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edited by G. Berthier, M. J. S. Dewar, H. Fischer et al. (Springer, Berlin)
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F. M. Fernandez and E. A. Castro, in Lecture Notes in Chemistry, edited by G. Berthier, M. J. S. Dewar, H. Fischer et al. (Springer, Berlin, 1987), Vol. 43.
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Fernandez, F.M.1
Castro, E.A.2
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11
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0010242016
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note
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Our results are primarily sensitive to the dipole function for close-in collisions, where the potential V(R) is repulsive and detailed quantum mechanical computations [R. L. Matcha and R. K. Nesbet, Phys. Rev. 160, 72 (1967)] are available for that region of R.
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Phys. Rev.
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Matcha, R.L.1
Nesbet, R.K.2
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13
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0002880737
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Q. Ma, R. H. Tipping, G. Birnbaum, and C. Boulet, J. Quant. Spectrosc. Radiat. Transf. 59, 259 (1998).
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J. Quant. Spectrosc. Radiat. Transf.
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Ma, Q.1
Tipping, R.H.2
Birnbaum, G.3
Boulet, C.4
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19
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0037128340
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A. Gross, H. Kornweitz, T. Raz, and R. D. Levine, Chem. Phys. Lett. 354, 395 (2002).
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Chem. Phys. Lett.
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Gross, A.1
Kornweitz, H.2
Raz, T.3
Levine, R.D.4
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4243429913
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U. Even, P. deLange, H. Jonkman, and J. Kommandeur, Phys. Rev. Lett. 56, 965 (1986).
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Even, U.1
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Kommandeur, J.4
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23
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0035981065
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M. Boyle, K. Hoffmann, C. P. Schulz, I. V. Hertel, R. D. Levine, and E. E. B. Campbell, Phys. Rev. Lett. 87, 273401 (2001).
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Phys. Rev. Lett.
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Boyle, M.1
Hoffmann, K.2
Schulz, C.P.3
Hertel, I.V.4
Levine, R.D.5
Campbell, E.E.B.6
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24
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0032263866
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J. M. Weber, K. Hansen, M.-W. Ruf, and H. Hotop, Chem. Phys. 239, 271 (1998).
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Weber, J.M.1
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Hotop, H.4
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33
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0041991633
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A. G. Basile, C. G. Gray, B. G. Nickel, and J. D. Poll, Mol. Phys. 66, 961 (1989).
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Basile, A.G.1
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Nickel, B.G.3
Poll, J.D.4
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39
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0000757103
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note
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α) can be written as the vector sum of the contribution of the atoms. This must be so obvious that we could find no reference to it. The nearest is the casual remark by Buckingham [A. D. Buckingham, Adv. Chem. Phys. 12, 107 (1967)] that for a neutral species the choice of origin of the dipole moment makes no difference to its value.
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Adv. Chem. Phys.
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Buckingham, A.D.1
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40
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0042492507
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note
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There is also a quantum correction that is due to the recoil when the photon is emitted.
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41
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36849131461
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note
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v|v>. In a nonstationary state the virial changes with time, J. O. Hirschfelder, J. Chem. Phys. 33, 1462 (1960)
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J. Chem. Phys.
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Hirschfelder, J.O.1
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45
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0041490656
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note
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2 is not quite a symmetric function of v about the origin. We show that this asymmetry arises naturally if the power radiated is not computed from the dipole but from the dipole velocity, as this introduces a quantal correction term. Eq. (27).
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47
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0042993263
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note
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-1 for rate gas atom-atom collisions.
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51
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0008984048
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note
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2), μ(v) is exactly a Gaussian in frequency. H. B. Levine and G. Birnbaum, Phys. Rev. 154, 86 (1967).
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Phys. Rev.
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Levine, H.B.1
Birnbaum, G.2
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54
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0011766188
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G. E. Caledonia, R. H. Krech, T. D. Wilkerson, R. L. Taylor, and G. Birmbaum, Phys. Rev. A 43, 6010 (1991).
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Phys. Rev. A
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Caledonia, G.E.1
Krech, R.H.2
Wilkerson, T.D.3
Taylor, R.L.4
Birmbaum, G.5
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55
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0041991631
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note
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The temperature parameter 1/β is the temperature of the electronic deformation and it is not equal to the translational temperature because we specifically constrained the electronic state to be the ground state. Therefore one cannot relate the exponential term in Eq. (36) to considerations of detailed balance. Also, note that to get Eq. (36) from Eq. (33) the sign of the frequency v needs to be changed because we write emission vs the photon frequency.
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