Adv. Chem. Phys. 12, 107 (1967)] that for a neutral species the choice of origin of the dipole moment makes no difference to its value.
    • (1967) Adv. Chem. Phys. , vol.12 , pp. 107
    • Buckingham, A.D.1
  • 40
    • 0042492507 scopus 로고    scopus 로고
    • note
    • There is also a quantum correction that is due to the recoil when the photon is emitted.
  • 41
    • 36849131461 scopus 로고
    • note
    • v|v>. In a nonstationary state the virial changes with time, J. O. Hirschfelder, J. Chem. Phys. 33, 1462 (1960)
    • (1960) J. Chem. Phys. , vol.33 , pp. 1462
    • Hirschfelder, J.O.1
  • 45
    • 0041490656 scopus 로고    scopus 로고
    • note
    • 2 is not quite a symmetric function of v about the origin. We show that this asymmetry arises naturally if the power radiated is not computed from the dipole but from the dipole velocity, as this introduces a quantal correction term. Eq. (27).
  • 47
    • 0042993263 scopus 로고    scopus 로고
    • note
    • -1 for rate gas atom-atom collisions.
  • 51
    • 0008984048 scopus 로고
    • note
    • 2), μ(v) is exactly a Gaussian in frequency. H. B. Levine and G. Birnbaum, Phys. Rev. 154, 86 (1967).
    • (1967) Phys. Rev. , vol.154 , pp. 86
    • Levine, H.B.1    Birnbaum, G.2
  • 55
    • 0041991631 scopus 로고    scopus 로고
    • note
    • The temperature parameter 1/β is the temperature of the electronic deformation and it is not equal to the translational temperature because we specifically constrained the electronic state to be the ground state. Therefore one cannot relate the exponential term in Eq. (36) to considerations of detailed balance. Also, note that to get Eq. (36) from Eq. (33) the sign of the frequency v needs to be changed because we write emission vs the photon frequency.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.